Geología en la costa: técnicas de análisis de sedimentos e interpretación de ambientes sedimentarios

El estudio de los componentes, tanto bióticos como abióticos, que forman los sedimentos y rocas sedimentarias posibilita de modo fácil y directo la obtención de información sobre el medio de depósito. En este taller se describe la metodología para el análisis de las micofacies utilizando, como ejemplo, sedimentos costeros y marinos de edad Messiniense y Plioceno de la Cuenca del Bajo Segura (Alicante).

Nanocontacts: probing electronic structure under extreme uniaxial strains

Nanometer-sized metallic necks have the unique ability to sustain extreme uniaxial loads (about 20 times greater than the bulk material). We present an experimental and theoretical study of the electronic transport properties under such extreme conditions. Conductance measurements on gold and aluminum necks show a strikingly different behavior: While gold shows the expected conductance decrease with increasing elastic elongation of the neck, aluminum necks behave in the opposite way. We have performed first-principles electronic-structure calculations which reproduce this behavior, showing that it is an intrinsic property of the bulk band structure under high uniaxial strain.

The "other" cities: urban planning and architecture for tourism: the case of the Spanish Mediterranean (1945-1975)

There we analyce the first touristic nucleus arouse in the Spanish Mediterranean coast between World War II and the Petroleum Crisis (1945-75). Special attention is payed to the characteristics of these new villages: the relation of their urban frame with nature -original or artificial- and the lack of industry. We make a distintion of three types: cluster nucleus (La Manga and El Saler), tridimentional urbanism (Playa de San Juan y Urbanova) and extreme typologies (Campoamor and Benidorm). With them the cities for vacations are discovered, mainly for second home purpouse (vacation home/holiday home). The panorama after the current crisis is a lineal chain of small urban settlements on the coast. Finally, Finally, we can see how these "secondary cities" without industry and specialized in leisure, are developing to our days until become new cities of services, doubling the existing ones; now they are "the other cities".

Probing the Electrocatalytic Oxygen Reduction Reaction Reactivity of Immobilized Multicopper Oxidase CueO

The bioelectrocatalytic (oxygen reduction reaction, ORR) properties of the multicopper oxidase CueO immobilized on gold electrodes were investigated. Macroscopic electrochemical techniques were combined with in situ scanning tunneling microscopy (STM) and surface-enhanced Raman spectroscopy at the ensemble and at the single-molecule level. Self-assembled monolayer of mercaptopropionic acid, cysteamine, and p-aminothiophenol were chosen as redox mediators. The highest ORR activity was observed for the protein attached to amino-terminated adlayers. In situ STM experiments revealed that the presence of oxygen causes distinct structure and electronic changes in the metallic centers of the enzyme, which determine the rate of intramolecular electron transfer and, consequently, affect the rate of electron tunneling through the protein. Complementary Raman spectroscopy experiments provided access for monitoring structural changes in the redox state of the type 1 copper center of the immobilized enzyme during the CueO-catalyzed oxygen reduction cycle. These results unequivocally demonstrate the existence of a direct electronic communication between the electrode substrate and the type 1 copper center.

Una mirada a la dispersión de semillas en las excretas de mamíferos

Terrestrial mammals are good dispersers of the fruits and seeds of seasonal rainforest in the Gulf of Mexico. Their importance lies in the huge quantity of fruit and seeds they consume, and their daily and seasonal movement through natural and secondary vegetation and agricultural fields. Their importance is even more noteworthy in the face of increasing deforestation and forest fragmentation, which limits the dispersal of propagules across the landscape and affects, among other things, the potential for forest regeneration. To evaluate fruit and seed consumption and dispersal over 12 months, the droppings of rainforest mammals were analyzed for the rainforest and an abandoned pasture (8,400 m2 respectively) on the coast of central Veracruz, Mexico. In the rainforest 158 droppings were collected and 47 in the pasture from a total of eight mammal species, six of which are known dispersers. The droppings contained 150 seeds belonging to 36 species and 19 families. The deposition of different species and quantities of seeds in the forest and pasture indicates that mammals disperse more rainforest species to the pasture than vice versa.

La expansión urbanística reciente de la costa alicantina, una realidad constatable

Se propone analizar la ocupación del suelo durante las dos últimas décadas en la costa de la provincia de Alicante; para ello se plantea estudiar las características de las nuevas ocupaciones, así como los nuevos modelos de ocupación urbana y territorial. Estas nuevas tendencias territoriales suponen un cambio importante en la utilización del territorio que conlleva nuevas relaciones espaciales y funcionales. Los objetivos del trabajo se centran, por tanto, en la identificación y caracterización de las áreas de nuevo crecimiento reciente y su evaluación cuantitativa —superficie, densidad, etc.— y cualitativa —nuevos paisajes, morfologías, etc. La metodología planteada parte del análisis gráfico y estadístico para abordar su consideración cuantitativa, posteriormente. A partir de la comparación entre las imágenes satelitales ofrecidas por el proyecto europeo Corine Land Cover en la Comunidad Valenciana correspondientes a los años 1990 y 2006, se identifican las principales áreas de crecimiento durante estas etapas. Una vez definidas dichas áreas de crecimiento, se plantea abordar el análisis gráfico en detalle, a partir de las fotografías aéreas correspondientes a las fechas más cercanas a las de Corine Land Cover. Por otro lado, las diferentes bases estadísticas ofrecidas por las distintas administraciones públicas permiten cuantificar dichos crecimientos y evaluar sus densidades. Los resultados esperados se centran en la caracterización y definición de los nuevos modelos de ocupación urbana en el litoral alicantino, así como las características territoriales del nuevo urbanismo reciente. La identificación de esos nuevos modelos residenciales permite incidir en las futuras planificaciones y planeamiento, tanto territorial como municipal.

Levantando las arquitecturas de las guerras en la costa del Mediterráneo (1936-1939)

During the civil war (1936-39) was built a network of defensive settlements on the coast in anticipation of attacks enemies, forming the so-called 'wall Mediterranean', because of its similarity with the Wall Atlantic of the World War II. These enclaves were composed of groups of batteries, bunkers and buildings. This communication comes to inventory and draw the remains of more than 50 architectures that are located in the Valencian South Coast (from Denia to Torrevieja), documenting the first ruins of hormigion armed with our history. It's a set of military settlements anti-aircraft, mostly scattered coastal rural, which are a great heritage and landscape value, and from which planes haven't been preserved. It is to lift current state record of them all, proceeding to its typological classification, in order to contribute to its assessment and protection on the grounds that they constitute a legacy of architectural heritage that increases our cultural memory.history.

La actividad laboral de las familias africanas y latinoamericanas reagrupadas en la España mediterránea

La investigación se basa en los resultados de una encuesta realizada en 2009-2010, por el equipo investigador, a 348 inmigrados reagrupantes africanos y a 457 latinoamericanos que residen en las provincias litorales entre Girona y Almería. La información que se ofrece está referida a los aspectos laborales de estos dos colectivos continentales, tanto a escala del conjunto territorial indicado como para tres subáreas incluidas en él: Cataluña litoral, Comunidad Valenciana y Murcia-Almería; según los temas, se trata por separado a los reagrupantes y a los subgrupos familiares que conviven en España (reagrupantes, cónyuges, hijos). El estudio se centra en las estructuras de empleo por sectores económicos. También se estudian las redes migratorias, tan decisivas en la orientación de estos flujos hacia España, la regulación laboral de estos trabajadores, la repercusión de la crisis actual en los empleos de las familias reagrupadas (paro, número de ocupados por familia e ingresos), la satisfacción laboral de los miembros de las familias (horas de trabajo, problemas laborales y salariales) y la estabilidad laboral (antigüedad en el empleo, cursos de formación profesional, trabajo actual y expectativas del inmigrante). El recorrido por los temas laborales indicados, vinculados a los distintos grupos continentales y familiares y a las diferentes escalas territoriales, concluyen en mostrar situaciones económicas y sociales muy diferentes entre africanos y latinoamericanos, y entre los que residen en Cataluña litoral y en Murcia-Almería, en lo que intervienen, entre otras causas, los distintos «capitales» personales aportados por los dos colectivos continentales para acceder al empleo (formación, idioma, …) y las diferentes estructuras económicas de los territorios estudiados. Los africanos y los que residen en las provincias meridionales son los que presentan peores situaciones socioeconómicas.

Polychaete distribution pattern on the Valencian Community coast, Spanish Mediterranean

Changes in benthic community structure are strongly related to environmental factors, and we need to determine how these natural changes occur in order to interpret the possible changes associated with anthropogenic impacts. The aim of this survey was to characterize and classify the polychaete assemblages inhabiting unpolluted soft bottoms in the Spanish Mediterranean in relation to environmental factors. Thirteen localities were sampled at depths between 9 and 31 m, from 2004 to 2006. Multivariate techniques showed that the structure of polychaete assemblages detected in 2004 was consistent over time and correlations between polychaetes and environmental factors were detected. The study area comprises four kinds of communities mainly characterized by polychaete assemblages, sediment types, and depth.

Colloidal gold immobilized on mesoporous silica as a highly active and selective catalyst for styrene epoxidation with H2O2

Colloidal gold nanoparticles were synthesized by different procedures affording suspensions with two different mean sizes (2 and 5 nm). Au catalysts were prepared by sol immobilization onto several silica frameworks with different 2D and 3D mesoporosities. The catalysts were tested in styrene oxidation reactions showing excellent efficiency and selectivity. The effect of nanoparticle size and mesoporous framework on the physical and catalytic properties of the final materials was studied. The most selective catalyst was prepared from the 5 nm Au nanoparticles and the more interconnected silica framework (3D mesoporosity).

Superior performance of gold supported on doped CeO2 catalysts for the preferential CO oxidation (PROX)

Herein, the preferential oxidation of CO in excess hydrogen (PROX reaction) was studied over Au catalysts supported on ceria and Y or Nb doped ceria. Both supports and catalysts have been extensively characterized by a number of advanced techniques; XRD, N2-adsortion, Raman spectroscopy, XPS, and H2-TPR. The catalytic results showed that when an ideal mixture of H2 and CO is used for the PROX reaction the gold supported on pure ceria behaves better than the others samples. However, when a typical reformate gas composition containing CO2 and H2O is used, the gold supported on Nb doped sample behaves better than gold supported in pure ceria. It is suggested that niobium hampers the strong adsorption of CO2 and H2O in the active sites, thus improving the catalytic performance in real reformate gas.

Gold Nanoparticles Supported on Polyacrylamide Containing a Phosphorus Ligand as an Efficient Heterogeneous Catalyst for Three-Component Synthesis of Propargylamines in Water

Gold nanoparticles supported on a polyacrylamide containing a phosphinite ligand have been synthesized and characterized using different techniques such as TEM, SEM, EDX, XPS, and solid UV analyses. The new material was successfully applied as a heterogeneous catalyst for the three-component A3 coupling of amines, aldehydes, and alkynes to give propargylamines. Reactions are performed in neat water at 80 °C with only 0.05 mol% catalyst loading. The heterogeneous catalyst is recyclable during seven consecutive runs with small decrease in activity.