Análise energética da madeira e do carvão de híbridos entre Corymbia citriodora (Hook.) K.D. Hill & L.A.S. Johnson e Corymbia torelliana (F. Muell.) K.D. Hill & L.A.S. Johnson

This research aimed to evaluate the wood and charcoal quality of hybrids clone of the crossing C. citriodora with C. torelliana in two different locations for charcoal production. Seven with 3,75 years old clones, planted at country of Itamarandiba – MG, and six 6,42 years old clones, planted in Dionísio – MG, were studied. For wood and charcoal quality analysis, samples were collected along the stem of the trees until the commercial height. Properties study of the wood was done by chemical analysis, basic density, superior heat power, and thermogravimetric analysis. The wood samples were carbonized in laboratory conditions with heating rate of 1.67 0 C.min -1 , starting at 100 0 C until 450 0 C and keeping on this temperature for 30 minutes. It were determined the carbonizations gravimetric yield, all in dry basis. The wood quality was evaluated based on the chemical immediate analysis, relative apparent density, and gross heating value. The experiment was installed according to the completely randomized design, with five repetitions. The collected data were submitted to analysis of variance and, when the evaluated effects were significant by “F” test, was applied the Scott-Knott test at 5% probability for multiple comparisons. For correlation analysis, Pearson correlation coefficient, tested by the "t" test at 5% probability was used. Results showed variability of wood between the genetic materials evaluated in relation to place and plant crossing. The thermal analysis of the wood showed significant variation between clones and it was possible to differentiate two stages of degradation (hemicelluloses and cellulose). The majority of the clones presented satisfactory properties for the charcoal production, while, clone 3, planted in Itamarandiba, obtained the best performance due it have the higher yield and energetic efficiency, thus, achieving the best potential for charcoal production. However, clone 9, planted in Dionísio, was the less indicated for charcoal production since it presented the lowest energetic efficiency, gravimetric yield, and densities.

Análise do teor de cocaína em amostras apreendidas pela polícia utilizando-se a técnica de cromatografia liquida de alta eficiência com detector UV-Vis

The HPLC technique with UV-Vis detection was employed in the analysis of cocaine content in apprehended samples of cocaine and crack. A peak signal for cocaine was obtained in 3.5 minutes run by using acetonitrile/water (95:5v/v) as a mobile phase. Optimized spectrophotometric signal was obtained at a wavelength of 224 nm. The analytical curve from 1.0 to 40.0 ppm of cocaine was obtained, showing a linear correlation coefficient of 0.9989, with detection and quantification limits of 0.75 ppm and 3.78 ppm, respectively. This methodology was employed at the dosage of confiscated samples of cocaine and crack in the Scientific Police Laboratory of Ribeirão Preto-SP city.

Recuperação e aplicação do dicromato de potássio proveniente do resíduo de sulfocrômica

A simple procedure for recovering potassium dichromate (K2Cr2O7 ) from treatment of residual sulphochromic solution was proposed in the present work by means of cooling crystallization. The decrease of temperature favored the crystallization of K2Cr2O7 due to the decrease of solubility. 5.0 L of sulphochromic wastes containing 48.08 g L-1 of Cr(VI) were treated and the process of crystallization was performed in three steps until crystals were not formed anymore. On each step the content of Crtotal was determined by flame atomic absorption spectrometry and Cr(VI) by colorimetric method with 1,5- diphenylcarbazide, resulting in the removal of 91% and 92% of Crtotal and Cr(VI), respectively. After the last step, the remaining Cr(VI) in the solution was reduced to Cr(III) from the addition of NaHSO3 , recovering via precipitation in pH 8 approximately 36.13 g of Cr(OH)3 . The final supernatant was discarded since chromium content was below the maximum limit established by the Brazilian legislation for effluents discharge, which corresponds to 0.10 and 1.0 mg L-1 of Cr(VI) and Cr(III), respectively. 628.4 g of K2Cr2O7 were recovered and the salt was characterized by X-ray diffraction and differential thermal analysis. Its applicability was compared to the standard K2Cr2O7 when determining the soil organic matter, in which there was no significant difference, thus inferring that the recovered compound may be incorporated on routine analyses. This recovering process allowed the reuse of K2Cr2O7 , thus reducing costs with the acquisition of new reagents and environmental impacts caused by the inadequate discard of sulphochromic solutions.