Effect of heat-treatment on strength of clays

The main objective of this investigation was to understand the strength development of clays below fusion or vitrification temperatures of 900°C. The other objective was to establish threshold temperatures to produce a satisfactory construction material from clayey sediments from the Western Beaufort Sea for shore protection of artificial islands with minimum expense of thermal energy. Studies were, therefore, conducted using kaolinite, bentonite, and a clayey sediment from the Beaufort Sea. Unconfined-compressive-strength tests were conducted on clay samples heat treated from 110 to 700°C. Furthermore, to understand the factors responsible for strength-development-thermogravimetric studies and pore-size analysis, using mercury porosimetry, were also conducted. A gradual increase in strength was obtained with an increase in firing temperature. However, substantial and permanent increase in strength occurred only after dehydroxylation of all the clays studied; Clay samples heated to temperatures above dehydroxylation became resistant to disintegration upon immersion in water. Results indicate that the clayey sediments from Western Beaufort Sea have to be heat treated to about 600°C to produce granular material for use as a fill or shore-protection material for artificial islands.

Calculation of elastic pinning strength of semicoherent Y2BaCuO5 precipitates in YBa2Cu3O7

The pinning energy due to the elastic interaction of a semicoherent Y2BaCuO5 precipitate with the YBa2Cu3O7 matrix is computed. This is achieved by setting up dislocation arrays at the interface. The elastic stresses generated by such arrays are integrated over a fluxoid volume to obtain the energy. It is seen that this elastic interaction energy makes an additive contribution to the total J(c) value.

Multifractal analysis, a method to investigate the morphology of materials

Using the multifractal formalism, we discuss the results obtained to characterized the morphology of polymer alloys and granular discontinuous metallic thin films. In the first case we have found a correlation between the multifractality and the mechanical properties of the alloys. In the second case, we have found that it is possible to measure the differences between the morphology of thin films induced by a growth process on a subtrate and that of percolation clusters of the classical theory of percolation.

Combustion synthesis and properties of the NASICON family of materials

The fine-particle NASICON family of materials, MZr2P3O12(where M = Na, K, ½Ca and ¼Zr) and NbZrP3O12, have been prepared by the combustion of aqueous heterogeneous mixtures of stoichiometric amounts of metal nitrate, zirconyl nitrate, niobium phosphate, diammonium hydrogen phosphate, ammonium perchlorate and carbohydrazide (CH) at 400 °C. The formation of NASICON materials was confirmed by powder X-ray diffraction (XRD), IR, solid-state (31P) NMR spectroscopy and thermal expansion coefficient measurements. The combustion-synthesized NASICON powders have an average agglomerate size of 9�13 µm with a specific surface area varying from 8 to 28 m2 g�1. The powders pelletized and sintered in the range 1100�1200 °C for 5 h achieved 95�97% theoretical density and showed fine-grain microstructure. The coefficient of thermal expansion of a sintered compact was measured up to 500 °C and ranged from �1.5 × 10�6°C�1 to 1.0 × 10�6°C�1 depending on the composition.

Punching shear strength of flat slab corner column connections .1. Reinforced concrete connections

This paper presents the details of an experimental study on punching shear strength and behaviour of reinforced concrete corner column connections in flat slabs; a quasi-empirical method is proposed for computing the punching shear strength. The method has also been extended for punching shear strength prediction at interior and edge column connections. The test results compare better with the strengths predicted by the proposed method than those by Ingvarson, Zaglool and Pollet available in the literature. Further, the experimental strengths of interior, edge and corner column connections have been compared with the strengths predicted by the proposed method and the two codes of practice, viz. ACI and BS code, to demonstrate the usefulness of the method.

Punching shear strength of flat slab corner column connections .2. Fibre-reinforced concrete connections

This paper gives the details of the studies undertaken to examine the strength and behaviour of fibre-reinforced concrete corner column connections in flat slabs. Tests have been conducted on 16 specimens with varying reinforcement ratio, moment/shear ratio (load eccentricity) and volume fraction of fibres. A quasi-empirical method has been proposed for computing the punching shear strength. The method has also been extended to fibre-reinforced concrete interior column connections, tests on which are available in the literature. The test results have been compared with the strength predicted by the proposed method for corner column as well as interior column connections and a satisfactory agreement noticed.

A finite element assessment of flexural strength of prestressed concrete beams with fiber reinforcement

This paper presents an assessment of the flexural behavior of 15 fully/partially prestressed high strength concrete beams containing steel fibers investigated using three-dimensional nonlinear finite elemental analysis. The experimental results consisted of eight fully and seven partially prestressed beams, which were designed to be flexure dominant in the absence of fibers. The main parameters varied in the tests were: the levels of prestressing force (i.e, in partially prestressed beams 50% of the prestress was reduced with the introduction of two high strength deformed bars instead), fiber volume fractions (0%, 0.5%, 1.0% and 1.5%), fiber location (full depth and partial depth over full length and half the depth over the shear span only). A three-dimensional nonlinear finite element analysis was conducted using ANSYS 5.5 [Theory Reference Manual. In: Kohnke P, editor. Elements Reference Manual. 8th ed. September 1998] general purpose finite element software to study the flexural behavior of both fully and partially prestressed fiber reinforced concrete beams. Influence of fibers on the concrete failure surface and stress-strain response of high strength concrete and the nonlinear stress-strain curves of prestressing wire and deformed bar were considered in the present analysis. In the finite element model. tension stiffening and bond slip between concrete and reinforcement (fibers., prestressing wire, and conventional reinforcing steel bar) have also been considered explicitly. The fraction of the entire volume of the fiber present along the longitudinal axis of the prestressed beams alone has been modeled explicitly as it is expected that these fibers would contribute to the mobilization of forces required to sustain the applied loads across the crack interfaces through their bridging action. A comparison of results from both tests and analysis on all 15 specimens confirm that, inclusion of fibers over a partial depth in the tensile side of the prestressed flexural structural members was economical and led to considerable cost saving without sacrificing on the desired performance. However. beams having fibers over half the depth in only the shear span, did not show any increase in the ultimate load or deformational characteristics when compared to plain concrete beams. (C) 2002 Published by Elsevier Science Ltd.

Nature and strength of C-H center dot center dot center dot O interactions involving formyl hydrogen atoms: computational and experimental studies of small aldehydes

Structural and electronic properties of C-H center dot center dot center dot O contacts in compounds containing a formyl group are investigated from the perspective of both hydrogen bonding and dipole-dipole interactions, in a systematic and graded approach. The effects of a-substitution and self-association on the nature of the formyl H-atom are studied with the NBO and AIM methodologies. The relative dipole-dipole contributions in formyl C-H center dot center dot center dot O interactions are obtained for aldehyde dimers. The stabilities and energies of aldehyde clusters (dimer through octamer) have been examined computationally. Such studies have an implication in crystallization mechanisms. Experimental X-ray crystal structures of formaldehyde, acrolein and N-methylformamide have been determined in order to ascertain the role of C-H center dot center dot center dot O interactions in the crystal packing of formyl compounds.

Enhancement of Strength of Soft Soils with Fly ash and Lime

Disposal of large quantities of fly ash poses a major environmental problem. To enhance its utilization, fly ash is considered for stabilizing of expansive soft soils. Improving the strength of soil, which is of major importance, depends on the pozzolanic nature of fly ash. Fly ashes with high pozzolanic reactivity are widely used but those with less pozzolanic reactivity are greatly inhibited. As the strength development in natural expansive soil considered in this investigation is very less with different percentages of fly ash, an attempt is made to increase the same by addition of lime along with fly ash. Based on several tests conducted, the optimum lime contents for fly ash and soils are 5% and 8% respectively. The strength of compacted soil with different fly ash contents of 10 to 40% with lime contents of 5% and 8% are determined after curing for different periods. The strength improvement for any soil-fly ash mixture, which is substantial with 5% of lime, is further improved with 8% of lime. The strength of soil-fly ash mixtures with any lime content increases with curing period.