6 resultados para Helio - Espalhamento

em Repositório Institucional da Universidade Estadual de São Paulo - UNESP


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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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Pós-graduação em Química - IQ

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Used as catalysts even in organic and inorganic molecules, as additives on catalysts, electrochromic films on smart windows the tungsten trioxide have been largely studied on the lasts decades, but there is just a few about it's luminescence. Using as precursors nitric acid and sodium tungstate the tungsten trioxide were been prepared thru wet process then treating on thermic and hydrothermal treatments. Where been evaluated the effects of methodology, nitric acid concentration, duration and temperature of treatments. The samples were characterized by X-ray diffraction (XRD), Raman scattering spectroscopy (RSS), Fourier transformed infrared spectroscopy, photoluminescence spectroscopy (PLS) and X-ray excited optical luminescence (XEOL). Hydrated phases of tungsten trioxide were obtained through hydrothermal treatments and the non-hydrated phases occur with thermic treatments. The acid concentration has the ability to determine the major phase formed as well the temperature determine the hydratation of the product. With lower temperatures dihydrate phase were preferable formed and with the rise of temperature, the water molecules were lost up to the fractionary hydratation and then the non-hydrated phase with higher temperatures depending on the atmosphere used on the thermal treatment. Doping the system with europium ions even substituting tungsten or in the interstices of the matrix were not been successful, as well the XEOL spectroscopy intensity were null and quite low for ultraviolet and visible excitation photoluminescence because of oxygen defect levels localized into the prohibited band.

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O Brasil é o terceiro maior consumidor de cosméticos no mundo, representando a segunda colocação em produtos de higiene capilar. Tal colocação está relacionada aos nossos padrões de cuidados estéticos capilares, que muitas vezes, provocam agressões físicas e químicas, deixando os cabelos danificados e quebradiços. Os condicionadores capilares tornam-se uma ferramenta interessante, devido aos inúmeros benefícios protetores oferecidos às superfícies dos fios. A presença de tensoativos catiônicos e álcoois graxos de cadeia longa, unidos à temperatura de fusão dos materiais, velocidade de agitação imposta e resfriamento adequado do produto, podem ser os responsáveis pela formação de cristais líquidos. Tais estruturas conferem estabilidade, viscosidade, melhorias na aparência estética e sensorial do produto e, devido a estas qualidades estão ganhando espaço no mercado cosmético. Assim, o objetivo do trabalho foi desenvolver e formular condicionadores capilares variando-se as concentrações e/ou os tensoativos catiônicos e álcoois graxos, visando obter estruturas líquido-cristalinas associadas aos condicionadores, através da técnica de microscopia de luz polarizada (MLP), caracterização das estruturas pela técnica de espalhamento de raios-X a baixo ângulo (SAXS) e analise do perfil de textura (TPA) das formulações. Foram manipuladas 14 emulsões O/A, variando-se os álcoois graxos de cadeia longa (16 a 18C) e ceras auto emulsionantes catiônicas. Os resultados da MLP foram, em sua maioria, positivos para a presença de estruturas na forma de cruz de malta. A técnica de SAXS confirmou os sistemas sugeridos pela MLP caracterizando a estrutura líquida cristalina do tipo lamelar. A TPA inferiu que a alta estabilidade física apresentada por estas emulsões, e seu particular desempenho no deslizamento dos cabelos, pode estar relacionada à presença de tal organização estrutural nas formulações...

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In this paper, we will present an overview of the smart grid defining the three main systems that compose it: smart infrastructure system, smart management system and smart protection system. We will conceptualize a functionality of smart management system, the conservative voltage reduction, citing its benefits and its history of application. And, finally, we'll cover a test in which we reduce the nominal voltages on incandescent bulbs, CFL and LED, in the context of residential lighting, and on LED and HPS, in the context of public lighting. The test aims to check whether the voltage reduction adversely affects sources of lighting by measuring the temperature manually with a thermal imaging camera FLIR and illuminance with a LUX meter. The set of power factor, total harmonic distortion, and input power values will be collected automatically through the power quality Analyzer Fluke 345 with a probe Fluke Hall Effect Current. For residential lighting, it was found that both CFL and LED had good performance with the smallest variations in illuminance. Between both, the LED source had the lowest harmonics and the lowest power consumption, on the other hand incandescent bulbs had a bad performance as expected. Public light sources also had a good performance and obtained power factors within the standards, as opposed to the CFL and LED residential sources. The data collected clearly shows the feasibility for nominal voltage reductions. Even with small reductions, there are possibilities of savings which can be passed on to the utilities and consumers

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)