7 resultados para Pseudo homogeneous variety

em Universidad de Alicante


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The objective of this study is to test the effect of the consumer’s variety-seeking behaviour on the distance the tourist is prepared to travel; that is, his/her willingness to travel further. The empirical application is carried out in Spain in a context with 26 destinations, by applying Mixed Logit Models. The results evidence that the variety-seeking behaviour reduces the dissuasive effect of distance.

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A Rh phosphine complex, derived from the Wilkinson’s catalyst, has been immobilized by ion-exchange on the ammonium form of a Al-MCM-41 sample. Ammonium ions have been exchanged by cholamine ions, which act as an amine ligand, and then the Wilkinson’s catalyst has been immobilized by substitution of a phosphine ligand by the anchored amine. This is a novel immobilization procedure, as a ligand, instead of the whole complex, is tethered to the support by ion exchange. The obtained hybrid catalyst has been characterized by Elemental Analysis, DRIFTS and XPS. The quantitative exchange of ammonium by cholamine and coordination of Rh to amines has been observed. Most of the anchored Rh is considered to be coordinated to the ligand tethered to the support and a small proportion seems to be interacting with the protonated ligand or with the support surface. The catalyst has been tested in the hydrogenation of cyclohexene and in the hydroformylation of 1-octene. In the first case the catalyst is active and reusable, while a strong Rh leaching takes place in the second one.

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The Growing Neural Gas model is used widely in artificial neural networks. However, its application is limited in some contexts by the proliferation of nodes in dense areas of the input space. In this study, we introduce some modifications to address this problem by imposing three restrictions on the insertion of new nodes. Each restriction aims to maintain the homogeneous values of selected criteria. One criterion is related to the square error of classification and an alternative approach is proposed for avoiding additional computational costs. Three parameters are added that allow the regulation of the restriction criteria. The resulting algorithm allows models to be obtained that suit specific needs by specifying meaningful parameters.

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Preparation of homogeneous CNT coatings in insulating silica capillary tubes is carried out by an innovative electrochemically-assisted method in which the driving force for the deposition is the change in pH inside the confined space between the inner electrode and the capillary walls. This method represents a great advancement in the development of CNT coatings following a simple, cost-effective methodology.

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This note provides an approximate version of the Hahn–Banach theorem for non-necessarily convex extended-real valued positively homogeneous functions of degree one. Given p : X → R∪{+∞} such a function defined on the real vector space X, and a linear function defined on a subspace V of X and dominated by p (i.e. (x) ≤ p(x) for all x ∈ V), we say that can approximately be p-extended to X, if is the pointwise limit of a net of linear functions on V, every one of which can be extended to a linear function defined on X and dominated by p. The main result of this note proves that can approximately be p-extended to X if and only if is dominated by p∗∗, the pointwise supremum over the family of all the linear functions on X which are dominated by p.

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Jerónimo Quijano fue uno de los ilustres arquitectos destacados del Renacimiento pleno en España. Su obra, la iglesia de Santiago en Orihuela -Alicante- posee una Capilla Mayor renacentista, de carácter funerario, de planta central y adosada a una nave gótica. Destaca su bóveda superior de 4 pares de arcos entrecruzados y revirados. Al ser dobles se reduce la superficie central de plementería y se gana en resistencia. Es de complicada geometría esférica y cuadrada a la vez: bóveda pseudo-vaída (esférica solo hasta los arcos exteriores) y plementería lateral adaptándose a la planta cuadrada. Supone la fusión de la antigüedad clásica con la tradición hispanomusulmana. Como referencia, se estudia sucintamente la Capilla Benavides en Baeza - Jaén-, obra de Andrés de Vandelvira e incluida en el tratado de arquitectura de su hijo Alonso, la cual plantea un gran espacio cuadrado cubierto por una bóveda vaída y reforzada por 4 arcos entrecruzados.

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The development and optimization of electrocatalysts for application in fuel cell systems have been the focus of a variety of studies where core–shell structures have been considered as a promising alternative among the materials studied. We synthesized core–shell nanoparticles of Sn x @Pt y and Rh x @Pt y (Sn@Pt, Sn@Pt2, Sn@Pt3, Rh@Pt, Rh@Pt2, and Rh@Pt3) through a reduction methodology using sodium borohydride. These nanoparticles were electrochemically characterized by cyclic voltammetry and further analyzed by cyclic voltammetry studying their catalytic activity toward glycerol electro-oxidation; chronoamperometry and potentiostatic polarization experiments were also carried out. The physical characterization was carried out by X-ray diffraction, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy. The onset potential for glycerol oxidation was shifted in 130 and 120 mV on the Sn@Pt3/C and Rh@Pt3/C catalysts, respectively, compared to commercial Pt/C, while the stationary pseudo-current density, taken at 600 mV, increased 2-fold and 5-fold for these catalysts related to Pt/C, respectively. Thus, the catalysts synthesized by the developed methodology have enhanced catalytic activity toward the electro-oxidation of glycerol, representing an interesting alternative for fuel cell systems.