Estimating the specific heat capacity of starch-water-glycerol systems as a function of temperature and compositions

Increasing interests in the use of starch as biodegradable plastic materials demand, amongst others, accurate information on thermal properties of starch systems particularly in the processing of thermoplastic starch (TPS), where plasticisers (water and glycerol) are added. The specific heat capacity of starch-water-glycerol mixtures was determined within a temperature range of 40-120degreesC. A modulated temperature differential scanning calorimeter (MTDSC) was employed and regression equations were obtained to predict the specific heat capacity as a function of temperature, water and glycerol content for four maize starches of differing amylose content (0 - 85%). Generally, temperature and water content are directly proportional to the specific heat capacity of the systems, but the influence of glycerol content on the thermal property varied according to the starch type.

A review of ACI recommendations for prevention of plastic cracking

The ACI recommendations for the prevention of cracking of plastic concrete attempt to eliminate such cracking by ensuring that the rate of evaporation from unprotected concrete surfaces does not exceed the estimated rate of bleed water production. The current recommendations, however do not account for the large scatter of the underlying experimental evaporation data nor the effect of altitude on evaporation rate. Ignoring the scatter of the evaporation data frequently leads to an unacceptably high probability that the evaporation rate will exceed the bleed rate. Ignoring the effect of altitude leads to similar high probabilities, but in only a comparatively small number of cases. Simple modifications of the ACI recommendations are suggested that can account for both effects. However; insufficient data on the variability of bleed rates are currently available to allow the scatter of the evaporation data to be accounted for completely.

Suctions, fracture energy, and plastic cracking of cement mortar and concrete

Plastic cracking of cement mortar and concrete is primarily attributable to desiccation by evaporation from unprotected surfaces. This causes high suctions (negative pressures) to develop in the pore water adjacent to these surfaces. Dissolved salts in the pore water can also contribute significantly to suctions. Quantitative expressions are available for all of the components of the total suction. The development of suctions over time is illustrated by the results of desiccation tests conducted on cement mortars, supplemented by data from the literature. It is shown that ambient conditions conducive to plastic cracking can arise almost anywhere, but that the extremely high suctions that develop in mature cement mortar and concrete do not imply that compression failures should occur A high value of fracture energy is derived from data from the desiccation tests that implies that plastic cracking is characterized by a significant zone of plastic straining or microcracking.

Crack depths in desiccating plastic concrete

The depths of cracks in desiccating plastic concrete are estimated by considering the effects of the suction (negative pore pressure) associated with desiccation and applying five failure models derived from fracture, theories combined with theories drawn from geotechnical engineering under the assumption that plastic concrete is a frictional particulate material. The estimated crack depths vary with the depth of desiccation, the suction profile, and a small number of material parameters that depend on the model adopted and are comparatively easy to estimate accurately. Four of the models predict excessively large crack depths. The fifth, however, predicts shallower crack depths that increase with the age of the concrete and are consistent with those of analogous desiccation cracks in coal mine tailings. It thus offers a relatively robust method of estimating the depth of desiccation cracks. Confirmation of this with data for plastic concrete is clearly desirable but not possible at present.

Yield functions for porous materials with cubic symmetry using different definitions of yield

Plastic yield criteria for porous ductile materials are explored numerically using the finite-element technique. The cases of spherical voids arranged in simple cubic, body-centred cubic and face-centred cubic arrays are investigated with void volume fractions ranging from 2 % through to the percolation limit (over 90 %). Arbitrary triaxial macroscopic stress states and two definitions of yield are explored. The numerical data demonstrates that the yield criteria depend linearly on the determinant of the macroscopic stress tensor for the case of simple-cubic and body-centred cubic arrays - in contrast to the famous Gurson-Tvergaard-Needleman (GTN) formula - while there is no such dependence for face-centred cubic arrays within the accuracy of the finite-element discretisation. The data are well fit by a simple extension of the GTN formula which is valid for all void volume fractions, with yield-function convexity constraining the form of the extension in terms of parameters in the original formula. Simple cubic structures are more resistant to shear, while body-centred and face-centred structures are more resistant to hydrostatic pressure. The two yield surfaces corresponding to the two definitions of yield are not related by a simple scaling.

Biodegradable starch-based nanocomposite packaging materials

Polymer processing experiments have been conducted with a twin screw extruder. Different formulations of starch-based nanocomposites are being tested in a pilot scale film blowing tower. The physical properties of different starch-based films have been examined with thermal and mechanical analysis and X-ray diffraction. The results show that the addition of organoclay significantly improves both the processing and tensile properties over the original starch blends. The mechanical and thermal properties of the blends are also sensitive to the scale the clay particles are dispersed.

Performance of some unbound roadbase materials from Queensland = Performance de certains matériaux granulaires de base du Queensland

This paper summarises recent investigations into characterisation and performance of unbound roadbase materials carried out by Main Roads, Queensland (QDMR), on road projects across the state. Performance based tests such as the Repeated Load Triaxial (RLT) and the Wheel Tracker (WT) are the primary tools which are increasingly used by QDMR to overcome the limitations of simple specification type tests. This paper shows the inadequacy of current specification tests to rank material performance. The performance based tests show that the properties of the coarse aggregate alone are inadequate for sound performance; enable the contribution to mechanical behaviour by plastic fines with high matric suction to be assessed,- further, and facilitates ranking of material behaviour. Simple shakedown analyses undertaken yield similar material rankings. Finally, some materials from the performance based characterisation are compared with Falling Weight Deflectometer (FWD) in-service pavement performance data.