6 resultados para Igreja de S. Bartolomeu da Charneca (Lisboa, Portugal)

em Universidade do Minho


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One of the most popular approaches to path planning and control is the potential field method. This method is particularly attractive because it is suitable for on-line feedback control. In this approach the gradient of a potential field is used to generate the robot's trajectory. Thus, the path is generated by the transient solutions of a dynamical system. On the other hand, in the nonlinear attractor dynamic approach the path is generated by a sequence of attractor solutions. This way the transient solutions of the potential field method are replaced by a sequence of attractor solutions (i.e., asymptotically stable states) of a dynamical system. We discuss at a theoretical level some of the main differences of these two approaches.

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Mycotoxins are toxic secondary metabolites produced by certain moulds, being ochratoxin A (OTA) one of the most relevant. Its chemical structure is a dihydro-isocoumarin connected at the 7-carboxy group to a molecule of L--phenylalanine via an amide bond. OTA contamination of wines might be a risk to consumer health, thus requiring treatments to achieve acceptable standards for human consumption [1]. According to the Regulation No. 1881/2006 of the European Commission, the maximum limit for OTA in wine is 2 µg/kg [2]. Therefore, the aim of this work was to know the effect of different fining agents on OTA removal, as well as their impact on white and red wine physicochemical characteristics. To evaluate their efficiency, 11 commercial fining agents (mineral, synthetic, animal and vegetable proteins) were used to get new approaches on OTA removal from white and red wines. Trials were performed in wines artificially supplemented (at a final concentration of 10 µg/L) with OTA. The most effective fining agent in removing OTA (80%) from white wine was a commercial formulation that contains gelatine, bentonite and activated carbon. Removals between 10-30% were obtained with potassium caseinate, yeast cell walls and pea protein. With bentonites, carboxymethylcellulose, polyvinylpolypyrrolidone and chitosan no considerable OTA removal was verified. In red wine, removals between 6-19% were obtained with egg albumin, yeast cell walls, pea protein, isinglass, gelatine, polyvinylpolypyrrolidone and chitosan. The most effective fining agents in removing OTA from red wine were an activated carbon (66%) followed again by the commercial formulation (55%), being activated carbon a well-known adsorbent of mycotoxins. These results may provide useful information for winemakers, namely for the selection of the most appropriate oenological product for OTA removal, reducing wine toxicity and simultaneously enhancing food safety and wine quality.

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The presence of mycotoxins in foodstuff is a matter of concern for food safety. Wines can also be contaminated with these toxicants. Several authors have demonstrated the presence of mycotoxins in wine, especially ochratoxin A (OTA) [1]. As these toxicants can never be completely removed from the food chain, many countries have defined levels in food in order to attend health concerns. The maximum acceptable level of OTA in wines is 2.0 µg/kg according to the Commission regulation No. 1881/2006 [2]. Although, higher levels of OTA have been detected in several wine samples. In order to reduce OTA to safer levels, several oenological products can be used in wine; including activated carbons, as shown in previous experiments. Regarding this, the aim of present study was to evaluate the effectiveness of several activated carbons for reducing the amount of OTA present in white and red wines as well as to evaluate their effect on wines physicochemical characteristics. Wine samples were artificially supplemented with OTA at a final concentration of 10.0 µg/L. The different activated carbons were applied at the concentration recommended by the manufacturer in order to evaluate their efficiency in reducing OTA levels. A mixture composed by gelatine, bentonite and activated carbon reduced 80% of OTA concentration in white wine. The same mixture was however less efficient in red wine, achieving only a reduction of 55%. Thereafter, the effect of activated carbon was evaluated in a red wine, achieving reductions of 66%. Considering these results more assays are being performed with other commercial activated carbons, in order to evaluate their efficiency. These results may provide valuable information for winemakers. Knowing the effect of commercial activated carbons they may choose most appropriate products to remove OTA, thus enhancing wine safety and quality.

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Tese de Doutoramento em Ciências da Cultura - Especialidade em Culturas do Extremo Oriente

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As modernas ideias científicas e tecnológicas da Europa mais desenvolvida transpoem fronteiras e institucionalizam-se em Portugal com a denominada Reforma Pombalina da Universidade de Coimbra (1770-72), no reinado de D. Jos. Mais: não s chega a Portugal o pensamento moderno da época como, antecipando a reforma do ensino universitário no resto da Europa, o ensino universitário português faz uma aposta clara nas ciências matemáticas,sicas e naturais, bem como num ensino experimental/laboratorial. Anos mais tarde, no reinado de D. Maria, surgem outros projectos educativos e científicos igualmente modernos tais como o da criação de uma Academia Real da Marinha (1779) ou o de uma Academia Real das Ciências (1779) e idealiza-se um projeto, porventura, ainda mais revolucionário: o da criação de uma instituição de ensino – também de ciências ditas superiores destinada, na sua génese, a orfãos e desvalidos à qual se chamou Casa Pia de Lisboa (1780), e que alguns autores reportam como sendo uma “universidade plebeia”. Com base em documentação autógrafa, ainda inédita, recentemente descoberta nos Fundos Setecentistas do Arquivo da Casa de Mateus, exploraremos o papel fundamental que Jos Anastácio da Cunha (1744-1787) – militar, matemático e poeta – desempenhou na concepção do Plano de Estudos para a instituição; em particular para o colégio de S. Lucas, consagrado às classes científicas.

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Tese de Doutoramento em Engenharia Industrial e de Sistemas