Assessing the Oxidative History of Miller Range Martian Meteorites

Miller Range (MIL) Martian meteorites are oxidized nakhlites. Early studies attribute their oxidation to reduction-oxidation reactions involving assimilated sulfate. I utilize the sulfur isotope and major element composition of the MIL pairs to assess their oxidative history. MIL sulfides display an average sulfur isotope composition that is different from Nakhla sulfate and sulfide. The sulfur isotope differences produce a mixing array between juvenile sulfur and mass-independent sulfur signatures, indicating assimilation of anomalous sulfur into the melt. I estimate an fO2 of QFM (+3.5 ± 0.4) and a sulfur content of 360 ppm ± 12 – 1300 ppm ± 50. With these results, I test the hypothesis of sulfate assimilation through models of charge balance, isotope mixing, and degassing of sulfur bearing compounds. I conclude that sulfate assimilation was significant in the oxidation of the MIL pairs but, additional oxidants were assimilated.

Dwelling Beyond: Sustainable Design On Mars

In 1620, over the course of 66 days, 102 passengers called the Mayflower their home before arriving and settling in Plymouth, New England. In the years following the Louisiana Purchase of 1803 nearly 7 million people traversed extreme wilderness in covered wagons to found and settle the American West. This year, 2015, the first spaceport has opened in anticipation of sub orbital space flights in 2017 and manned settlement flights to mars by 2026. This thesis explores the questions: In this next phase of human exploration and settlement, what does it mean to dwell beyond earth? What are the current architectural limitations regarding structure and material sustainability? And, How can architecture elevate the traditionally sterile environments of survival shelters to that of permanent dwellings?