Multi-scale modeling of the mechanical behavior of polymer-based materials

Polymers have become the reference material for high reliability and performance applications. In this work, a multi-scale approach is proposed to investigate the mechanical properties of polymeric based material under strain. To achieve a better understanding of phenomena occurring at the smaller scales, a coupling of a Finite Element Method (FEM) and Molecular Dynamics (MD) modeling in an iterative procedure was employed, enabling the prediction of the macroscopic constitutive response. As the mechanical response can be related to the local microstructure, which in turn depends on the nano-scale structure, the previous described multi-scale method computes the stress-strain relationship at every analysis point of the macro-structure by detailed modeling of the underlying micro- and meso-scale deformation phenomena. The proposed multi-scale approach can enable prediction of properties at the macroscale while taking into consideration phenomena that occur at the mesoscale, thus offering an increased potential accuracy compared to traditional methods.

Predicting the mechanical behavior of amorphous polymeric materials under strain through multi-scale simulation

Polymeric materials have become the reference material for high reliability and performance applications. However, their performance in service conditions is difficult to predict, due in large part to their inherent complex morphology, which leads to non-linear and anisotropic behavior, highly dependent on the thermomechanical environment under which it is processed. In this work, a multiscale approach is proposed to investigate the mechanical properties of polymeric-based material under strain. To achieve a better understanding of phenomena occurring at the smaller scales, the coupling of a finite element method (FEM) and molecular dynamics (MD) modeling, in an iterative procedure, was employed, enabling the prediction of the macroscopic constitutive response. As the mechanical response can be related to the local microstructure, which in turn depends on the nano-scale structure, this multiscale approach computes the stress-strain relationship at every analysis point of the macro-structure by detailed modeling of the underlying micro- and meso-scale deformation phenomena. The proposed multiscale approach can enable prediction of properties at the macroscale while taking into consideration phenomena that occur at the mesoscale, thus offering an increased potential accuracy compared to traditional methods.

PODEM AS DÍVIDAS DO BES SER DO NOVO BANCO?

No ponto de vista jurídico existe um velho instituto jurídico que se chama “Levantamento ou desconsideração da personalidade colectiva” que pode permitir – por palavras breves – imputar as dívidas do BES ao Novo Banco. Também é possível nos socorrermos do instituto do Abuso do Direito (art. 334º do Código Civil): “É ilegítimo o exercício de um direito, quando o titular exceda manifestamente os limites impostos pela boa fé, pelos bons costumes ou pelo fim social ou económico desse direito”. Aplica-se o art. 11º/8 do Código Penal: «8 - A cisão e a fusão não determinam a extinção da responsabilidade criminal da pessoa colectiva ou entidade equiparada, respondendo pela prática do crime: § a) A pessoa colectiva ou entidade equiparada em que a fusão se tiver efectivado; § e § b) As pessoas colectivas ou entidades equiparadas que resultaram da cisão». § In the legal point of view there is an old legal principle called "Lifting or disregard of legal personality" which can allow - for brief words - charge the debts of the BES to the New Bank. It is also possible in socorrermos Law Abuse Institute (Article 334 of the Civil Code.): "It is illegitimate exercise of a right, where the proprietor clearly exceed the bounds of good faith, morality or the social or economic purpose this right ". Applies the art. 11/8 of the Penal Code: "8 - The split and the merger does not determine the extinction of criminal liability of the legal or related entity person, accounting for the crime: § a) The legal person or related entity in the merger if paid up; § and § b) A legal entity or similar entities resulting from the split. "