Encapsulation of Eu(TTA)(3) into MCM-41 mesoporous molecular sieve by sol-gel method

The rare earth complex Eu(TTA)(3) was successfully encapsulated into MCM-41 mesoporous molecular sieve by the addition of the complex into the sol-gel mixture for the synthesis of MCM-41 mesoporous material under microwave radiation. The as-synthesized MCM-41-hosted Eu(TTA)(3) mesophase was confirmed to possess hexagonally ordered mesostructure and a uniform crystal. size of about 30 nm with XRD and HRTEM techniques. Moreover, the IR spectrum, photoluminescence effect and fluorescence lifetime of the Eu(TTA)(3)/MCM-41 hybrid were also studied. An increase in Stokes' shift and no change in luminescence lifetime were observed to the resultant mesophase in comparison with Eu(TTA)(3) in ethanol solution.

An encapsulation of the rare earth complex in modified mesoporous molecular sieve MCM-41

The encapsulation of a rare earth (RE) complex Eu(DBM)(3)phen in modified S1-MCM-41 with 3-aminopropyltriethoxysilane is reported for the first time. The luminescence intensity of the RE complex in the modified Si-MCM-41 is about 9 times as strong as in unmodified Si-MCM-41 and the luminescence of the RE complex in the modified SI-MCM-41 has good color purity.

Encapsulation of fluorescein into MCM-41 mesoporous molecular sieve by a sol-gel method

MCM-41-hosted fluorescein mesophase was prepared by addition of the dye into the sol-gel mixture for the synthesis of MCM-41 mesoporous molecular sieve under microwave radiation. The as-synthesized organo-silica-surfactant material possessed hexagonal mesostructure with short-range symmetry and a uniform nanosize of about 30 nm. Furthermore, fluorescence spectrum, increase in lifetime and lack of aggregation at high concentration were discussed in terms of the effect of the host-guest interaction on these properties. (C) 2001 Published by Elsevier Science B.V.

Electrochemical behavior of heteropoly acid anions adsorbed in electrodes modified with mesoporous molecular sieve silica

Heteropoly acid H4SiW12O48 (denoted as SiW12) was assembled with the mesoporous materials MCM-41 modified with 3-aminopropyltriethoxysilane (APTES) (denote MCM-41((m))). The electrochemical behavior of SiW12/MCM-41((m)) complexes-based electrode indicated SiW12 anion was adsorbed by MCM-41((m)). In MCM-41((m)) electrode, large voltammetric waves, showing that the electrostatic bound ions adsorbed in MCM-41((m)) were electrochemically active. The potential application as amperometric sensors for nitrite is anticipated.

Direct synthesis and characterization of titanium-substituted mesoporous molecular sieve SBA-15

Ti-substituted mesoporous SBA-15 (Ti-SBA-15) materials have been synthesized by using a new approach in which the hydrolysis of the silicon precursor (tetramethoxysilane, TMOS) is accelerated by fluoride. These materials were characterized by powder X-ray diffraction patterns (XRD), X-ray fluorescence spectroscopy (Y-RF), N-2 sorption isotherms, diffuse-reflectance UV-visible (UV-vis) and UV-Raman spectroscopy, Si-29 MAS NMR, and the catalytic epoxidation reaction of styrene. Experiments show that Ti-SBA-15 samples of high quality can be obtained under the following conditions: F/Si greater than or equal to 0.03 (molar ratio), pH less than or equal to 1.0, aging temperature less than or equal to 80 degreesC, and Ti/Si less than or equal to 0.01. It was found that the hydrolysis rate of TMOS was remarkably accelerated by fluoride, which was suggested to play the main role in the formation of Ti-SBA-15 materials of high quality. There is no stoichiometric incorporation of Ti, and the Ti contents that are obtained are quite low in the case of the approach that is proposed. The calcined Ti-SBA-15 materials show highly catalytic activity in the epoxidation of styrene.

Influence of 3A molecular sieve to tetrahydrofuran(THF) hydrate formation

Visual observation of the THF hydrate formation process in the presence of a 3A molecular sieve has been made at normal atmosphere and below a temperature of zero by microscopy. The results indicate that a 3A molecular sieve can induce the nucleation of the THF hydrate and promote the THF hydrate growth. With the existence of a 3A molecular sieve, the growth rate of THF hydrate is between 0.01 and 0.05 mu m/s. In comparison with the system without any 3A molecular sieve, the growth rate increases about 4 nm/s. After the THF hydrate grows into megacryst, the crystals will recombine and partially change under the same condition.

Immobilization of the heteropoly acid (HPA) H4SiW12O40 (SiW12) on mesoporous molecular sieves (HMS and MCM-41) and their catalytic behavior

Supported catalysts, consisting of SiW12 immobilized on hexagonal mesoporous silica (HMS) and its aluminum-substituted derivative (MCM-41) with different loadings and calcination temperatures, have been prepared and characterized by X-ray diffraction, FT-IR and NH3-temperature programmed desorption. It is shown that SiW12 retains the Keggin structure on the mesoporous molecular sieves and no HPA crystal phase is developed, even at SiW12 loadings as high as 50 wt%. In the esterification of acetic acid by n-butanol, supported catalysts exhibit a higher catalytic activity and stability and held some promise of practical application. In addition, experimental results indicate that the loaded amount of SiW12 and the calcination temperatures have a significant influence on the catalytic activity, and the existence of aluminum has also an effect on the properties of supported catalysts.

Direct spectroscopic evidence for vanadium species in V-MCM-41 molecular sieve characterized by UV resonance Raman spectroscopy

Vanadium species in tetrahedral and octahedral coordination in V-MCM-41 molecular sieve are characterized by UV resonance Raman bands at 1070 and 930 cm(-1) respectively.

Synthesis of FeCoMnAPO-5 molecular sieve and catalytic activity in cyclohexane oxidation by oxygen

A new FeCoMnAPO-5 with AFI structure was synthesized under hydrothermal conditions and characterized by XRD, FT-IR, X-ray fluorescence, nitrogen adsorption and SEM. The oxidation of cyclohexane with molecular oxygen was studied over the catalyst at 403 K. It show d higher activity compared to FeAPO-5, CoAPO-5 and MnAPO-5. The FeCoMnAPO-5 catalyst was recycled twice without loss of activity or selectivity.