Evaluation of double treated starches using thermal tools.

Starch is the main polysaccharide found in cereals, composed by amylose and amylopectin. Corn is the principal source of starches worldwide. Starches treatment, through physical, chemical and/or biological methods, can improve the applications range. Acid modification in alcoholic solution promotes minimally degradation in the granule. Ball mill is one physical method poorly explored. The aim was to treat the starches using HCl 0.5 mol L-1 for 1 hour in 100 ml of aqueous, ethanol or methanol solutions with subsequent ball milling processes. One sample was selected as native sample. The four others, one native sample and three acid modified samples, were treated by physical process with the oscillating ball mill. The DTG-60H equipment was used for the TG and DTA analysis. The TG curves showed three mass losses related to dehydration, decomposition and oxidation. The native sample without physical modification showed major resistance to total degradation. This occurs because the physical modification cleaves hydrogen bonds, leaving a weakened granule. The TGDTA results showed that the mass loss in the 2nd event was minor in the hydrolyzed samples compared with native samples. The acid modification can provide starch higher resistance to degradation up to 340 °C. These results showed that chemical and physical treatment changed the thermal behaviors of the starches.

Álgebra de mapas de atributos de solos para estimativa da aptidão agrícola das terras.

The land suitability evaluation is used to establish land zonings for agriculture activities. Geographic information systems (GIS) are useful for integrating different attributes necessaries to define apt and not apt lands. The present study had as main objective to describe procedures to define land suitability using GIS tools, soils maps and data soils profiles data, emphasizing procedures to define soil atributes. The area studied was the watershed of Córrego Espraiado, Ribeirão Preto-SP, located on the recharging area of the Guarani Aquifer, with approximately 4,130 ha and predominance of sugar cane culture. The database project was developed using the GIS Idrisi 32. The land suitability evaluation was done considering the intensive agricultural production system predominant in the watershed, adjusted for the vulnerability of the areas of recharge and for the methodology of GIS tools. Numerical terrain models (NTM) had been constructed for cation exchange capacity, basis saturation, clay content and silt+clay content using kriging (geostatistical interpolator), and for aluminum saturation using the inverse-square-distance. Boolean operations for handling geographic fields (thematic maps and NTM) to produce information plans are described and a land suitability map obtained by GIS tools is presented, indicating that 85% of watershed lands are apt to annual cultures.

Método de elaboração de mapas dos cenários climáticos futuros para o Brasil.

Human activities are altering greenhouse gas concentrations in the atmosphere and causing global climate change. The issue of impacts of human-induced climate change has become increasingly important in recent years. The objective of this work was to develop a database of climate information of the future scenarios using a Geographic Information System (GIS) tools. Future scenarios focused on the decades of the 2020?s, 2050?s, and 2080?s (scenarios A2 and B2) were obtained from the General Circulation Models (GCM) available on Data Distribution Centre from the Third Assessment Report (TAR) of Intergovernmental Panel on Climate Change (IPCC). The TAR is compounded by six GCM with different spatial resolutions (ECHAM4:2.8125×2.8125º, HadCM3: 3.75×2.5º, CGCM2: 3.75×3.75º, CSIROMk2b: 5.625×3.214º, and CCSR/NIES: 5.625×5.625º). The mean monthly of the climate variables was obtained by the average from the available models using the GIS spatial analysis tools (arithmetic operation). Maps of mean monthly variables of mean temperature, minimum temperature, maximum temperature, rainfall, relative humidity, and solar radiation were elaborated adopting the spatial resolution of 0.5° X 0.5° latitude and longitude. The method of elaborating maps using GIS tools allowed to evaluate the spatial and distribution of future climate assessments. Nowadays, this database is being used in studies of impacts of climate change on plant disease of Embrapa projects.