Molecular dynamics computer simulation of scratch resistance testing of polymers: visualization

Experimental scratch resistance testing provides two numbers: the penetration depth Rp and the healing depth Rh. In molecular dynamics computer simulations, we create a material consisting of N statistical chain segments by polymerization; a reinforcing phase can be included. Then we simulate the movement of an indenter and response of the segments during X time steps. Each segment at each time step has three Cartesian coordinates of position and three of momentum. We describe methods of visualization of results based on a record of 6NX coordinates. We obtain a continuous dependence on time t of positions of each of the segments on the path of the indenter. Scratch resistance at a given location can be connected to spatial structures of individual polymeric chains.

Mechanical Behavior of the Lamellar Structure in Semi-Crystalline Polymers

We have employed molecular dynamics simulations to study the behavior of virtual polymeric materials under an applied uniaxial tensile load. Through computer simulations, one can obtain experimentally inaccessible information about phenomena taking place at the molecular and microscopic levels. Not only can the global material response be monitored and characterized along time, but the response of macromolecular chains can be followed independently if desired. The computer-generated materials were created by emulating the step-wise polymerization, resulting in self-avoiding chains in 3D with controlled degree of orientation along a certain axis. These materials represent a simplified model of the lamellar structure of semi-crystalline polymers,being comprised of an amorphous region surrounded by two crystalline lamellar regions. For the simulations, a series of materials were created, varying i) the lamella thickness, ii) the amorphous region thickness, iii) the preferential chain orientation, and iv) the degree of packing of the amorphous region. Simulation results indicate that the lamella thickness has the strongest influence on the mechanical properties of the lamella-amorphous structure, which is in agreement with experimental data. The other morphological parameters also affect the mechanical response, but to a smaller degree. This research follows previous simulation work on the crack formation and propagation phenomena, deformation mechanisms at the nanoscale, and the influence of the loading conditions on the material response. Computer simulations can improve the fundamental understanding about the phenomena responsible for the behavior of polymeric materials, and will eventually lead to the design of knowledge-based materials with improved properties.

Comissão de fiscalização e disciplina do sindicato nacional do ensino superior (CFD/SNESup): quem somos, o que temos feito e para que serve?

A Comissão de Fiscalização e Disciplina, como o próprio nome indica, serve para fiscalizar e disciplinar, no caso de necessidade, adequação, proporcionalidade, sempre com uma intervenção mínima. De acordo com o art. 8º/6 dos Estatutos do SNESup cabe à CFD declarar a perda ou suspensão compulsiva da qualidade de associado na sequência de processo disciplinar, em virtude de incumprimento grave dos respectivos deveres. Abstract: The Audit and Discipline, as its name implies, is to supervise and regulate, in case of necessity, appropriateness, proportionality, always with minimal intervention. According to art. 8/6 of the Statute SNESup it is for the CFD to confiscate or forced suspension of membership in the disciplinary procedure, due to a serious breach of his duties.