Applying reactive models to column experiments to assess the hydrogeochemistry of seawater intrusion: optimising ACUAINTRUSION and selecting cation exchange coefficients with PHREEQC

Three sets of laboratory column experimental results concerning the hydrogeochemistry of seawater intrusion have been modelled using two codes: ACUAINTRUSION (Chemical Engineering Department, University of Alicante) and PHREEQC (U.S.G.S.). These reactive models utilise the hydrodynamic parameters determined using the ACUAINTRUSION TRANSPORT software and fit the chloride breakthrough curves perfectly. The ACUAINTRUSION code was improved, and the instabilities were studied relative to the discretisation. The relative square errors were obtained using different combinations of the spatial and temporal steps: the global error for the total experimental data and the partial error for each element. Good simulations for the three experiments were obtained using the ACUAINTRUSION software with slight variations in the selectivity coefficients for both sediments determined in batch experiments with fresh water. The cation exchange parameters included in ACUAINTRUSION are those reported by the Gapon convention with modified exponents for the Ca/Mg exchange. PHREEQC simulations performed using the Gains-Thomas convention were unsatisfactory, with the exchange coefficients from the database of PHREEQC (or range), but those determined with fresh water – natural sediment allowed only an approximation to be obtained. For the treated sediment, the adjusted exchange coefficients were determined to improve the simulation and are vastly different from those from the database of PHREEQC or batch experiment values; however, these values fall in an order similar to the others determined under dynamic conditions. Different cation concentrations were simulated using two different software packages; this disparity could be attributed to the defined selectivity coefficients that affect the gypsum equilibrium. Consequently, different calculated sulphate concentrations are obtained using each type of software; a smaller mismatch was predicted using ACUAINTRUSION. In general, the presented simulations by ACUAINTRUSION and PHREEQC produced similar results, making predictions consistent with the experimental data. However, the simulated results are not identical to the experimental data; sulphate (total S) is overpredicted by both models, most likely due to such factors as the kinetics of gypsum, the possible variations in the exchange coefficients due to salinity and the neglect of other processes.

Albaceteplural: perspectiva de género y gestión de la participación en un plan de ordenación municipal

La incorporación de la perspectiva de género al planeamiento es una obligación de las administraciones públicas españolas, nacionales, autonómicas y locales. El ayuntamiento de Albacete y la Junta de Comunidades de Castilla La Mancha, en cumplimiento de estos preceptos y en ocasión de la revisión del Plan General de Ordenación Urbana, encargan a la autora del presente artículo la dirección de los equipos de trabajo para la gestión de la participación ciudadana, que se sitúa en la base misma de la consecución de los objetivos propuestos. El trabajo presentado se centra en la experiencia metodológica de la participación in situ, en la investigación que la sustentó y en las innovaciones que aporta. Se exponen los mecanismos e instrumentos habilitados para la participación que, habida cuenta de la casi total ausencia de referencias en España, constituyen una primera aproximación de posibles buenas prácticas a aplicar en otros proyectos similares.

Pulsar science with the SKA

The unprecedented sensitivity and large field of view of SKA will be of paramount importance for pulsar science, and for many related research fields. In particular, beside the obvious discovery of many more pulsars (even those with very low luminosity), and the extremely accurate timing analysis of the current pulsar population, SKA will allow to use pulsars to measure or put strong constraints on gravitational waves, Galactic magnetism, planet masses, general relativity and nuclear physics.

Are pulsars born with a hidden magnetic field?

The observation of several neutron stars in the centre of supernova remnants and with significantly lower values of the dipolar magnetic field than the average radio-pulsar population has motivated a lively debate about their formation and origin, with controversial interpretations. A possible explanation requires the slow rotation of the protoneutron star at birth, which is unable to amplify its magnetic field to typical pulsar levels. An alternative possibility, the hidden magnetic field scenario, considers the accretion of the fallback of the supernova debris on to the neutron star as responsible for the submergence (or screening) of the field and its apparently low value. In this paper, we study under which conditions the magnetic field of a neutron star can be buried into the crust due to an accreting, conducting fluid. For this purpose, we consider a spherically symmetric calculation in general relativity to estimate the balance between the incoming accretion flow and the magnetosphere. Our study analyses several models with different specific entropy, composition, and neutron star masses. The main conclusion of our work is that typical magnetic fields of a few times 1012 G can be buried by accreting only 10−3–10−2 M⊙, a relatively modest amount of mass. In view of this result, the central compact object scenario should not be considered unusual, and we predict that anomalously weak magnetic fields should be common in very young (< few kyr) neutron stars.