Time-dependent density-functional calculations for optical spectra of Na-2 and Na-4 clusters

With the frame of the time-dependent local density approximation, an efficient description of the optical response of clusters has been used to study the photo-absorption cross section of Na-2 and Na-4 clusters. It is shown that our calculated results are in good agreement with the experiment. In addition, our calculated spectrum for the Na-4 cluster is in better agreement with experiment than the GW absorption spectrum.

Cross-correlation between WMAP and 2MASS: non-Gaussianity induced by the SZ effect

We study the non-Gaussianity induced by the Sunyaev-Zel'dovich (SZ) effect in cosmic microwave background (CMB) fluctuation maps. If a CMB map is contaminated by the SZ effect of galaxies or galaxy clusters, the CMB maps should have similar non-Gaussian features to the galaxy and cluster fields. Using the WMAP data and 2MASS galaxy catalogue, we show that the non-Gaussianity of the 2MASS galaxies is imprinted on WMAP maps. The signature of non-Gaussianity can be seen with the fourth-order cross-correlation between the wavelet variables of the WMAP maps and 2MASS clusters. The intensity of the fourth-order non-Gaussian features is found to be consistent with the contamination of the SZ effect of 2MASS galaxies. We also show that this non-Gaussianity can not be seen by the high-order autocorrelation of the WMAP. This is because the SZ signals in the autocorrelations of the WMAP data generally are weaker than the WMAP-2MASS cross-correlations by a factor f(2), which is the ratio between the powers of the SZ-effect map and the CMB fluctuations on the scale considered. Therefore, the ratio of high-order autocorrelations of CMB maps to cross-correlations of the CMB maps and galaxy field would be effective to constrain the powers of the SZ effect on various scales.

Construction of coordination networks with high connectivity: a new 8-connected self-penetrating network based on tetranuclear metal clusters

Two highly connected cobalt(II) and zinc(II) coordination polymers with tetranuclear metal clusters as the nodes of network have been prepared, being the first example of an 8-connected self-penetrating net based on a cross-linked alpha-Po subnet.

Electron collision cross sections and rate coefficients for the Na-like Cu ion

Collision cross sections are calculated using the R-matrix method for excitations between the three lowest LS states for Na-like Cu ion. The complex resonance structures are investigated. The collision rate coefficients have been calculated assuming a Maxwellian distribution of electron-impact energies. The results of the collision cross sections are in good agreement with those of the other theory.