7 resultados para Eugene Sandow

em Boston University Digital Common


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http://www.archive.org/details/thingsastheyarem00wilsuoft

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http://www.archive.org/details/thestoryofthefuh00stocuoft

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http://www.archive.org/details/missionasfrontie00boltrich

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http://www.archive.org/details/anheroicbishopli00stocuoft

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http://www.archive.org/details/diaryofdavid01zeisrich http://www.archive.org/details/diaryofdavid02zeisrich

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http://www.archive.org/details/beginningsinindi00stocuoft/

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Using Monte Carlo simulations we study a coarse­grained model of a water layer confined in a fixed disordered matrix of hydrophobic nanoparticles at different particle concentrations c. For c = 0 we find a 1st order liquid­liquid phase transition (LLPT) ending in one critical point at low pressure P. For c > 0 our simulations are consistent with a LLPT line ending in two critical points at low and high pressure. For c = 25% at high P and low temperature T we find a dramatic decrease of compressibility, thermal expansion coefficient, and specific heat. Surprisingly, the effect is present also for c as low as 2.4%. We conclude that even a small presence of nanoscopic hydrophobes can drastically suppress thermodynamic fluctuations, making the detection of the LLPT more difficult.