Wavelength Dependence of Raman Enhancement from Gold Nanorod Arrays: Quantitative Experiment and Modeling of a Hot Spot Dominated System

Surface-enhanced Raman scattering (SERS) spectra from molecules adsorbed on the surface of vertically aligned gold nanorod arrays exhibit a variation in enhancement factor (EF) as a function of excitation wavelength that displays little correlation with the elastic optical properties of the surface. The key to understanding this lack of correlation and to obtaining agreement between experimental and calculated EF spectra lies with consideration of randomly distributed, sub-10 nm gaps between nanorods forming the substrate. Intense fields in these enhancement “hot spots” make a dominant contribution to the Raman scattering and have a very different spectral profile to that of the elastic optical response. Detailed modeling of the electric field enhancement at both excitation and scattering wavelengths was used to quantitatively predict both the spectral profile and the magnitude of the observed EF.

EXPERIMENTAL STUDIES OF THE MNF PHOTORESONANT EXCITATION SOFT-XRL SCHEME

Photoresonant excitation has been examined as a mechanism for enhancing the maximum gain achievable on a H-like recombination scheme. Modelling of the system, using the MED101/NIMP package, has shown that the photoresonant excitation of the 1s-3p (Ly(beta)) transition at 12.644 angstrom in a H-like fluorine plasma by a Be-like manganese transition at 12.643 angstrom offers the possibility of considerable gain enhancement on the 3d-2p Balmer alpha at 80.91 angstrom over the simple H-like system. Some experimental evidence for a transitory increase in intensity on the Balmer-alpha has been obtained for a fluorine-coated C-fiber system pumped by irradiating a manganese stripe in close proximity to the fiber.

Multi-access communication system in a highly reverberant environment

We investigate by numerical EM simulation the potential communication channel capacity of a reverberant environment using the time reversal approach, excited at 2.4 GHz by ON-OFF keyed RF pulse excitation. It is shown that approximately 725 1.25MHz propagation channels can be allocated with the cavity contains a 4×4 ? or 1×1 ? LOS obstruction positioned between the transceiver antenna and the time reversal unit. Furthermore the results show that two co-located transceiver dipoles separated by a spacing of 3?/4 can successfully resolve a 10ns pulse. Our findings suggest that different independent channels with identical operating frequency can be realized in an enclosed environment such as ventilation duct or underground tunnel. This suggests that there is a possibility of implementing a parallel channel radio link with the minimum inter-antenna spacing of 3?/4 between the transceivers in a rich multipath environment. © 2012 IEEE.