Holiday house, Judge House, Camp Island

View from ocean to holiday house pavilions.

Holiday houses, Judge House, Camp Island

As seen from hill behind.

Covered walkway, Judge House, Camp Island

View past bedroom pavilions, through the covered walkway to living room pavilion.

Judge House, Camp Island

Caretakers house in foreground, holiday house and ocean beyond.

Covered walkway, Judge House, Camp Island

View down covered walkway with kitchen pavilion on the left and the living room pavilion on the right.

Judge House, Camp Island

Caretakers house in foreground, holiday house and ocean beyond.

Owner's residence and guest house, Judge House, Camp Island

View over owner's residence to holiday house pavilions and ocean beyond.

The crosslinking mechanism in gamma irradiation of polyarylsulfone: Evidence for Y-links

Measurements of molecular weights, soluble fractions and examination of NMR spectra of bisphenol-A polysulfone, after gamma irradiation in vacuum at 150 degrees C were used to elucidate the mechanism of crosslinking. Excellent agreement was obtained between G(S) and G(X) determined from measurements above and below the gel dose when a Y-linking mechanism was assumed, whereas poor agreement was obtained when an H-link mechanism was assumed, which is the mechanism normally believed to be responsible for crosslinking. New resonances were observed in the C-13 NMX spectra of the irradiated polymer which were consistent with the formation of Y-links involving phenylene units in the backbone chain. (C) 1998 John Wiley & Sons, Ltd.