Effective collision strengths for transitions in Fe XI

Collision strengths for transitions among the lowest 48 fine- structure levels belonging to the (1s(2)2s(2)2p(6)) 3s(2)3p(4), 3s3p(5), 3s(2)3p(3)3d and 3p(6) configurations of Fe XI have been calculated using the Dirac Atomic R-matrix Code (DARC) of Norrington & Grant (2003). Results are tabulated at energies above thresholds in the range 10 less than or equal to E less than or equal to 100 Ry, although resonances have been resolved in a fine energy mesh in the thresholds region. Effective collision strengths, obtained after integrating the collision strengths over a Maxwellian distribution of electron velocities, are also tabulated over a wide electron temperature range below 5 x 10(6) K. Comparisons with other available results are made, and the accuracy of the present data is assessed.

Effective collision strengths for transitions within the ground configuration of Fe XXI

Effective collision strengths for transitions among the energetically lowest 46 fine-structure levels belonging to the (1s(2)) 2S(2) 2p(2), 2s2p(3), 2p(4), 2S(2)2p3s, 2s(2)2p3p and 2S(2)2p3d configurations of Fe XXI are computed, over an electron temperature range of 5.6 less than or equal to log T-e less than or equal to 7.4 K, using the recent Dirac Atomic R- matrix Code (DARC) of Norrington and Grant. Results are presented for transitions within the ground configuration only, and are compared with earlier R matrix calculations. Large discrepancies are observed for many transitions, especially at lower temperatures.

Radiative rates, collision strengths and effective collision strengths for transitions in Gd XXXVII

Energy levels and radiative rates for transitions among 107 fine-structure levels belonging to the (1s(2)2S(2)p(6)) 3S(2)3p(6)3d(10), 3S(2)3p(6)3d(9)4e. 3S(2)3p(5)3d(10)4e. and 3s3p(6)3d(10)4e configurations of Ni-like Gd XXXVII have been calculated using the fully relativistic GRASP code. Radiative rates and oscillator strengths are tabulated for all allowed transitions among these levels. Additionally. collision strengths for transitions among the lowest 59 levels have been computed using the Dirac Atomic R-matrix Code. Resonances in the threshold region have been delineated, but results for collision strengths are tabulated only at energies above thresholds in the range 120

Effective collision strengths for transitions in Fe XV

Collision strengths for transitions among the energetically lowest 53 fine-structure levels belonging to the (1s(2)2s(2)2p(6)) 3l(2), 3l3l', 3s4l and 3p4s configurations of Fe XV are computed, over an electron energy range below 160 Ryd, using the Dirac Atomic R-matrix Code (DARC) of Norrington & Grant (2003). Effective collision strengths, obtained after integrating the collision strengths over a Maxwellian distribution of electron energies, have also been calculated. These results of effective collision strengths are tabulated for all 1378 inelastic transitions over a wide temperature range of 10(5) to 10(7) K. Comparisons are also made with other R-matrix calculations and the accuracy of the results is assessed.

Energy levels, radiative rates, and collision strengths for transitions in Fe XVII

Energy levels and radiative rates have been calculated for fine-structure transitions among the lowest 89 levels of the (1s(2)) 2s(2)2p(6), 2s(2) 2p(5) 3 l, 2s(2) 2p(5) 4l, 2s2p(6) 3 l, and 2s2p(6)4l configurations of Fe XVII using the GRASP code of Dyall et al. Collision strengths have also been calculated, for transitions among the lowest 55 levels, using the recently developed Dirac atomic R-matrix code (DARC) of Norrington & Grant. The results are compared with those available in the literature, and the accuracy of the data is assessed.

Effective collision strengths for transitions among the 3s(2), 3s3p and 3p(2) configurations of Fe xv

Effective collision strengths for transitions among the ten energetically lowest fine-structure levels belonging to the (1s(2)2s(2)2p(6))3s(2), 3s3p and 3p(2) configurations of Fe xv have been calculated in the electron temperature range of 10(5)-10(7) K, using the recent Dirac atomic R-matrix code of Norrington and Grant. The results are compared with the other recently available independent Breit-Pauli R-matrix calculations of Eissner et al (Eissner W, Galavis M E, Mendoza C and Zeippen C J 1999 Astron. Astrophys. Suppl. 137 165) and Griffin et al (Griffin DC, Badnell N R, Pindzola M S and Shaw J A 1999 J. Phys. B: At. Mol. Opt. Phys. 32 2139, 4129). Large differences are observed for many transitions over almost the entire temperature range. These differences are analysed and discussed, and the accuracy of the calculations is assessed.

Electron impact excitation of Al XIII: Collision strengths and rate coefficients

Collision strengths for all transitions up to and including the n = 5 levels of Al XIII have been computed in the LS coupling scheme using the R-matrix code. All partial waves with angular momentum L less than or equal to 45 have been included, and resonances have been resolved in a fine energy grid in the threshold region. Collision strengths are tabulated at energies above thresholds in the range 162.30 less than or equal to E less than or equal to 220.0 Ry, and results for the 1s-2s and 1s-2p transitions are compared with those of previous authors. Additionally, effective collision strengths, obtained after integrating the collision strengths over a Maxwellian distribution of electron velocities, are tabulated over a wide temperature range of 4.40 less than or equal to log T-e less than or equal to 6.40 K.

Effective collision strengths for electron impact excitation of C1III

Effective collision strengths for electron-impact excitation of the phosphorus-like ion Cl III are presented for all fine- structure transitions among the levels arising from the lowest 23 LS states. The collisional cross sections are computed in the multichannel close-coupling R-matrix approximation, where sophisticated configuration-interaction wave functions are used to represent the target states. The 23 LS states are formed from the basis configurations 3s(2)3p(3). 3s3p(4). 3s(2)3p(2)3d, and 3s(2)3p(2)4s, and correspond to 49 fine- structure levels, leading to a total possible 1176 fine- structure transitions. The effective collision strengths. obtained by averaging the electron collision strengths over a Maxwellian distribution of electron velocities. are tabulated in this paper for all 1176 transitions and for electron temperatures in the ranges T(K) = 7500-25.000 and log T(K) = 4.4-5.3. The former range encompasses the temperatures of particular importance for application to gaseous nebulae. while the latter range is more applicable to the study of solar and laboratory-type plasmas. (C) 2001 Academic Press.

Effective collision strengths for electron impact excitation of Si VIII

Effective collision strengths for electron-impact excitation of the nitrogen-like ion Si VIII are presented over the wide range of electron temperatures log T(K) = 4.0-6.5. All 231 fine- structure transitions among the 22 fine-structure levels arising from the lowest 11 LS target states (2s(2)2p(3), 2s2p(4), 2p(5), and 2s(2)2p(2)3s) are considered in the tabulation. The collision strengths are evaluated in a multi- channel R-matrix approach, and the corresponding effective collision strengths are obtained by averaging these over a Maxwellian distribution of electron velocities. Comparisons are made with recent distorted-wave results at high incident electron energies. Differences of up to 20% are found, particularly for some allowed transitions. (C) 2003 Elsevier Inc. All rights reserved.

Shifts in electron capture to the continuum at low collision energies: Enhanced role of target postcollision interactions

Measurements of electron velocity distributions emitted at 0degrees for collisions of 10- and 20-keV H+ incident ions on H-2 and He show that the electron capture to the continuum cusp formation, which is still possible at these low impact energies, is shifted to lower momenta than its standard position (centered on the projectile velocity), as recently predicted. Classical trajectory Monte Carlo calculations reproduce the observations remarkably well, and indicate that a long-range residual interaction of the electron with the target ion after ionization is responsible for the shifts, which is a general effect that is enhanced at low nuclear velocities.

Charge exchange emission from solar wind helium ions

Charge exchange X-ray and far-ultraviolet (FUV) aurorae can provide detailed insight into the interaction between solar system plasmas. Using the two complementary experimental techniques of photon emission spectroscopy and translation energy spectroscopy, we have studied state-selective charge exchange in collisions between fully ionized helium and target gasses characteristic of cometary and planetary atmospheres (H2O, CO2, CO, and CH4). The experiments were performed at velocities typical for the solar wind (200-1500 km s(-1)). Data sets are produced that can be used for modeling the interaction of solar wind alpha particles with cometary and planetary atmospheres. These data sets are used to demonstrate the diagnostic potential of helium line emission. Existing Extreme Ultraviolet Explorer (EUVE) observations of comets Hyakutake and Hale-Bopp are analyzed in terms of solar wind and coma characteristics. The case of Hale-Bopp illustrates well the dependence of the helium line emission to the collision velocity. For Hale-Bopp, our model requires low velocities in the interaction zone. We interpret this as the effect of severe post-bow shock cooling in this extraordinary large comet.

Collision mechanisms in one-electron capture by slow H and He- like ions of C, N and O in H and H-2

Translational energy spectroscopy (TES) has been used to study state-selective one-electron capture by H and He-like ions of C, N and O in both H and H-2 within the range 250-900 eV amu(- 1). The main collision mechanisms leading to state-selective electron capture have been identified, their relative importance assessed and compared, where possible, with theoretical predictions and with any previous measurements based on photon emission spectroscopy. For one-electron capture in H-2, the relative importance of contributions from non- dissociative and dissociative capture as well as from two- electron capture into autoionizing states is found to be strikingly different for the cases considered. Our TES measurements in atomic hydrogen provide an important extension of previous measurements to energies below 1000 eV amu(-1) and show that, as the impact energy decreases, electron capture becomes more selective until only a single n product channel is significant. These product main channels are well described by reaction windows calculated using a Landau-Zener approach. However, the same approach applied to the more complex energy- change spectra observed in H-2 is found to be less successful.

Multi-zone TAP-reactors theory and application - IV. Ideal and non-ideal boundary conditions

We study the influence of non-ideal boundary and initial conditions (BIC) of a temporal analysis of products (TAP) reactor model on the data (observed exit flux) analysis. The general theory of multi-response state-defining experiments for a multi-zone TAP reactor is extended and applied to model several alternative boundary and initial conditions proposed in the literature. The method used is based on the Laplace transform and the transfer matrix formalism for multi-response experiments. Two non-idealities are studied: (1) the inlet pulse not being narrow enough (gas pulse not entering the reactor in Dirac delta function shape) and (2) the outlet non-ideality due to imperfect vacuum. The effect of these non-idealities is analyzed to the first and second order of approximation. The corresponding corrections were obtained and discussed in detail. It was found that they are negligible. Therefore, the model with ideal boundary conditions is proven to be completely adequate to the description and interpretation of transport-reaction data obtained with TAP-2 reactors.