40Ar/39Ar dating of Mn-iron ore of the Sapecado Mine, Qadrilatero Ferrifero, Brazil

The SW region of Amazonian craton presents policyclic evolution between 1.80-1.00 Ga and is comprised of the Rio Negro-Juruena, Rondoniana and Sunsas Provinces. The evolution of this region has being characterized by four orogens: Alto Jauru (1.79-1.74 Ga), Cachoeirinha (1.58-1.52 Ga), Suíte Santa Helena (1.45-1.42 Ga) e Sunsas/Aguapeí (1.0-0.9 Ga). The Alto Jauru orogen consists of TTG gneissic associations, greenstone sequences and intrusive granitoids origined in volcanic arc setting. Eight 40Ar/39Ar step-heating analyses were carried out in minerals (biotiteand hornblende) to investigate the thermal history and crustal evolution of this region. From the Alto Jauru orogen was sampled the gneiss banded and two biotite grains provide large dispersion of apparent ages, suggesting heterogenity in reservoir of the argon. Apparent age diagram yielded integrated ages of 1472 ± 6 Ma, interpreted as minimum ages of regional cooling episode. Three analyses of hornblende present ages varing from 1310 to 1400 Ma, possibly because smaller grain size become more susceptible to argon loss. 40Ar/39Ar step-heating methodology applied on biotite of pyroclastic tuff (U-Pb age about 1758 ± 7 Ma) presented integrated age of 1507 ± 7 Ma. The results found for this terrane demonstrated a geochronological correlation with metamorphic process linked Cachoeirinha orogen. Biotite and hornblende grains separates from granite and a tonalite origined during Cachoeirinha orogen were analyzed and the apparent age diagrams indicated well-defined plateau ages of 1520-1540 Ma. Biotite grains from a granitic sample were analized, and integrated ages about 1526 ± 2 Ma were obtained due argon loss in the initial steps. Thermochronologic history of SW region Amazonian craton is coherent with regional policyclic events and 40Ar/39Ar ages here presented probably correspond to regional cooling period of Cachoeirinha orogen.

Ultrastructure, aggregation-state, and crystal growth of biogenic nanocrystalline sphalerite and wurtzite

In this study, we investigated the size, submicrometer-scale structure, and aggregation state of ZnS formed by sulfate-reducing bacteria (SRB) in a SRB-dominated biofilm growing on degraded wood in cold (Tsimilar to8degreesC), circumneutral-pH (7.2-8.5) waters draining from an abandoned, carbonate-hosted Pb-Zn mine. High-resolution transmission electron microscope (HRTEM) data reveal that the earliest biologically induced precipitates are crystalline ZnS nanoparticles 1-5 nm in diameter. Although most nanocrystals have the sphalerite structure, nanocrystals of wurtzite are also present, consistent with a predicted size dependence for ZnS phase stability. Nearly all the nanocrystals are concentrated into 1-5 mum diameter spheroidal aggregates that display concentric banding patterns indicative of episodic precipitation and flocculation. Abundant disordered stacking sequences and faceted, porous crystal-aggregate morphologies are consistent with aggregation-driven growth of ZnS nanocrystals prior to and/or during spheroid formation. Spheroids are typically coated by organic polymers or associated with microbial cellular surfaces, and are concentrated roughly into layers within the biofilm. Size, shape, structure, degree of crystallinity, and polymer associations will all impact ZnS solubility, aggregation and coarsening behavior, transport in groundwater, and potential for deposition by sedimentation. Results presented here reveal nanometer- to micrometer-scale attributes of biologically induced ZnS formation likely to be relevant to sequestration via bacterial sulfate reduction (BSR) of other potential contaminant metal(loid)s, such as Pb2+, Cd2+, As3+ and Hg2+, into metal sulfides. The results highlight the importance of basic mineralogical information for accurate prediction and monitoring of long-term contaminant metal mobility and bioavailability in natural and constructed bioremediation systems. Our observations also provoke interesting questions regarding the role of size-dependent phase stability in biomineralization and provide new insights into the origin of submicrometer- to millimeter-scale petrographic features observed in low-temperature sedimentary sulfide ore deposits.

The role of advanced DEM based modelling tools in increasing comminution energy efficiency

Particle breakage is an essential part of mineral processing. The aim is to reduce run of mine mineral ore to an optimal size for liberating target minerals and for subsequent recovery by separation processes such as flotation. This size reduction is typically accomplished in a series of stages in a grinding circuit tailored to the properties of the particular mine ore. Commonly this involves two or more classes of equipment starting with crushers, followed by SAG mills and then sometimes ball mills. Occasionally, high pressure grinding rolls or other novel devices are substituted. Broadly, energy consumption increases and energy efficiency decreases with the fineness of the material produced by each piece of equipment.