1 resultado para ASYMMETRIC ALLYLIC ALKYLATION
em Greenwich Academic Literature Archive - UK
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Relevância:
Resumo:
Allylic sulfonyl halides can be generated by halogenolysis of the corresponding triorganotin sulfinates. Allylic sulfonyl bromides and iodides undergo a first order, thermal desulfination with allylic rearrangement to yield the corresponding allylic halides. The desulfination of a cyclic allylic sulfonyl bromide is stereospecific, proceeding with T-syn bromine migration.
