Correlating Additives to Deterioration and Assessing the Effectiveness of Acrylic Coatings for the Protection of Rubber

Conservators have long been aware of the problems associated with the preservation of rubber objects due to inherent instability that can be attributed, in part, to the presence of additives. Inorganic additives, such as fillers, accelerators, stabilizers, and special ingredients are necessary in manufacturing to alter the properties of natural rubber. These materials all have different interactions with the rubber, and each other, and differing effects on the ageing process. To date, the most effective and accepted methods to preserve rubber are cold, dark storage of objects, or the use of low oxygen environments. While these methods are effective, they greatly limit access. The application of coatings to the surface of rubber objects can slow deterioration and greatly increase the ability of an institution to handle and display rubber objects. While numerous coatings for preventive and interventive treatment have been tested, none have been so successful to warrant routine use. The first section of this research highlighted the relationship between the inclusion of certain additives in natural rubber objects and the accelerated or slowed down overall degradation. In the second part of this research, the acrylic varnishes Golden Polymer Varnish with UVLS, Lascaux Acrylic Transparent Varnish-UV, Sennelier Matte Lacquer with UV Protection, and Liquitex Soluvar Varnish containing ultraviolet light absorbers or stabilizers were tested as a preventative coating for rubber. Through testing the visual and physical properties of the samples, as well as compound analysis the results of this research suggest that acrylic varnishes do provide protection, each to varying degrees. The results also provided insight into the behavior of rubber and these varnishes with continuing light exposure.

L’Utilisation D’Entretiens Quantitatifs Pour Détecter L’influence des Parents Dans le Développement de Compétences Sportives Chez Les Athlètes

Past research has indicated that parents influence children’s sport performance, but studies using qualitative methodologies and lacking comparison groups have failed to outline specific parent behaviors that constitute support, pressure, involvement, and resource provision at each stage of development. This paper presents a quantitative methodology that assesses specific, observable, verifiable parent behaviors across development, allowing future researchers to highlight differences in parental behaviors of athletes who reach high levels of performance and those who do not. The combined survey and interview methodology examines parents’ demographic information, children’s involvement in sporting activities, and the nature of parents’ involvement in those activities. A case study conducted with the parents of three Canadian junior ice hockey athletes using this methodology found parents’ invested time and specific behaviors changed throughout the development of the athlete.