U-Pb geochronology and Nd isotope contributions to the interpretation of a peculiar ring massif: the Santa Eulália plutonic complex (SW Iberia, Portugal)

The Santa Eulalia plutonic complex (SEPC) is a late-Variscan granitic body placed in the Ossa-Morena Zone. The host rocks of the complex belong to metamorphic formations from Proterozoic to Lower Paleozoic. The SEPC is a ring massif (ca. 400 km2 area) composed by two main granitic facies with different colours and textures. From the rim to the core, there is (i) a peripheral pink medium- to coarse-grained granite (G0 group) involving large elongated masses of mafic and intermediate rocks, from gabbros to granodiorites (M group), and (ii) a central gray medium-grained granite (G1 group). The mafic to intermediate rocks (M group) are metaluminous and show wide compositions: 3.34–13.51 wt% MgO; 0.70–7.20 ppm Th; 0.84–1.06 (Eu/Eu*)N (Eu* calculated between Sm and Tb); 0.23–0.97 (Nb/Nb*)N (Nb* calculated between Th and La). Although involving the M-type bodies and forming the outer ring, the G0 granites are the most differentiated magmatic rocks of the SEPC, with a transitional character between metaluminous and peraluminous: 0.00–0.62 wt% MgO; 15.00–56.00 ppm Th; and 0.19–0.42 (Eu/Eu*)N ; 0.08–0.19 (Nb/Nb*)N [1][2]. The G1 group is composed by monzonitic granites with a dominant peraluminous character and represents the most homogeneous compositional group of the SEPC: 0.65–1.02 wt% MgO; 13.00–16.95 ppm Th; 0.57–0.70 (Eu/Eu*)N ; 0.14–0.16 (Nb/Nb*)N . According to the SiO2 vs. (Na2O+K2O–CaO) relationships, the M and G1 groups predominantly fall in the calc-alkaline field, while the G0 group is essencially alkali-calcic; on the basis of the SiO2 vs. FeOt/(FeOt+MgO) correlation, SEPC should be considered as a magnesian plutonic association [3]. New geochronological data (U-Pb on zircons) slightly correct the age of the SEPC, previously obtained by other methods (290 Ma, [4]). They provide ages of 306  2 Ma for the M group, 305  6 Ma for the G1 group, and 301  4 Ma for the G0 group, which confirm the late-Variscan character of the SEPC, indicating however a faintly older emplacement, during the Upper Carboniferous. Recent whole-rock isotopic data show that the Rb-Sr system suffered significant post-magmatic disturbance, but reveal a consistent set of Sm-Nd results valuable in the approach to the magmatic sources of this massif: M group (2.9 < Ndi < +1.8); G1 group (5.8 < Ndi < 4.6); G0 group (2.2 < Ndi < 0.8). These geochemical data suggest a petrogenetic model for the SEPC explained by a magmatic event developed in two stages. Initially, magmas derived from long-term depleted mantle sources (Ndi < +1.8 in M group) were extracted to the crust promoting its partial melting and extensive mixing and/or AFC magmatic evolution, thereby generating the G1 granites (Ndi < 4.6). Subsequently, a later extraction of similar primary magmas in the same place or nearby, could have caused partial melting of some intermediate facies (e.g. diorites) of the M group, followed by magmatic differentiation processes, mainly fractional crystallization, able to produce residual liquids compositionally close to the G0 granites (Ndi < 0.8). The kinetic energy associated with the structurally controlled (cauldron subsidence type?) motion of the G0 liquids to the periphery, would have been strong enough to drag up M group blocks as those occurring inside the G0 granitic ring.

A busca visual da cor, como medida avaliadora do funcionamento do sistema visual: um estudo exploratório a propósito da objetividade da felicidade em crianças

Este estudo, procura explicar a modularidade da mente humana, como um conjunto de módulos, permitindo desta forma contribuir para o estudo das ciências cognitivas. Estes módulos da arquitetura mental, permitem que a nossa mente interprete a cor resultante do sistema visual e das longitudes de ondas do espetro eletromagnético refratado dos objetos. Tendo por base o estudo do sistema visual, as células sensíveis, designadas por fotorrecetores percorrem o nervo ótico até atingir o encéfalo, localizando-se aí o sistema percetivo, permitindo desta forma realizar o estudo sobre busca visual da cor, como medida avaliadora do funcionamento do sistema visual, um estudo exploratório a propósito da objetividade da felicidade em crianças, que visa explorar a busca visual disjuntiva da cor como medida objetiva do bom funcionamento mental, do bem-estar subjetivo, como construto da felicidade. A amostra foi constituída por um grupo de 49 crianças não institucionalizadas e por um grupo de 16 crianças institucionalizadas, de ambos os sexos. Para a concretização deste estudo, foi necessária a utilização de uma tarefa de busca visual disjuntiva, que utilizou as simetrias de cores pertencentes ao mesmo par oponente e cores pertencentes a diferentes pares oponentes. Os resultados sugerem que não há qualquer interferência da institucionalização no funcionamento mental, logo no bem-estar subjetivo nas crianças; ABSTRACT: This study seeks to explain the modularity of the human mind, as a set of modules, giving this way a contribution to the study of the cognitive sciences. These modules of the mental architecture, allow our mind to interpret the resulting color of the visual system and the wavelengths of the electromagnetic spectrum refracted from the objects. Based on the study of our visual system, sensitive cells known as photoreceptors, which run along the optic nerve to the encephalon, being the perceptive system located there, allowing in this way to carry out the study on visual search of colour, as an assessment measure of the functioning of the visual system, an exploratory study concerning the objectivity of happiness in children, which aims to explore the disjunctive visual search of color as an objective measure of good mental functioning, of subjective well-being, as a construct of happiness. The sample consisted of a group of 49 non institutionalized children and of a group of 16 institutionalized children from both sexes. For the implementation of this study it was necessary to use a disjunctive visual search task, which used the Symmetry of colours belonging to the same opponent pair, and colours belonging to different opponent pairs. The results suggest that there is no interference from the institutionalization in mental functioning, therefore in the children’s subjective well being.

Characterization of the glaze and in-glaze pigments of the nineteenth-century relief tiles from the Pena National Palace, Sintra, Portugal

The glaze and in-glaze pigments of the historical nineteenth-century glazed tiles from the Pena National Palace (Sintra, Portugal) were characterized using a multi-analytical approach. Chemical composition and microstructural characterization were ascertained by µ-PIXE, µ-Raman, optical microscopy and VP-SEM–EDS. The manufacturing technique and colour palette in these tiles were found to be close to the ceramic pigments used in traditional majolica. The blue and purple colours derive from cobalt oxide and manganese oxide, respectively. A mixture of Pb–Sn–Sb yellow with cobalt oxide and iron oxide was used for green and dark yellow, respectively, while grey tonalities consist of a complex mixture of cobalt oxide, manganese oxide and Pb–Sn–Sb yellow in different proportions. Results obtained allowed the determination of the oxides and elements used in pigments as well as production techniques, resorting to traditional majolica manufacture, although the tiles were produced by the end of the nineteenth century.