Influence of peroxometallic intermediaries present on polyoxometalates nanoparticles surface on the adipic acid synthesis

The cyclohexene oxidation by hydrogen peroxide catalysed by polyoxometalates (POM) has been shown as an adequate green route for the adipic acid synthesis. In this study, it has been demonstrated that POM's salts are effective catalysts for this reaction and how peroxopolyoxometalates intermediaries are the truly responsible species of the POM's salts catalytic activity and solubility. However, the latter can be reduced by calcining the catalyst previously. Polyoxomolybdates salts generally present a higher activity than polyoxotungstenates salts. Finally, it must be remarked the positive effect exerted by the acetic acid stabilising the peroxide of hydrogen against its decomposition.

Direct versus indirect channels: Differentiated loss aversion in a high‐involvement, non‐frequently purchased hedonic product

Purpose – This article aims to investigate whether intermediaries reduce loss aversion in the context of a high-involvement non-frequently purchased hedonic product (tourism packages). Design/methodology/approach – The study incorporates the reference-dependent model into a multinomial logit model with random parameters, which controls for heterogeneity and allows representation of different correlation patterns between non-independent alternatives. Findings – Differentiated loss aversion is found: consumers buying high-involvement non-frequently purchased hedonic products are less loss averse when using an intermediary than when dealing with each provider separately and booking their services independently. This result can be taken as identifying consumer-based added value provided by the intermediaries. Practical implications – Knowing the effect of an increase in their prices is crucial for tourism collective brands (e.g. “sun and sea”, “inland”, “green destinations”, “World Heritage destinations”). This is especially applicable nowadays on account of the fact that many destinations have lowered prices to attract tourists (although, in the future, they will have to put prices back up to their normal levels). The negative effect of raising prices can be absorbed more easily via indirect channels when compared to individual providers, as the influence of loss aversion is lower for the former than the latter. The key implication is that intermediaries can – and should – add value in competition with direct e-tailing. Originality/value – Research on loss aversion in retailing has been prolific, exclusively focused on low-involvement and frequently purchased products without distinguishing the direct or indirect character of the distribution channel. However, less is known about other types of products such as high-involvement non-frequently purchased hedonic products. This article focuses on the latter and analyzes different patterns of loss aversion in direct and indirect channels.

Nuevas perspectivas de la contratación on line de servicios turísticos y paquetes dinámicos de turismo

La implementación de las nuevas tecnologías o TIC’s en el sector turístico se ha visto favorecida, en los últimos años, por las posibilidades que Internet ofrece de poder comprobar instantáneamente la existencia real del proveedor del servicio, la veracidad del servicio prestado o las condiciones en que se presta.. El aumento de la contratación electrónica de servicios turísticos exige que los proveedores de estos servicios y los turistas tengan en cuenta las diferentes normas jurídicas que resultan de aplicación en el ámbito de los servicios de la sociedad de la información, principalmente, la Ley 34/2002, de 11 de julio, de Servicios de la Sociedad de la Información y de Comercio Electrónico (LSSI), las normas reguladoras del consumo, en concreto, el Real Decreto legislativo 1/2007, de 16 de noviembre, por el que se aprueba el texto refundido de la Ley General para la Defensa de los Consumidores y Usuarios y otras leyes complementarias (TRLGDCU) y su modificación por la Ley 3/2014, de 27 de marzo, así como las diferentes normas autonómicas reguladoras del turismo que existen en la actualidad. En definitiva, un estudio detallado de las implicaciones que la contratación electrónica de servicios turísticos supone realizar una descripción legal del régimen jurídico que resulta de aplicación a los diferentes oferentes e intermediarios que intervienen esta nueva modalidad contractual y a los denominados paquetes dinámicos de turismo.

Dimeric assemblies of lanthanide-stabilised dilacunary Keggin tungstogermanates: A new class of catalysts for the selective oxidation of aniline

In this work we demonstrate the efficiency of some dimeric [Ln4(H2O)6(β-GeW10O38)2]12− anions composed of lanthanide-stabilised dilacunary Keggin tungstogermanate fragments (ββ-Ln4, Ln = Dy, Ho, Er, Tm) as heterogeneous catalysts for the organic phase oxidation of aniline with hydrogen peroxide. The results obtained evidence total conversion of aniline at room temperature, as well as full selectivity towards nitrosobenzene, and the catalysts are able to retain both their activity and selectivity after several runs. Peroxopolyoxometalate intermediaries have been identified as the catalytically active species during the aniline-to-nitrosobenzene oxidation process.