Lithium ion rechargeable batteries: State of the art and future needs of microscopic theoretical models and simulations

This review deals with the recent developments and present status of the theoretical models for the simulation of the performance of lithium ion batteries. Preceded by a description of the main materials used for each of the components of a battery -anode, cathode and separator- and how material characteristics affect battery performance, a description of the main theoretical models describing the operation and performance of a battery are presented. The influence of the most relevant parameters of the models, such as boundary conditions, geometry and material characteristics are discussed. Finally, suggestions for future work are proposed.

Analysis and selection of indicators for a sustainability assessment method for school buildings based on SBTool ‐ PT

Nowadays, the sustainability of buildings has an extreme importance. This concept goes towards the European aims of the Program Horizon 2020, which concerns about the reduction of the environmental impacts through such aspects as the energy efficiency and renewable technologies, among others. Sustainability is an extremely broad concept but, in this work, it is intended to include the concept of sustainability in buildings. Within the concept that aims the integration of environmental, social and economic levels towards the preservation of the planet and the integrity of the users, there are, currently, several types of tools of environmental certification that are applicable to the construction industry (LEED, BREEAM, DGNB, SBTool, among others). Within this context, it is highlighted the tool SBTool (Sustainable Building Tool) that is employed in several countries and can be subject to review in institutions of basic education, which are the base for the formation of the critical masses and for the development of a country. The main aim of this research is to select indicators that can be used in a methodology for sustainability assessment (SBTool) of school buildings in Portugal and in Brazil. In order to achieve it, it will also be analyzed other methodologies that already incorporate parameters directly related with the schools environment, such as BREEAM or LEED.

Lazer e livre motricidade: caminhos para o desenvolvimento da inteligência e sustentabilidade

O objetivo fundamental deste texto é realizar uma abordagem introdutória sobre a perspectiva do lazer e da (livre) motricidade, como caminhos para o desenvolvimento da inteligência emocional, tendo como referência temporal as primeiras idades. Vivemos num contexto de pós-modernidade (corpo e espírito sujeito a novas tensões) e, ao mesmo tempo, presenciamos uma crise antropológica e ontológica profunda. O desaparecimento do exemplo e o relativismo dos valores levaram ao paradoxo atual – viver entre a felicidade (“efêmera”?!) e a infelicidade com medo do futuro. A esse propósito, Sennet (2000) refere que: “…assiste-se à inquietação dos mais velhos que reclamam da destruição daquilo que lhes permitiu constituírem-se enquanto pessoas: relações e profissões definidas e estáveis; vidas estruturadas e organizadas em forma de rentabilizar o tempo, a única coisa que realmente possuíam. Valores como a lealdade, a solidariedade, a cooperação, o investimento recíproco, o prosseguimento de objetivos a longo prazo… resultavam experiências ricas e compensadoras…. por seu lado, os mais novos também se sentem inquietos, porque receiam viver num mundo que não lhes dá a segurança, que estruturou a vida dos seus pais… Neste sentido a vida Social, Profissional, Familiar (EDUCATIVA), desenrola-se segundo valores pouco sólidos…” (p.126). É esse progressivo apagar de valores e emoções que orienta a vida dos cidadãos que Sennett chama de “Corrosão do Caráter”. Nessa direção, pretendemos fazer um exercício teórico e recuperar a memória antropológica e ontológica ao enfatizar a livre motricidade e o lazer como instrumentos da “naturalidade humana” que sempre estiveram a serviço do seu equilíbrio (emocional) e da sua felicidade, e, também, posicionar a educação emocional nesse contexto do núcleo familiar.

Maternidade e parentalidade: reconfigurações e conflitos ideológicos

(Excerto) A construção da maternidade como o acto paradigmático de cuidado adequado deve ser vista como uma construção cultural específica. É comum conceber o cuidado como uma relação entre duas pessoas e especialmente como uma relação entre mãe e filho. Como observa Joan Tronto, uma tal compreensão conduziu frequentemente à idealização deste duo que se converteu numa espécie de casal romântico no discurso contemporâneo ocidental sobre a maternidade (Tronto, 1993, pp. 103, 109-110). A ênfase ideológica na díade mãe/filho subsiste, não obstante revestir-se de novos cambiantes e ser paralela à valorização da paternidade reflectida numa diversidade de estudos (e.g. Monteiro & Domingos, 2013; Torres, 2002) e nas práticas sociais.

Titanium oxide adhesion layer for high temperature annealed Si/Si3N4/TiOx/Pt/LiCoO2 battery structures

This work describes the influence of a high annealing temperature of about 700C on the Si(substrate)/Si3N4/TiOx/Pt/LiCoO2 multilayer system for the fabrication of all-solid-state lithium ion thin film microbatteries. Such microbatteries typically utilize lithium cobalt oxide (LiCoO2) as cathode material with a platinum (Pt) current collector. Silicon nitride (Si3N4) is used to act as a barrier against Li diffusion into the substrate. For a good adherence between Si3N4 and Pt, commonly titanium (Ti) is used as intermediate layer. However, to achieve crystalline LiCoO2 the multilayer system has to be annealed at high temperature. This post-treatment initiates Ti diffusion into the Pt-collector and an oxidation to TiOx, leading to volume expansion and adhesion failures. To solve this adhesion problem, we introduce titanium oxide (TiOx) as an adhesion layer, avoiding the diffusion during the annealing process. LiCoO2, Pt and Si3N4 layers were deposited by magnetron sputtering and the TiOx layer by thermal oxidation of Ti layers deposited by e-beam technique. Asdeposited and annealed multilayer systems using various TiOx layer thicknesses were studied by scanning electron microscopy (SEM) and time-of-flight secondary ion mass spectrometry (ToF-SIMS) and x-ray photoelectron spectroscopy (XPS). The results revealed that an annealing process at temperature of 700C leads to different interactions of Ti atoms between the layers, for various TiOx layer thicknesses (25–45 nm).

The display gamut available to simulate colors perceived by anomalous trichromats

The aim of this work was to investigate the effect on a display gamut of varying the optical density and the position of the maximum sensitivity of the cones spectra of anomalous trichromatic observers. The anomalous cone spectral sensitivities were estimated for a set of varying optical density and maximum sensitivity spectra conditions and used to compute the display color gamut. The computed display gamut simulated for normal observers the chro- matic diversity perceived by anomalous observers. It was found that even small variations on the optical density and on the position of the maximum sensitivity spectra have an impact on the simulations of the display gamut for anomalous observers. It was also found that simulations for deuteroanomalous observers are the ones with greater impact if the estimation of the corresponding color display gamut is not carefully adjusted for the observer.

A study of risk-aware program transformation

In the trend towards tolerating hardware unreliability, accuracy is exchanged for cost savings. Running on less reliable machines, functionally correct code becomes risky and one needs to know how risk propagates so as to mitigate it. Risk estimation, however, seems to live outside the average programmer’s technical competence and core practice. In this paper we propose that program design by source-to-source transformation be risk-aware in the sense of making probabilistic faults visible and supporting equational reasoning on the probabilistic behaviour of programs caused by faults. This reasoning is carried out in a linear algebra extension to the standard, `a la Bird-Moor algebra of programming. This paper studies, in particular, the propagation of faults across standard program transformation techniques known as tupling and fusion, enabling the fault of the whole to be expressed in terms of the faults of its parts.

Mother’s depression at childbirth does not contribute to the effects of antenatal depression on neonate’s behavioral development

Background: Maternal depression is a worldwide phenomenon that has been linked to adverse developmental outcomes in neonates. Aims: To study the effect of antenatal depression (during the third trimester of pregnancy) on neonate behavior, preference, and habituation to both the mother and a stranger’s face/voice. To analyze mother’s depression at childbirth as a potential mediator or moderator of the relationship between antenatal depression and neonate behavioral development. Method: A sample of 110 pregnant women was divided in 2 groups according to their scores on the Edinburgh Postnatal Depression Scale during pregnancy (EPDS; ≥10, depressed; <10, non-depressed). In the first 5 days after birth, neonatal performance on the Neonatal Behavioral Assessment Scale (NBAS) and in the ‘Preference and habituation to the mother’s face/voice versus stranger’ paradigm was assessed; each mother filled out an EPDS. Results: Neonates of depressed pregnant women, achieved lower scores on the NBASs (regulation of state, range of state, and habituation); did not show a visual/auditory preference for the mother’s face/voice; required more trials to become habituated to the mother’s face/voice; and showed a higher visual/auditory preference for the stranger’s face/voice after habituation compared to neonates of non-depressed pregnant women. Depression at childbirth does not contribute to the effect of antenatal depression on neonatal behavioral development. Conclusion: Depression even before childbirth compromises the neonatal behavioral development. Depression is a relevant issue and should be addressed as a routine part of prenatal health care.