Petrology and geochemistry of the Bandas del Sur Formation, Las Canadas Edifice, Tenerife (Canary Islands)

The Bandas del Sur Formation preserves a Quaternary extra-caldera record of central phonolitic explosive volcanism of the Las Canadas volcano at Tenerife. Volcanic rocks are bimodal in composition, being predominantly phonolitic pyroclastic deposits, several eruptions of which resulted in summit caldera collapse, alkali basaltic lavas erupted from many fissures around the flanks. For the pyroclastic deposits, there is a broad range of pumice glass compositions from phonotephrite to phonolite. The phonolite pyroclastic deposits are also characterized by a diverse, 7-8-phase phenocryst assemblage (alkali feldspar + biotite + sodian diopside + titanomagnetite + ilmenite + nosean-hauyne + titanite + apatite) with alkali feldspar dominant, in contrast to interbedded phonolite lavas that typically have lower phenocryst contents and lack hydrous phases. Petrological and geochemical data are consistent with fractional crystallization (involving the observed phenocryst assemblages) as the dominant process in the development of phonolite magmas. New stratigraphically constrained data indicate that petrological and geochemical differences exist between pyroclastic deposits of the last two explosive cycles of phonolitic volcanism. Cycle 2 (0.85-0.57 Ma) pyroclastic fall deposits commonly show a cryptic compositional zonation indicating that several eruptions tapped chemically, and probably thermally stratified magma systems. Evidence for magma mixing is most widespread in the pyroclastic deposits of Cycle 3 (0.37-0.17 Ma), which includes the presence of reversely and normally zoned phenocrysts, quenched mafic glass blebs in pumice, banded pumice, and bimodal to polymodal phenocryst compositional populations. Syn-eruptive mixing events involved mostly phonolite and tephriphonolite magmas, whereas a pre-eruptive mixing event involving basaltic magma is recorded in several banded pumice-bearing ignimbrites of Cycle 3. The periodic addition and mixing of basaltic magma ultimately may have triggered several eruptions. Recharge and underplating by basaltic magma is interpreted to have elevated sulphur contents (occurring as an exsolved gas phase) in the capping phonolitic magma reservoir. This promoted nosean-hauyne crystallization over nepheline, elevated SO3 contents in apatite, and possibly resulted in large, climatologically important SO2 emissions.

Palynostratigraphy of Ordovician strata, Canning Basin, Western Australia. Part Two: chitinozoans and biostratigraphy

This second and concluding part of a comprehensive palynological study of the Lower to Middle Ordovician succession of the central-northeastern Canning Basin completes the systematic documentation of the palynomorphs, i.e., chitinozoans, and formulates a palynostratigraphic zonation scheme embracing all three constituent formations of this investigation, viz., the Willara, Goldwyer, and Nita formations. A total of 21 species of chitinozoans (five genera), detailed systematically herein, are identified. Although chitinozoan recovery per sample proved variable, the following species occur fairly persistently in the productive samples: Belonechitina micracantha, Conochitina subcylindrica, C. poumoti, C. langei, Calpichitina windjana, and Rhabdochitina magna. Five, stratigraphically successive acritarch/prasinophyte assemblage zones, ranging in age from early Arenig through late Llanvirn, are proposed as follows (ascending order): Athabascaella rossii Assemblage Zone (corresponding to the lower Willara Formation; and dated as early-mid Arenig); Comasphaeridium setaricum Assemblage Zone (upper Willara and lowermost Goldwyer; late Arenig-earliest Llanvirn); Sacculidium aduncum Assemblage Zone (lower Goldwyer; early Llanvirn); Aremorica-nium solaris Assemblage Zone (middle and lower upper Goldwyer; mid Llanvirn); and Dactylofusa striatogranulata Assemblage Zone (upper Goldwyer and lower Nita; late Llanvirn). Four chitinozoan assemblage zones, stratigraphically coinciding (within the limits of sampling) with the acritarch/prasinophyte zones, comprise (in ascending order): Lagenochitina combazi Assemblage Zone (equivalent to the A. rossii and L. heterorhabda Assemblage Zones); Conochitina langei Assemblage Zone; Conocbitina subcylindrica Assemblage Zone; and Belonecbitina micracantha Assemblage Zone. Chronostratigraphic assignments are based principally on associated conodont and graptolite faunas. Whereas the acritarch/prasinophyte zones bear scant similarities to those established globally elsewhere, the chitinozoan zones show significant affiliations with those known from Laurentia.