Estrutura e algumas propriedades ópticas de difenilfosfinatos de terras-raras

Coordination compounds of trivalent lanthanides cations with diphenylphosphinate are originated from direct reaction between a lanthanide salt and diphenylphosphinic acid. These complexes have peculiar and intriguing features, as (i) quickly obtainment through wet process precipitation, (ii) appreciable thermal stability, similar to inorganic phosphates, (iii) polymeric structure, and consequently, (iv) low solubility in both polar and non-polar solvents. Nowadays, coordination polymers are classified as coordination networks or, in case of porous materials, as metal-organic frameworks (MOFs). By this study, we aim to determine some optical properties of rare-earth diphenylphosphinate (RE = La3+, Eu3+, Gd3+, Lu3+) and conduct an updated classification of these compounds, bringing more details of its structure and the possible proposal of new materials with applications in lighting, detection of ionizing radiation and magnetism. The complexes of trivalent rare-earth cation with diphenylphosphinate were prepared by direct mixture of diphenylphosphinic acid with rare-earth metal chloride, both in ethanolic solution. The solution of diphenylphosphinic acid was kept in a beaker under constant stirring with pH measurements of the solution and gadolinium chloride solution was then dripped slowly with the aid of a burette until its complete addition; the following metal:ligand molar ratios were tested: 1:1, 1:2, 1:3, 2:1 e 3:1. The compounds were characterized by spectroscopic and structural techniques. By Fourier Transform Infrared Spectroscopy (FT-IR), it was possible to check the total ionization of diphenylphosphinic acid in synthesized complexes, confirmed by the absence of the band type A, B, C related to ѵ(O-H) of the acid (2663 cm-1, 2168 cm-1, 1684 cm-1), as well as the disappearance of ѵ(P-OH)=961 cm-1. Furthermore, the occurrence of bands shifts of ѵ(POO-) [symmetrical and asymmetrical] of...

Classificação de anomalias e redução de falsos positivos em sistemas de detecção de intrusão baseados em rede utilizando métodos de agrupamento

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Classificação automatizada do relevo a partir de parâmetros morfométricos

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

O Raciocínio lógico-matemático: classificação e uso em concursos públicos

This study offers an analysis of classification of the main issues of logic and logical thinking found in competitive tendering and math tests, according to their concepts and characteristics, whether involving mathematics, or not. Moreover, a research on the evolutionary historic processes of logic according to three major crises of the foundations of mathematics was conducted. This research helped to define Logic as a science that is quite distinctive from Mathematics. In order to relate the logical and the mathematical thinking, three types of knowledge, according to Piaget, were presented, with the logical-mathematical one being among them. The study also includes an insight on the basic concepts of propositional and predicative logic, which aids in the classification of issues of logical thinking, formal logic or related to algebraic, and geometric or arithmetic knowledge, according to the Venn diagrams. Furthermore, the key problems - that are most frequently found in tests are resolved and classified, as it was previously described. As a result, the classification in question was created and exemplified with eighteen logic problems, duly solved and explained