High-resolution seismic reflection investigation of gas accumulation and seepage in the tidal channels of the Ria of Aveiro barrier lagoon (Portugal)

O metano é um gás de estufa potente e uma importante fonte de energia. A importância global e impacto em zonas costeiras de acumulações e escape de gás metano são ainda pouco conhecidas. Esta tese investiga acumulações e escape de gás em canais de maré da Ria de Aveiro com dados de cinco campanhas de reflexão sísmica de alta resolução realizadas em 1986, 1999, 2002 e 2003. Estas incluem três campanhas de Chirp (RIAV99, RIAV02 e RIAV02A) e duas campanhas de Boomer (VOUGA86 e RIAV03). O processamento dos dados de navegação incluíram filtros de erros, correcções de sincronização de relógios de sistemas de aquisição de dados, ajuste de “layback” e estimativa da posição de “midpoint”. O processamento do sinal sísmico consistiu na correcção das amplitudes, remoção de ruído do tipo “burst”, correcções estáticas, correcção do “normal move-out”, filtragem passabanda, desconvolução da assinatura e migração Stolt F-K. A análise da regularidade do trajecto de navegação, dos desfasamentos entre horizontes e dos modelos de superfícies foi utilizada para controlo de qualidade, e permitiu a revisão e melhoria dos parâmetros de processamento. A heterogeneidade da cobertura sísmica, da qualidade do sinal, da penetração e da resolução, no seu conjunto constrangeram o uso dos dados a interpretações detalhadas, mas locais, de objectos geológicos da Ria. É apresentado um procedimento para determinar a escolha de escalas adequadas para modelar os objectos geológicos, baseado na resolução sísmica, erros de posicionamento conhecidos e desfasamentos médios entre horizontes. As evidências de acumulação e escape de gás na Ria de Aveiro incluem turbidez acústica, reflexões reforçadas, cortinas acústicas, domas, “pockmarks” e alinhamentos de “pockmarks” enterradas, horizontes perturbados e plumas acústicas na coluna de água (flares). A estratigrafia e a estrutura geológica controlam a distribuição e extensão das acumulações e escape de gás. Ainda assim, nestes sistemas de baixa profundidade de água, as variações da altura de maré têm um impacto significativo na detecção de gás com métodos acústicos, através de alterações nas amplitudes originais de reflexões reforçadas, turbidez acústica e branqueamento acústico em zonas com gás. Os padrões encontrados confirmam que o escape de bolhas de gás é desencadeado pela descida da maré. Há acumulações de gás em sedimentos Holocénicos e no substrato de argilas e calcários do Mesozóico. Evidências directas de escape de gás em sondagens em zonas vizinhas, mostraram gás essencialmente biogénico. A maioria do gás na área deve ter sido gerado em sedimentos lagunares Holocénicos. No entanto, a localização e geometria de estruturas de escape de fluidos em alguns canais de maré, seguem o padrão de fracturas do substrato Mesozóico, indicando uma possível fonte mais profunda de gás e que estas fracturas funcionam como condutas preferenciais de migração dos fluidos e exercem um controlo estrutural na ocorrência de gás na Ria.

Calibration and validation of hydrodynamic, salt and heat transport models for Ria de Aveiro lagoon (Portugal)

Ria deAveiro is a very complex shallow water coastal lagoon located on the northwest of Portugal. Important issues would be left unanswered without a good understanding of hydrodynamic and transport processes occurring in the lagoon. Calibration and validation of hydrodynamic, salt and heat transport models for Ria de Aveiro lagoon are presented. The calibration of the hydrodynamic model was performed adjusting the bottom friction coefficient, through the comparison between measured and predicted time series of sea surface elevation for 22 stations. Harmonic analysis was performed in order to evaluate the model's accuracy. To validate the hydrodynamic model measured and predicted SSE values were compared for 11 stations, as well as main flow direction velocities for 10 stations. The salt and heat transport models were calibrated comparing measured and predicted time series of salinity and water temperature for 7 stations, and the RMS of the difference between the series was determined. These models were validated comparing the model results with an independent field data set. The hydrodynamic and the salt and heat transport models for Ria de Aveiro were successfully calibrated and validated. They reproduce accurately the barotropic flows and can therefore adequately represent the salt and heat transport and the heat transfer processes occurring in Ria deAveiro.

Lagrangian transport of particles in Ria de Aveiro lagoon, Portugal

A two-dimensional vertically integrated hydrodynamic model coupled to a particle tracking model is applied to study the dispersion processes and residence time in Ria de Aveiro lagoon (Portugal). The only dispersion process that is considered in this study is the advection, according to the main characteristics of the local hydrodynamic. The particle tracking model computes the particles position at each time step, using a fourth-order Runge-Kutta integration method. The dispersion of passive particles released along the lagoon and in critical areas are studied in this work. The residence time is also determined for the entire lagoon. The results show that the mixture between particles coming from different channels of the lagoon is negligible in a time scale higher than 2 tidal cycles. The residence time for the lagoon central area is about 2 days, revealing a strong marine influence in this area. At the upper reaches of the channels were found values higher than 2 weeks.

Biology, ecology, population dynamics and distribution of metals in Sepia officinalis on a typical estuarine coastal lagoon - Ria de Aveiro

The common cuttlefish, Sepia officinalis, is a necto-benthic cephalopod that can live in coastal ecosystems, with high influence of anthropogenic pressures and thus be vulnerable to exposure to various types of contaminants. The cuttlefish is a species of great importance to the local economy of Aveiro, considering the global data of catches of this species in the Ria de Aveiro. However, studies on this species in Ria de Aveiro are scarce, so the present study aims to fill this information gap about the cuttlefish in the Ria de Aveiro. The cuttlefish enters Ria de Aveiro in the spring and summer to reproduce, returning to deeper waters in the winter. In terms of abundance, the eastern and center regions of the lagoon, closer to the sea, showed the highest values of abundance, while the northern and southern regions of the main channel had the lowest abundance. This fact may be related to abiotic factors, as well as depth, salinity and temperature. In the most southern point of the Ria de Aveiro (Areão) no cuttlefish was caught. This site had the lowest values of salinity and depth. The cuttlefish has an allometric the females being heavier than males to mantle lengths greater than 82.4 mm. Males reach sexual maturity first than females. In Ria de Aveiro in a generation of parents was found. The cuttlefish, presents itself as opportunistic predators, consuming a wide variety of prey from different taxa. The diet was similar in different sampling locations observing significant differences for the seasons. S. officinalis was captured at 10 sites in the Ria de Aveiro with different anthropogenic sources of contamination. Thus, levels of metals analyzed were similar at all sampling sites, with the exception of a restricted area, Laranjo, which showed higher values. The cuttlefish has the ability to accumulate metals in your body. The levels of Fe, Zn, Cu, Cd, Pb and Hg found in the digestive gland and mantle reflect a differential accumulation of metals in the tissues. This accumulation is related to the type and function of tissue analyzed and the type of metal analysis (essential and non-essential). The metal concentrations in the digestive gland are higher than in the mantle, with the exception of mercury. This may be due to the high affinity of the mantle for the incorporation of methylmercury (MeHg), the most abundant form of mercury. The accumulation of metals can vary over a lifetime, depending on the metal. The concentrations of Zn, Cd and Hg increases throughout life, while Pb decreases and essential metals such as Fe and Cu remain constant. The data collected suggest that the cuttlefish (Sepia officinalis) can be used as a bioindicator of environmental contamination for some metals.

European life project: a global strategy for the responsible use of a coastal lagoon: a case study from Portugal

Rin de Aveiro is a coastal lagoon located at the Central Region of Portugal subjected to the influence of the tides, resulting in a set of characteristic biotopes favouring anthropic and natural processes. Once managed and controlled correctly, each of these biotopes will allow simultaneously the biodiversity and integration in the making of the wetland landscape. In 1998, one of the final conclusions of the "MARIA" Demonstration Programme for the Integrated Management of Ria de Aveiro was that the poor current state of the environment area resulted from a set of interrelated factors. The Programme selected four (4) pilot-projects towards the integrated management of the lagoon biotopes as possible scenarios for an intervention. This selection was based in criteria related to environmental priorities and the maintenance of traditional economic activities in the region. The idea of choosing projects that would involve the whole geographic space of the Ria, without forgetting the other important themes interrelated with the Management Structure, emerged as a relevant aspect for their definition. Thus, and as a first test of this Management Structure functionality, the following task forces were put forward: Recovery and valorisation of the piers; Recovery of the former salt pans; Management of the agricultural fields of Baixo-Vouga; Implementation of measures for the classification of the Protected Landscape Area of the River Caster Mouth. This payer will report the main results of these pilot-projects attained during their first year period, especially the intervention strategies defined by the Partnership created for this aim.

The disappearing of palheiros in Aveiro lagoon

Palheiros are traditional timber constructions existing in the littoral centre region of Portugal. This is particularly the case of the Aveiro lagoon region where for many years many such constructions have existed. They were originally built to store working tools related with lagoon activity (fishing and sea salt extraction) and to give shelter for the fishermen during the fishing season. These constructions were built with superimposed veneers in vertical or horizontal directions. Since they are mostly located near the sea, they have started to be used as holiday houses and are often painted in vivid colours. Most of these buildings are being replaced by concrete constructions, since their preservation state is rather unsatisfactory or simply because there is a need to increase their size. Additionally, little knowledge about the possibilities of maintenance and building in timber structures exists. In some cases, although the structures were changed from timber to concrete, the exterior appearance of the palheiros remains the same, which might be interesting from the pictorial point of view but it isn’t certainly from a heritage preservation perspective. However in many other situations, they are being substituted by “modern” constructions that were not valuable in any of the previous viewpoints. Fortunately, there are also cases where palheiros have been preserved and remain in good condition. For how long these examples will remain is certainly the major question that must be answered since these are only on the dependence of owner’s will and not based on local authorities concern. A consciousness of local authorities and citizens is mandatory in order to preserve this heritage because it is perfectly possible to preserve the traditional constructions offering all the comfort of modern houses. Keywords: timber construction, vernacular construction, preservation.

Evaluation of the nutrient inputs to a coastal lagoon: the case of the Ria de Aveiro, Portugal

The Ria de Aveiro estuary-coastal lagoon system of northern Portugal is estimated to currently receive mean annual influxes of total nitrogen (N) and total phosphorus (P) of c. 6118 t y−1 and 779 t y−1, respectively, from its influent rivers. In low summer flows the mean N and P fluxes decrease to c. 10% of the annual average. The sewage contribution to the inland-derived N load on an annual basis is c. 5% but, during the summer low flow conditions, the sewage component increases to c. 65% of the total river loading. The sewage contribution to the inland-derived P load on an annual basis is c. 11% but, during the dry season, it is 1.2 times larger than the river-derived flux. The construction of a regional sewer system linked to a submarine outfall, due for completion in 2005, is expected to lead to a reduction in nutrient fluxes from inland to the lagoon of c. 15% for N and c. 26% for P relative to the present values. While this system will reduce the nutrient loading in the upper reaches of the lagoon, an increase in nutrients derived from the ocean is anticipated, due to the proximity of the outfall to the inlet.

An evaluation of trace metal distribution, enrichment factors and risk in sediments of a coastal lagoon (Ria de Aveiro, Portugal)

This paper describes a sediment survey undertaken to unravel patterns of distribution and dispersion of trace metals in an Iberian Peninsula northwestern coastal lagoon (Ria de Aveiro). Cadmium, lead, chromium, copper and zinc were analyzed in bottom sediments. Geochemical normalization is performed and two different regression models for each metal versus aluminum are tested and compared using the respective enrichment factors (EF), an estimation of the relative importance of anthropogenic contributions to the studied sediments. Mean sediment quality guideline quotients (mSQGQ) are used to evaluate sediment quality and associated potential risk to biota with effects range low as empirical sediment quality guideline (SQG) in the basis for mSQGQ calculation. Additionally, the geoaccumulation index is calculated to compare studied sediment levels to global baseline levels. The application of SQGs revealed insufficient characterization capability, especially when contrasted to EF calculated from the regression methods. These pointed a mildly enriched system with localized “hot spot” areas. Therefore, it can be considered that bottom sediments in the Ria de Aveiro system are in their majority unpolluted, zinc being the only metal of concern, presenting enrichment in all four main channels. The major rivers outlets (Caster, Antuã, and Vouga) constitute point sources, thus presenting potential risk for biota. Yet, the strong tidal influence creates a damping effect by efficiently redistributing sediment bound metals.

Inputs from a mercury-contaminated lagoon: impact on the nearshore waters of the Atlantic Ocean

Ria de Aveiro, a Portuguese coastal lagoon that exchanges water with the Atlantic Ocean, received the effluent from a chlor-alkali industry for over 50 years; consequently several tons of mercury had been buried in the sediments of an inner basin. To assess the importance (and seasonal variation) of the lagoon waters as carriers of mercury to the nearby coastal area, we measured total mercury levels in several compartments: in surface sediments, in surface and deep waters (including dissolved and particulate matter!, and in biota. Dissolved (reactive and total) mercury concentrations both in surface and deep waters were low (<1 to 15 ng L '). Mean mercury values in suspended particulate matter varied hetween 0.2 and 0.6 jxg g ' and in sediments between 1 and 9 ng g '. Aquatic organisms displayed levels below regulatory limits but exhibited some bioaccumulation of mercury, with concentrations ranging from 0.05 to 0.8 ^ig g ' Idry weight (dw)|. No seasonal pattern was found in this study for mercury-related determinations. Levels found in the estuary mouth during ebb tide provide evidence for the transport of mercury to the coastal zone. No significant changes in the partition of mercury between dissolved and particulate phases were found in the coastal waters in comparison with the values found in the estuary mouth. In spite of the high levels of mercury found inside some areas of the lagoon, the wide web of islands and channels allows some spreading of contaminants before they reach the coastal waters. Moreover, the low efficiency of local marine sediments in trapping mercury contributes to a dilution of mercury transported in suspended particulate matter over a broader area, reducing the impact in the nearby manne coastal zone.

Online marketing internationally: Bizpartner and the parallel cases of Portugal and Greece

This report is the result of the curricular internship carried out in Bizpartner, a company from Slovakia, for the Master’s degree in Languages and Business Relations. The objective of this report is to present the activities developed during the internship, as well as a brief study of how Bizpartner internationalizes and the different results obtained from Portugal, Greece and the United Kingdom. There is a contextualization of Slovakia, Bizpartner and Internationalization, followed by the specific cases of Portugal, Greece and the United Kingdom. Finally, there is a reflection on all the work done, attempting to relate the internship with the knowledge acquired during the course.