Determinação da densidade amostral ótima para a geração de mapas temáticos na cafeicultura de precisão

Among the crops commercially exploited in Brazil, the coffee has a great economic importance, especially in the states of Minas Gerais and Espirito Santo. In the search for higher yield and lower environmental impact, farmers and researchers seek to develop new technologies that result in greater efficiency in various production processes of the coffee. For this, the adoption of precision agriculture in the management of operations in coffee crops, called precision coffee, has shown results that justify its use, by identifying the spatial variability of several variables, allowing its localized management and in the proper intensity. Unlike conventional management that is based on the average of observations in an area, precision agriculture uses a more detailed sampling, based on a sampling grid, which allows to represent in greater detail the reality of farming. Many previous studies have identified the spatial variability of the production of coffee system variables, but without worrying about the quality of information obtained due to the sampling grid used as precision and accuracy. Given the above, the objective of this study was to evaluate the quality of four different sampling grids for different variables and three times, in order to identify the most appropriate grid for use in precision coffee. Also aimed to compare the results between the precision coffee and conventional, according to reference values.

Síntese do complexo ferro (III) com ácido pirazina tetracarboxílico e aplicação como catalisador em reação fenton

The amount of waste generated by industries has increased gradually in recent years. The proper disposal of residues has been an area of study of many researchers. Several organic compounds are considered potential contaminants of natural waters due to their high toxicity, difficult natural degradation and long persistence in the environment. Ways of recovery and reutilization as well as concepts that minimize the generation of wastes have been increasing widely. Organometallic compound of pyrazine carboxylic acid has proven to be of great interest in many areas. Herein, we studied the use of pyrazine tetracarboxylic acid ligand for complex formation with iron (Fe). The binder (C 8H4N2O8) was synthetized with the addition of Fe (complex) and tested as a catalyst in oxidation reactions of the organic model compound methylene blue (MB). Tetramethyl pyrazine was used in the synthesis, which was oxidized with potassium permanganate in order to form the ligand. The ligand (C 8H4N2O8) was then characterized to validate its formation. For the complex solution, it was used (C 8H4N2O8) and Fe (NO3)3.9H2O 0,01molL-1. After preliminary tests, it was found that the best ratio of Fe and the ligand was 2: 1. Through the oxidation tests, it could be seen that the complex has great potential for the degradation of different concentrations of MB. During only 20 minutes of reaction, approximately 60% of MB 500 mgL -1 was oxidized. The use of the complex was found to be an attractive alternative for oxidation of effluents with high organic compounds levels and contributes to the minimization of organic contaminants hazards in the environment.