Análise das projeções de mudanças climáticas do quinto relatório do IPCC dentro das áreas protegidas brasileiras

Entre os impactos das mudanças climáticas previstas para este século estão as possíveis alterações no padrão de distribuição de espécies, comunidades, e até mesmo biomas. Tais impactos ocorrerão, sem distinção, tanto dentro como fora de áreas protegidas. No Brasil, as unidades de conservação (UCs) estão organizadas segundo o Sistema Nacional de Unidades de Conservação (SNUC). Porém, a lei federal 9985/2000 que rege o SNUC não contempla a ocorrência de mudanças climáticas e as possíveis ações de manejo para contornar o problema dentro delas. Sendo assim, esta pesquisa pretende, de forma pioneira, iniciar a investigação das mudanças climáticas a ocorrerem dentro das áreas protegidas (AP) em âmbito nacional. Para isso, fez-se uma análise geográfica das mudanças de temperatura e precipitação oriundas de vários modelos climáticos utilizados pelo IPCC no seu quinto relatório dentro das áreas compreendidas dentro das UCs cadastradas no SNUC e Terras Indígenas. Tal análise pautou-se pelos diversos tipos de áreas protegidas e também pelas macrorregiões geográficas do Brasil. Nossos resultados mostram que as APs passíveis de mudanças climáticas mais extremas (aumento de temperatura > 3ºC e redução de precipitação >50mm/mês) são aquelas que contemplam a presença de populações tradicionais na região Norte e Centro-Oeste do país. Ao final do projeto os resultados do projeto foram apresentados em Brasília no Instituto Chico Mendes de Conservação da Biodiversidade. Tal interação demonstrou a inexistência de uma estratégia do governo federal para a adaptação das áreas protegidas Brasileiras aos efeitos de mudanças climáticas futuras

Estrutura e algumas propriedades ópticas de difenilfosfinatos de terras-raras

Coordination compounds of trivalent lanthanides cations with diphenylphosphinate are originated from direct reaction between a lanthanide salt and diphenylphosphinic acid. These complexes have peculiar and intriguing features, as (i) quickly obtainment through wet process precipitation, (ii) appreciable thermal stability, similar to inorganic phosphates, (iii) polymeric structure, and consequently, (iv) low solubility in both polar and non-polar solvents. Nowadays, coordination polymers are classified as coordination networks or, in case of porous materials, as metal-organic frameworks (MOFs). By this study, we aim to determine some optical properties of rare-earth diphenylphosphinate (RE = La3+, Eu3+, Gd3+, Lu3+) and conduct an updated classification of these compounds, bringing more details of its structure and the possible proposal of new materials with applications in lighting, detection of ionizing radiation and magnetism. The complexes of trivalent rare-earth cation with diphenylphosphinate were prepared by direct mixture of diphenylphosphinic acid with rare-earth metal chloride, both in ethanolic solution. The solution of diphenylphosphinic acid was kept in a beaker under constant stirring with pH measurements of the solution and gadolinium chloride solution was then dripped slowly with the aid of a burette until its complete addition; the following metal:ligand molar ratios were tested: 1:1, 1:2, 1:3, 2:1 e 3:1. The compounds were characterized by spectroscopic and structural techniques. By Fourier Transform Infrared Spectroscopy (FT-IR), it was possible to check the total ionization of diphenylphosphinic acid in synthesized complexes, confirmed by the absence of the band type A, B, C related to ѵ(O-H) of the acid (2663 cm-1, 2168 cm-1, 1684 cm-1), as well as the disappearance of ѵ(P-OH)=961 cm-1. Furthermore, the occurrence of bands shifts of ѵ(POO-) [symmetrical and asymmetrical] of...

Políticas e desenvolvimento do estado de Mato Grosso após abertura comercial: análise da visão de dois empresários atuantes no setor

After realizing two interviews, with distinct managers/businessmen working in the cotton industry, the objective is to put in evidence the political, economical and social factors that contributed to the formation and configuration of the Mato Grosso state, after the trade liberalization that occurred in the early 90's, it's effects and consequences in the eyes of the interviewed. The study of public policies is primordial to the discovery of the configuration of determined place, evaluating advances and possible errors in the social, economical and environmental areas. Through the analysis of the interviews it has been found that the urban centers have been developing with a direct link to the industrial activities related to agriculture and that the labor work force have also been attracted because of these changes, and as a consequence this labor force is now becoming more specialized to be able to accompany the jobs requirements in the industry. Analyzing the interviews, it is possible to highlight some information about the development of Mato Grosso, among those the following factors and public policies. The creation and expansion of the cities in the state are possible through public and private investment in infrastructure the socioeconomic development of the state is linked with the advances made in the private sector that grows because of advances made in crops technology in contrast to the occupation of the cerrado, in relation to the cotton crops. The problems that Mato Grosso is facing are mainly linked to the region infrastructure, that can count on investment plans to transportation and production flow that dates before the globalization era. The pattern that is seen today with top of the line agricultural production, big monoculture with high productivity and the arrival of multinational giants, was implanted because of two important events: the trade liberalization in the 1990's and the cambial depreciation in the 1999's...