Highly Sensitive, Uniform, and Reproducible Surface-Enhanced Raman Spectroscopy from Hollow Au-Ag Alloy Nanourchins

A hierarchical nanoparticle strategy to simultaneously gain super Raman signal amplification, high uniformity, and reproducibility is presented. Using hollow Au-Ag alloy nanourchins, an ultrahigh sensitivity, e.g., down to 1 fM concentrations for DEHP molecule is obtained. A small standard deviation of <10% is achieved by simply dropping and evaporating sub-100 nm nanourchins onto a substrate.

Circular polarisation frequency selective surface operating in Ku and Ka band

Single and double layer frequency selective surfaces (FSS) for Circular polarization (CP) operation were designed. The designed FSS provide reflection in the Ku-band (11.7 – 12.75 GHz) and transmission in the Ka-band (17.3 – 20.2 GHz). CP is conserved in each of the bands. For the double layer design over the Ku-band the reflection loss was less than 0.05 dB for TE and TM polarizations while the axial ratio was below 0.2 dB. Over the Ka-band transmission loss and axial ratio were each less than 0.25 dB.

Linear to Circular Polarization Reflector with Transmission Band

A frequency selective surface (FSS) which can be utilized as a diplexer for circular polarization (CP) applications is proposed. The structure consists of two dipole-based FSS placed parallel to each other. The dipoles in one array are rotated by 90° with respect to those in the other. For an angle of incidence of 45° at one frequency band the structure allows a CP signal to be transmitted while at a further band it converts a linearly polarized (LP) signal to CP upon reflection. Full-wave simulation results validated the concept.

Optimised extraction of heterocyclic aromatic amines from blood using hollow fibre membrane liquid-phase microextraction and triple quadrupole mass spectrometry

Heterocyclic aromatic amines (HCA) are carcinogenic mutagens formed during cooking of proteinaceous foods, particularly meat. To assist in the ongoing search for biomarkers of HCA exposure in blood, a method is described for the extraction from human plasma of the most abundant HCAs: 2-Amino-1-methyl-6-phenylimidazo(4,5-b)pyridine (PhIP), 2-amino-3,8-dimethylimidazo[4,5-f]quinoxaline (MeIQx) and 2-amino-3,4,8-trimethylimidazo[4,5-f]quinoxaline (4,8-DiMeIQx) (and its isomer 7,8-DiMeIQx), using Hollow Fibre Membrane Liquid-Phase Microextraction. This technique employs 2.5 cm lengths of porous polypropylene fibres impregnated with organic solvent to facilitate simultaneous extraction from an alkaline aqueous sample into a low volume acidic acceptor phase. This low cost protocol is extensively optimised for fibre length, extraction time, sample pH and volume. Detection is by UPLC-MS/MS using positive mode electrospray ionisation with a 3.4 min runtime, with optimum peak shape, sensitivity and baseline separation being achieved at pH 9.5. To our knowledge this is the first description of HCA chromatography under alkaline conditions. Application of fixed ion ratio tolerances for confirmation of analyte identity is discussed. Assay precision is between 4.5 and 8.8% while lower limits of detection between 2 and 5 pg/mL are below the concentrations postulated for acid-labile HCA-protein adducts in blood.

Crush responses of composite cylinder under quasi-static and dynamic loading

Despite the abundance of studies investigating the performance of composite structures under crush loading, disagreement remains in the literature regarding the effect of increased strain rate on the crush response. This study reports an experimental investigation of the behaviour of a carbon-epoxy composite energy absorber under static and dynamic loading with a strain rate of up to 100s^-1. Consistent damage modes and measured force responses were obtained in samples tested under the same strain rate. The energy absorption was found to be independent of strain rate as the total energy absorption appeared to be largely associated with fibre-dominated fracture, which is independent of strain rate within the studied range. The results from this study are beneficial for the design of energy absorbing structures.

Linear-to-Circular Polarization Reflector With Transmission Band

A new class of polarizing surface is proposed that in a given frequency band can reflect incident linearly polarized waves with circular polarization (CP) while at other frequencies is transparent allowing incident waves to transmit unaffected. The proposed structure consists of two parallel anisotropic frequency selective surfaces (FSSs) that independently interact with TE or TM waves, respectively. The FSSs are designed to, respectively, transmit TE and TM waves within the same transmission frequency range, so that the combined structure is transparent to all polarizations in this band. Likewise, the two arrays are designed to, respectively, reflect TE and TM incident waves in a common reflection band, so that all polarizations are fully reflected in this range; if the separation of the two arrays is such that the TE and TM components of an incident wave polarized at slant 45° experience a 90° phase shift, reflection will occur in CP. The concept and performance limitations are theoretically investigated using transmission line theory as well as full wave results. The predicted performance is validated by means of experimental results on a fabricated prototype. The proposed structure is pertinent for employment as a quasi-optical diplexer in CP dual-band systems such as reflector antennas.

Electrochemical promotion of a Pt catalyst supported on La 0.6Sr 0.4Co 0.2Fe 0.8O 3 - δ hollow fibre membranes

The use of wireless electrochemical promotion of catalysis (EPOC) of a Pt catalyst supported on a mixed ionic electronic conducting hollow fibre membranes is investigated. This reactor configuration offers high surface areas per unit volume and is ideally suited for scaled-up applications. The MIEC membrane used is the La _0.6Sr _0.4Co _0.2Fe _0.8O ₃ perovskite (LSCF) with a Pt catalyst film deposited on the outer surface of the LSCF membrane. Experimental results showed that after initial catalyst deactivation (in the absence of an oxygen chemical potential difference across the membrane) the catalytic rate can be enhanced by using an oxygen sweep and wireless EPOC can be used for the in situ regeneration of a deactivated catalyst. © 2012 Elsevier B.V.

Experimental study on PC hollow-core slab strengthened with bamboo plates

An experimental study on strengthening prestressed concrete (PC) hollow-core slabs was conducted. Nine PC hollow-core slabs were tested, including three unstrengthened reference slabs and six slabs strengthened with bamboo plates. The results show that compared with unreinforced slabs, the cracking loads of PC hollow-core slabs strengthened with bamboo plates increase by 5% to 96% (with an average of 41%), the loads at allowable deflection increase by 8% to 76% (with an average of 35%), and the ultimate loads increase by 83% to 184% (with an average of 123%), respectively. All the degrees of improvement in the crack load, allowable load and ultimate load increase with the increase in the thickness and width of the bamboo plates. With the increase in the loads, the strain distribution along the height of the strengthened slabs at the mid-span basically remains a plan-assumption. With the increase in the thickness and width of the bamboo plates, both the bamboo tensile strain on the tensile face and the concrete compressive strain on the compression face of the strengthened slabs decrease under the same load level.

Circular polarisation frequency selective surface operating in Ku and Ka band

A double layer circular polarization (CP) frequency selective surface (FSS) for use as a dual-band quasi-optical diplexer suitable for deployment in reflector antenna systems is described. The FSS was designed to reflect Ku band signals (11.7–12.75 GHz) while transmitting Ka band signals (17.3–20.2 GHz) and conserving CP in each of these bands. The simulated/measured reflection loss over the Ku band was less than 0.05/0.1 dB for both TE and TM polarizations, while the simulated/measured axial ratio was less than 0.2/0.75 dB. Over the Ka band, the simulated/measured transmission loss for both polarizations was below 0.25/0.4 dB and the simulated/measured axial ratio was less than 0.25/0.75 dB. To the best of our knowledge, this is the first report of a metallo-dielectric FSS that simultaneously operates in CP for an oblique angle of incidence in both Ku and Ka bands.