Reductive dechlorination of TCE and cis-DCE by zero-valent iron and iron-based bimetallic reductants

CEs are the most frequently detected pollutants in groundwater. Several studies have been shown iron-based bimetallic reductants as a good method toward to chlorinated ethylenes degradation. However, many fundamental issues surrounding the chemistry of this phenomena remains elusive. In this study, kinetics and compound specific isotope analysis for reductive dechlorination of TCE and cis-DCE by unamended iron and iron-based bimetal reductants was evaluated. Generally, all the bimetals reductants tested revealed to increase the reactivity of the degradation, in which palladium and nickel were the additional metals more reactive. Ethene and ethane were the major products of TCE degradation. It is supported the simultaneous hydrogenolysis and β-elimination reaction hypothesis, however, the first step of TCE degradation by Au/Fe undergoes preferably by β-elimination, while by unamended iron, Pt/Fe and Co/Fe goes preferably by hydrogenolysis. No apparent elucidation was obtained to explain the high reactivity on bimetals systems; Degradação do TCE e cis-DCE por ferro de valência zero e redutores bimetálicos à base de ferro Resumo: Etilenos clorados são os poluentes mais frequentemente detetados na água subterrânea. Vários estudos têm mostrado que redutores bimetálicos à base de ferro são um bom método para a degradação dos etilenos clorados. Porém, muitas questões fundamentais acerca da química deste fenómeno permanecem elusivas. Neste estudo foi avaliada a cinética e a análise isotópica de compostos específicos para a degradação do TCE e cis-DCE por ferro e redutores bimetálicos à base de ferro. Genericamente, os redutores bimetálicos mostraram aumentar a reatividade da degradação, sendo paládio e níquel os metais adicionais mais reativos. Os produtos principais da degradação do TCE foram eteno e etano. É apoiada a hipótese da simultaneidade de hidrogenólise e β-eliminação, porém, o primeiro passo da degradação do TCE por Au/Fe é realizada preferencialmente por β-eliminação, enquanto por ferro, Pt/Fe e Co/Fe é realizada preferencialmente por hidrogenólise. Não houve uma elucidação aparente para explicar a reatividade nos sistemas bimetálicos.

Reconstituição histórica virtual do retábulo-mor da Igreja do Espírito Santo de Évora: aplicação ao Património da infografia web-based

As a part of a multidisciplinary and integrated research, including conservation sciences and history, a proposal is presented for the historical reconstitution and the virtual restoration of the mannerist altarpiece of the main altar at the Espírito Santo Church, in Évora. The collected data is abundant and the scientific information, because of its technicality, is less prone to be easily understood by the general public, thus becoming less accessible. Web-based infographics are explored as privileged forms of disseminating results and raising awareness to Cultural Heritage. The project materializes as an Internet platform where data and a reconstitution proposal are shared in a visual and interactive way. In addition to the digital virtual reconstitution (2D), some tridimensional models (3D) are presented of various elements of the altarpiece, obtained using methods of computer graphics and digital photogrammetry

A novel two-stage discrete crack method based on the screened Poisson equation and local mesh refinement

We propose an alternative crack propagation algo- rithm which effectively circumvents the variable transfer procedure adopted with classical mesh adaptation algo- rithms. The present alternative consists of two stages: a mesh-creation stage where a local damage model is employed with the objective of defining a crack-conforming mesh and a subsequent analysis stage with a localization limiter in the form of a modified screened Poisson equation which is exempt of crack path calculations. In the second stage, the crack naturally occurs within the refined region. A staggered scheme for standard equilibrium and screened Poisson equa- tions is used in this second stage. Element subdivision is based on edge split operations using a constitutive quantity (damage). To assess the robustness and accuracy of this algo- rithm, we use five quasi-brittle benchmarks, all successfully solved.

Computer-based monitoring platform for renewable energy systems: Four experimental application cases using NI LabVIEW

Sustainability and responsible environmental behaviour constitute a vital premise in the development of the humankind. In fact, during last decades, the global energetic scenario is evolving towards a scheme with increasing relevance of Renewable Energy Sources (RES) like photovoltaic, wind, biomass and hydrogen. Furthermore, hydrogen is an energy carrier which constitutes a mean for long-term energy storage. The integration of hydrogen with local RES contributes to distributed power generation and early introduction of hydrogen economy. Intermittent nature of many of RES, for instance solar and wind sources, impose the development of a management and control strategy to overcome this drawback. This strategy is responsible of providing a reliable, stable and efficient operation of the system. To implement such strategy, a monitoring system is required.The present paper aims to contribute to experimentally validate LabVIEW as valuable tool to develop monitoring platforms in the field of RES-based facilities. To this aim, a set of real systems successfully monitored is exposed.