Non-linear analysis of piezolaminated structures

In the recent years the study of smart structures has attracted significant researchers, due to their potential benefits in a wide range of applications, such as shape control, vibration suppression, noise attenuation and damage detection. The applications in aerospace industry are of great relevance, such as in active control of airplane wings, helicopter blade rotor, space antenna. The use of smart materials, such as piezoelectric materials, in the form of layers or patches embedded and/or surface bonded on laminated composite structures, can provide structures that combine the superior mechanical properties of composite materials and the capability to sense and adapt their static and dynamic response, becoming adaptive structures. The piezoelectric materials have the property of generate electrical charge under mechanical load or deformation, and the reverse, applying an electrical field to the material results in mechanical strain or stresses.

Study of sewage sludge aimed at agricultural soil amendment by thermogravimetric analysis and fourier-transform infrared spectroscopy

Thermal degradation and gaseous products evolving from the pyrolysis of sewage sludge, aimed at agricultural soil amendment, were investigated using Thermogravimetric Analysis in conjunction with Fourier Transform Infrared Analysis (TG-FTIR). The materials were studied in temperatures ranging from 30 to 800 ºC. Furthermore infrared spectra of sewage sludge samples were performed as a complementary technique. In parallel the sewage sludge was spiked with ibuprofen in order to test whether the mentioned techniques are able to detect the drug. Thermal analysis showed the range of 200-400ºC as the most characteristic for weight loss, corresponding with the organic matter volatilization, while the range of 500-800ºC was also characteristic and due to the volatilization of carbonates. On the other hand, ibuprofen-spiking tests identified at temperature range (150-250ºC) where the compound totally volatilizes, therefore, in this work, the detection of ibuprofen by TGA was established for concentrations higher than 0.5 g/kg sludge, concentration 102 times higher than the concentrations measured by other authors in regular sewage sludge (Martín, et al., 2010). A correlation has been found between the ibuprofen concentrations in the sludge and the intensity of the absorption bands, both for FT-IR spectra at the maximum emission temperature for ibuprofen (232ºC) as for the FT-IR spectra of the non-pyrolyzed samples.