Aplicación de un modelo geográfico con información climática para el cálculo del balance hídrico de la comarca de la Marina Baja (Alicante)

Este trabajo analiza las nuevas tendencias en la creación y gestión de información geográfica, para la elaboración de modelos inductivos basados exclusivamente en bases de datos geográficas. Estos modelos permiten integrar grandes volúmenes de datos de características heterogéneas, lo que supone una gran complejidad técnica y metodológica. Se propone una metodología que permite conocer detalladamente la distribución de los recursos hídricos naturales en un territorio y derivar numerosas capas de información que puedan ser incorporadas a estos modelos «ávidos de datos» (data-hungry). La zona de estudio escogida para aplicar esta metodología es la comarca de la Marina Baja (Alicante), para la que se presenta un cálculo del balance hídrico espacial mediante el uso de herramientas estadísticas, geoestadísticas y Sistemas de Información Geográfica. Finalmente, todas las capas de información generadas (84) han sido validadas y se ha comprobado que su creación admite un cierto grado de automatización que permitirá incorporarlas en análisis de Minería de Datos más amplios.

Ion balance in waters through inductively coupled plasma optical emission spectrometry

Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) has been employed to carry out the determination of both major anions and cations in water samples. The anion quantification has been performed by means of a new automatic accessory. In this device chloride has been determined by continuously adding a silver nitrate solution. As a result solid silver chloride particles are formed and retained on a nylon filter inserted in the line. The emission intensity is read at a silver characteristic wavelength. By plotting the drop in silver signal versus the chloride concentration, a straight line is obtained. As regards bicarbonate, this anion has been on-line transformed into carbon dioxide with the help of a 2.0 mol L−1 nitric acid stream. Carbon signal is linearly related with bicarbonate concentration. Finally, information about sulfate concentration has been achieved by means of the measurement of sulfur emission intensity. All the steps have been simultaneously and automatically performed. With this setup detection limits have been 1.0, 0.4 and 0.09 mg L−1 for chloride, bicarbonate and sulfate, respectively. Furthermore, it affords good precision with RSD below 6 %. Cation (Ca, Mg, Na and K) concentration, in turn, has been obtained by simultaneously reading the emission intensity at characteristic wavelengths. The obtained limits of detection have been 8 × 10−3, 2 × 10−3, 8 × 10−4 and 10−2 mg L−1 for sodium, potassium, magnesium and calcium, respectively. As regards sample throughput, about 30 samples h−1 can be analysed. Validation results have revealed that the obtained concentrations for these anions are not significantly different as compared to the data provided by conventional methods. Finally, by considering the data for anions and cations, precise ion balances have been obtained for well and mineral water samples.