液相外延法制备β-BBO薄膜

采用液相外延法在掺Sr^2＋的Q—BBO（001）衬底上制备了β-BBO薄膜，研究了制备条件对薄膜质量的影响．结果表明：当生长温度为810℃时，转速为300r／min生长的外延膜具有较高的结晶质量，且随着生长时间的延长，外延膜的结晶质量有所提高．β—BBO薄膜呈C轴高度择优取向，薄膜的双晶摇摆曲线半峰宽值FWHM仅为676．6”，表明β-BBO薄膜较好的结晶质量；在不具备相位匹配的条件下，β—BBO外延膜也能够实现二次谐波输出．

Fractography and Crack Initiation of Very-High-Cycle Fatigue for a High Carbon Low Alloy Steel

Very-High-Cycle Fatigue (VHCF) is the phenomenon of fatigue damage and failure of metallic materials or structures subjected to 108 cycles of fatigue loading and beyond. This paper attempts to investigate the VHCF behavior and mechanism of a high strength low alloy steel (main composition: C-1% and Cr-1.5%; quenched at 1108K and tempered at 453K). The fractography of fatigue failure was observed by optical microscopy and scanning electron microscopy. The observations reveal that, for the number of cycles to fatigue failure between 106 and 4108 cycles, fatigue cracks almost initiated in the interior of specimen and originated at non-metallic inclusions. An “optical dark area” (ODA) around initiation site is observed when fatigue initiation from interior. ODA size increases with the decrease of fatigue stress, and becomes more roundness. Fracture mechanics analysis gives the stress intensity factor of ODA, which is nearly equivalent to the corresponding fatigue threshold of the test material. The results indicate that the fatigue life of specimens with crack origin at the interior of specimen is longer than that with crack origin at specimen surface. The experimental results and the fatigue mechanism were further analyzed in terms of fracture mechanics and fracture physics, suggesting that the primary propagation of fatigue crack within the fish-eye local region is the main characteristics of VHCF.

Organic/inorganic nanocomposite polymer electrolyte

The organic/inorganic nanocomposites polymer electrolytes were designed and synthesized. The organic/inorganic nanocomposites membrane materials and their lithium salt complexes have been found thermally stable below 200 degrees C. The conductivity of the organic/inorganic nanocomposites polymer electrolytes prepared at room temperature was at magnitude range of 10(-6) S/cm. (c) 2007 Li Qi. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

Preparation and luminescence properties of sol-gel hybrid materials incorporated with europium complexes

Microporous silica gel has been prepared by the sol-gel method utilizing the hydrolysis and polycondensation of tetraethylorthosilicate (TEOS). The gel has been doped with the luminescent ternary europium complex Eu(TTA)(3). phen: where HTTA = 1-(2-thenoyl)-3,3,3-trifluoracetone and phen = 1,10-phenanthroline. By contrast to the weak f-f electron absorption bands of Eu3+, the complex organic ligand exhibits intense near ultraviolet absorption. Energy transfer from the ligand to Eu3+ enables the production of efficient, sharp visible luminescence from this material. Utilizing the polymerization of methyl methacrylate or ethyl methacrylate, the inorganic/polymer hybrid materials containing Eu(TTA)(3). phen have also been obtained. SEM micrographs show uniformly dispersed particles in the nanometre range. The characteristic luminescence spectral features of europium ions are present in the emission spectra of the hybrid material doped with Eu(TTA)3 phen. (C) 2000 Kluwer Academic Publishers.

In Situ Synthesis of Nanocrystalline Intermetallic Compound Layer During Surface Mechanical Attrition Treatment of Zirconium

The surface mechanical attrition treatment (SMAT) technique was developed to synthesize a nanocrystalline (NC) layer on the surface of metallic materials for upgrading their overall properties and performance. In this paper, by means of SMAT to a pure zirconium plate at the room temperature, repetitive multidirectional peening of steel shots (composition (wt%): 1C, 1.5Cr, base Fe) severely deformed the surface layer. A NC surface layer consisting of the intermetallic compound FeCr was fabricated on the surface of the zirconium. The microstructure characterization of the surface layer was performed by using X-ray diffraction analysis, optical microscopy, scanning and transmission electron microscopy observations. The NC surface layer was about 25 mu m thick and consisted of the intermetallic compound FeCr with an average grain size of 25 +/- 10 nm. The deformation-induced fast diffusion of Fe and Cr from the steel shots into Zr occurred during SMAT, leading to the formation of intermetallic compound. In addition, the NC surface layer exhibited an ultrahigh nanohardness of 10.2 GPa.

合金材料超高周疲劳行为的基本特征和影响因素

合金材料在超高周疲劳下具有与低周和高周疲劳不同的裂纹萌生和扩展行为以及不同的S-N曲线特征.材料的强度、循环加载的频率、所处的环境等都显著影响超高周疲劳的特性.本文综述了合金材料超高周疲劳行为的基本特征和影响因素的研究进展.

新一代无机相变光存储材料研究进展

光存储技术正在向着大容量、高数据传输率的方向发展。新一代的光存储将从目前广泛使用的红光波段向蓝光波段发展。综述了可用于新一代高密度光存储无机相变材料的研究现状和最新进展，并对今后的发展前景进行了简要的展望。

Effect of lithium-potassium mixed alkali on spectroscopic properties of Er3+-doped aluminophosphate glasses

Er3+-doped lithium-potassium mixed alkali aluminophosphate glasses belonging to the oxide system xK(2)O-(15x)Li2O-4B(2)O(3)-11Al(2)O(3)-5BaO-65P(2)O(5) are obtained in a semi-continuous melting quenching process. Spectroscopic properties of Er3+-doped glass matrix have been analysed by fitting the experimental data with the standard Judd-Ofelt theory. It is observed that Judd-Ofelt intensity parameters-Omega(t)(t=2, 4 and 6) of Er3+ change when the second alkali is introduced into glass matrix. The variation of line strength S-ed[I-4(13/2),I-4(15/2)] follows the same trend as that of the Omega(6) parameter. The effect of mixed alkali on the spectroscopic properties of the aluminophosphate glasses, such as absorption cross-section, stimulated emission cross-section, spontaneous emission probability, branching ratio and the radiative lifetime, has also been investigated in this paper.

Investigation of high cycle and Very-High-Cycle Fatigue behaviors for a structural steel with smooth and notched specimens

The high cycle and Very-High-Cycle Fatigue (VHCF) properties of a structural steel with smooth and notched specimens were studied by employing a rotary bending machine with frequency of 52.5 Hz. For smooth specimens, VHCF failure did occur at fatigue cycles of 7.1 x 10(8) with the related S-N curve of stepwise tendency. Scanning Electron Microscopy (SEM) was used for the observations of the fracture surfaces It shows that for smooth specimens the crack origination is surface mode in the failure regime of less than 10(7) cycles While at VHCF regime, the material failed from the nonmetallic inclusion lies in the interior of material, leading to the formation of fisheye pattern. The dimensions of crack initiation region were measured and discussed with respect to the number of cycles to failure. The mechanism analysis by means of low temperature fracture technique shows that the nonmetallic inclusion in the interior of specimen tends to debond from surrounding matrix and form a crack. The crack propagates and results to the final failure. The stress intensity factor and fatigue strength were calculated to investigate the crack initiation properties. VHCF study on the notched specimens shows that the obtained S-N curve decreases continuously. SEM analysis reveals that multiple crack origins are dominant on specimen surface and that fatigue crack tends to initiate from the surface of the specimen. Based on the fatigue tests and observations, a model of crack initiation was used to describe the transition of fatigue initiation site from subsurface to surface for smooth and notched specimens. The model reveals the influences of load, grain size, inclusion size and surface notch on the crack initiation transition. (C) 2010 Elsevier Ltd. All rights reserved

Development of an intermediate energy heavy-ion micro-beam irradiation system

The micro-beam irradiation system, which focuses the beam down to micron order and precisely delivers a predefined number of ions to a predefined spot of micron order, is a powerful tool for radio-biology, radio-biomedicine and micromachining. The Institute of Modern Physics of Chinese Academy of Sciences is developing a heavy-ion microbeam irradiation system up to intermediate energy. Based on the intermediate and low energy beam provided by Heavy Ion Research Facility of Lanzhou, the micro-beam system takes the form of the magnetic focusing. The heavy-ion beam is conducted to the basement by a symmetrical achromatic system consisting of two vertical bending magnets and a quadrupole in between. Then a beam spot of micron order is formed by a magnetic triplet quadrupole of very high gradient. The sample can be irradiated either in vacuum or in the air. This system will be the first opening platform capable of providing heavy ion micro-beam, ranging from low (10MeV/u) to intermediate energy (100MeV/u), for irradiation experiment with positioning and counting accuracy. Target material may be biology cell, tissue or other non-biological materials. It will be a help for unveiling the essence of heavy-ion interaction with matter and also a new means for exploring the application of heavy-ion irradiation.

Europium complexes immobilization on titania via chemical modification of titanium alkoxide

We report a facile strategy to tether lanthanide complexes to organic-inorganic hybrid titania materials via sol-gel processing by employing chemically modified titanium alkoxide as the precursor where the organic ligand sensitizing the luminescence of lanthanide ions is bonded to titanium.

从字形到语义：跨语言Stroop效应的ERP研究

According to the influential dual-route model of reading (Coltheart, Rastle et al. 2001), there are two routes to access the meaning of visual words: one directly by orthography (orthography-semantic) and the other indirectly via the phonology (phonology-semantic). Because of the dramatic difference between written Chinese and alphabetical languages, it is still on debate whether Chinese readers have the same semantic activation processes as readers of alphabetical languages. In this study, the semantic activation processes in alphabetical German and logographic Chinese were compared. Since the N450 for incongruent color words in the Stroop tasks was induced by the semantic conflict between the meaning of the incongruent color words and color naming, this component could be taken as an index for semantic activation of incongruent color words in Stroop tasks. Two cross-script Stroop experiments were adopted to investigate the semantic activation processes in Chinese and German. The first experiment focused on the the role of phonology, while the second one focused on the realative importance of orthography. Cultural differences in cognitive processing between individuals in western and eastern countries have been found (Nisbett & Miyamoto, 2005). In order to exclude potential differences in basic cognitive processes like visual discrimination capabilities during reading, a visual Oddball experiment with non-lexical materials was conducted with all participants. However, as indicated by the P300 elicited by deviant stimuli in both groups, no group difference was observed. In the first Stroop experiments, color words (e.g., “green”), color-word associates (e.g., “grass”), and homophones of color words were used. These words were embedded into color patches with either congruent color (e.g. word “green” in green color patch) or incongruent colors (e.g. word “green” in either red or yellow or blue color patch). The key point is to observe whether homophones in both languages could induce similar behavioral and ERP Stroop effects to that induced by color words. It was also interesting to observe to which extent the N450 was related to the semantic conflicts. Nineteen Chinese adult readers and twenty German adult readers were asked to respond to the back color of these words in the Stroop experiment in their native languages by pressing the corresponding keys. In the behavioral data, incongruent conditions (incongruent color words, incongruent color-word associates, incongruent homophones) had significantly longer reaction times as compared to corresponding congruent conditions. All incongruent conditions in the Geman group elicited an N450 in the 400 to 500 ms time window. In the Chinese group, the N450 in the same time window was also observed for the incongruent color words and incongruent color-word associates. These results indicated that the N450 was very sensitive to semantic conflict-even words with semantic association to colors (e.g. “grass”) could elicite similar N450. However, the N450 was absent for incongruent homophones of color words in the Chinese group. Instead, in a later time window (600-800 ms), incongruent homophones elicited a positivity over left posterior regions as compared to congruent homophones. Similar positivity was also observed for color words in the 700 to 1000 ms time window in the Chinese group and 600 to 1000 ms time window for incongruent color words and homophones in the Geman group. These results indicate that phonology plays an important role in Geman semantic activation processes, but not in Chinese. In the second Stroop experiment, color words and pseudowords which had similiar visual shape to color words in both languages were used as materials. Another group of eighteen Chinese and twenty Germans were involved in the Stroop experiment in their native languages.The ERPs were recorded during their performance. In the behavioral data, strong and comparable Stroop effects (as counted by substract the reaction times in the congruent conditions from reaction times in the incongruent conditions) were observed. In the ERP data, both incongruent color words and incongruent pseudowords elicited an N450 over the whole brain scalp in both groups. These results indicated that orthography played an equally important role in semantic activation processes in both languages. The results of the two Stroop experiments support the view that the semantic activation process in Chiense readers differs significantly from that in German readers. The former rely mainly on the direct route (orthography-semantic), while the latter use both direct route and incirect route (phonology-semantic). These findings also indicate that the characteritics of different languages shape the semantic activation processes.