4 resultados para Máquina de vetor de suporte
em Repositório Institucional da Universidade Estadual de São Paulo - UNESP
Resumo:
Pós-graduação em Psicologia do Desenvolvimento e Aprendizagem - FC
Resumo:
Fuel cells powered directly with ethanol (Direct Ethanol Fuel Cell-DEFC) are very attractive for the possibility of using a renewable fuel in the generation of clean energy. However, it is still necessary to deepen the understanding of catalytic processes and their dependence on the catalytic properties. This work proposes to study the catalytic activity of ethanol oxidation in an alkaline medium of Pd nanoparticles supported in carbon oxide hybrids using various transition metal oxides (MoO3, TiO2, WO3 and ZrO2). The materials prepared were characterized by techniques such as X-ray diffraction, transmission electron microscopy (TEM) and X-ray dispersive spectroscopy (EDX) to verify the structure, the distribution of particles in the supports and the presence of Pd on particles oxide. Experiments of X-rays absorption spectroscopy were carried out using soft X-rays (SXS) to evaluate the changes in the electronic properties of the Pd particles caused by interactions with different oxides. Measurements of cyclic voltammetry and potential sweeps of adsorbed CO oxidation allowed evaluating general aspects of the catalysts' electrochemical behavior and determining the electrochemically active area thereof. The catalytic performances of ethanol oxidation in alkaline medium were evaluated by electrochemical techniques (potential scan and chronoamperometry), and showed an improvement in activity with the addition of oxides in material containing only carbon, which was most pronounced for the catalyst containing TiO2. This improvement was predominantly associated with the electronic effects caused by the interaction of Pd on the support, causing a vacancy in the 4d band of Pd which, in turn, produces variations in adsorption energies of the species...
Resumo:
The object of this study is a glass heating machine for rolling process, designed in 2006 and which is manufactured regularly. By customer request it is intended to increase the production capacity of this machine. However, initial tests have shown that the existing heat exchanger cannot supply the necessary thermal energy demand. A study of the thermal characteristics of the equipment was performed in order to obtain the required information to study alternatives for expanding its capacity taking into account space limitations and the need to rationalize costs, avoiding unnecessary oversizing
Estudo do meio físico e caracterização da capacidade de suporte natural da região de Pirassununga/SP
Resumo:
Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)