14 resultados para National Research Council Canada
em Chinese Academy of Sciences Institutional Repositories Grid Portal
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We present the design and numerical simulation results for a silicon waveguide modulator based on carrier depletion in a linear array of periodically interleaved PN junctions that are oriented perpendicular to the light propagation direction. In this geometry the overlap of the optical waveguide mode with the depletion region is much larger than in designs using a single PN junction aligned parallel to the waveguide propagation direction. Simulations predict that an optimized modulator will have a high modulation efficiency of 0.56 V.cm for a 3V bias, with a 3 dB frequency bandwidth of over 40 GHz. This device has a length of 1.86 mm with a maximum intrinsic loss of 4.3 dB at 0V bias, due to free carrier absorption. (C) 2009 Optical Society of America
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本文用加拿大国立研究院(National Research Council of Canada) Fuhrer等人编制的FORTRAN语言程序(以下简称NRCC程序),对两个冠醚类化合物进行了简正坐标分析,这两个化合物分子是二氧六环(C_4H_8O_2)和12-冠-4(C_8H_(16)O_4)。作者用Synder和Zerbi提出的一般价力场,计算了二氧六环的36个简正振动频率,精化四次后的结果误差为14.04 cm~(-1),得到了二氧六环的精化力场和势能分析矩阵;做了12-冠-4-的中红外光谱(3200-5000cm~(-1))。远红外光谱(500-70cm~(-1))和拉曼光谱(3200-50 cm~(-1),从而归属出12-冠-4的78个简正振动频率实验值;利用二氧六环的精化力场作为初始力场,计算了12-冠-4的简正振动频率,对78个简正振动频率进行了精化计算,精化三次后的结果误差为13.99 cm~(-1),精化后得到12-冠-4的精化力场和势能分布矩阵;将NRCC程序以BASIC语言移至TRS-80微型机上,对二氧六环进行了计算,结果良好,首次给出二氧六环一般价力场的势能分布。一、对二氧六环的处理 二氧六环分子式C_4H_8O_2,合14个原子,有3N-6=36个简正振动频率。分子结构系由二个乙氧基(-CH_2-CH_2-O-)单元组成的含有四个碳,两个氧的六元环,平衡态分子为椅式构象,属于C_(2h)点群,36个简正振动频率分为四个对称类Ag、Au、Bg和Bu,分布是:Ag 10个,Bg 8个,Au 9个,Bu9个。二氧六环的分子结构及坐标示意图见28而图5,定义了14个伸缩内坐标,26个弯曲内坐标,6个扭曲内坐标,共46个,C-C键长1.54A,C-O键长1.41 A,C-H键长1.096A,键角都用109°28'。用CART程序(NRCC程序之一)计算二氧六环14个原子的笛卡尔坐标,用GMAT程序(NRCC程序之二)计算其B矩阵和G矩阵,用FPERT程序(NRCC程序之三)计算其简正振动频率、精化力场,计算用一般价力场,引入V矩阵对称化,将46个坐标化为46个(内)对称坐标,10个多余坐标在FPERT程序计算中除去。二、对12-冠-4的处理 12-冠-4分子式C_8H_(16)O_4,含28个原子,共3N-6=78个简正振动频率,分子结构为四个乙氧基(-CH_2-CH_2-O-)单元组成的含八个碳、四个氧的12元环,自由分子的12-冠-4属于C点群。结构数据引自Groth的X光衍射分数和坐标,自己编制了BASIC语言程度将分数坐标化为笛卡尔坐标,用GMAT程序计算B矩阵和G矩阵,FPERT程序计算78个简正振动频率、精化力场、计算势能分布矩阵,引入U矩阵将92个内坐标化为92个对称坐标,14个多余坐标在FPERT程序中自动除去。三、结果 势能分布矩阵给出分子的振动归属,对这两个冠醚类分子的3N-6个简正振动频率,可以划分为五个振动区域。1.C-H伸缩振动区(3000-2800 cm~(-1)) 在该区中,二氧六环有八个值:2974、2966、2854和2867 cm~(-1)各两个,12-冠-4有16个值:2935、2923、2915和2907 cm~(-1)各两个,2860 cm~(-1)8个,高于2900 cm~(-1)者为反对称伸缩振动,低于2900 cm~(-1)者为对称伸缩振动。2.亚甲基弯曲振动之一(1500-1400 cm~(-1)) 该区的主要振动是亚甲基剪式振动(Scissor),其它振动小于10%二氧六环在该区有四个频率:1443、1461、1451和1457 cm~(-1),12-冠-4有八个频率:1466、1450、1450和1405 cm~(-1)各两个。3.亚甲基弯曲振动区二(1400-1200 cm~(-1))该区的主要振动模式为亚甲基的颤动(wag)、卷曲(twist)和摆动(rock)振动,其它振动小于13%。二氧六环在该区有八个频率:1334、1303、1396、1216、1367、1264、1377和1296 cm~(-1),12-冠-4有十六个频率:1388、1363、……1229 cm~(-1)(其中1288、1307cm~(-1)非简并,其余皆两重简并)。4.环的骨架伸缩振动区(1200-600 cm~(-1))该区振动模式复杂,除环的骨架伸缩振动外,还有亚甲基的wag、twist、rock以及环的骨架弯曲振动,而且这些振动的势能分布值都不小。二氧六环在该区有十一个频率,从1127至610 cm~(-1),12-冠-4有二十个频率,从1135至184 cm~(-1)且大都是二重简并的。5.低频区(600-50cm~(-1))这两个分子在低频区的势能分布略有差别。二氧六环在该区有五个频率:503、486、427、276和224 cm~(-1),主要振动模式为骨架弯曲振动和扭曲振动,C-O、C-C的扭曲振动在三个最低频率中分布占10-30%。12-冠-4在该区有18个频率,除570和547cm~(-1)处,都是二重简并的,六个最低频率的振动模式完全属于C-O、C-C键的扭曲振动,其它振动小于10%,所以200 cm~(-1)以下可称为12-冠-4的扭曲振动区,在600-200cm~(-1)之间的12个频率主要是骨架的弯曲振动,也有一定量的亚甲基wag、twist、rock振动。12-冠-4的简正坐标分析尚未有人做过。二氧六环的计算结果与Snyder和Zerbi的分析相吻合,12-冠-4和二氧六环两分子势能分布的相对一致性证明了对12-冠-4的简正坐标分析基本是正确的。本文比较了二分子的力常数和振动频率,探讨了环的大小对振动光谱的影响。四、NRCC程序简介 NRCC程序由CART、GMAT和FPERT三个程序组成,即可联一起运用,亦可分开独立进行运算。该程序功能强,所占内存大,适于大、中型计算机使用。CART程序之名字取自Cartisian Co-or-dinates的前四个字母,功能系由分子结构参数(键长、键角)计算分子内各原子的笛卡尔坐标。GMAT程序之名字取自G matrix的前四个字母,功能系由分子内各原子的笛卡尔坐标,原子质量和内坐标定义计算分子内各原子的坐标交换矩阵B和Wilson振动动能矩阵G。FPERT程序之名字取自F Perturbation的前五个字母,功能系由分子振动功能矩阵G、势能常数即力常数矩阵F计算分子的简正振动频率和势能分布矩阵,再通过实验频率精化势能矩阵F。NRCC程序可对含30个原子、60个内坐标的分子进行简正坐标分析,扩充后容量增大一倍。该程序可选用一般价力场(General Valence Force Field, 简称GVFF)和UBS力场(Urey-Bradley-Shimanouchi Force Field),简称UBSFF或UBFF)。可选用对称化U矩阵,可自行决定力场精化次数和阻尼常数以限制精化结果的收敛性。五、NRCC程序在TRS-80微型机上移植试尝(该部分曾在第三届长春夏季化学讨论会上宣读)针对NRCC程序占内存空间大、难以在微型机上实现的情况,作者将NRCC程序改编为BASIC语言,改变程序的原来结构,形成一组BASIC语言程序:CART/BAS、GMAT/BAS和VIFR/BAS,改编后的BASIC程序在TRS-80微型机调试通过,TRS-80机字长8位,New Dos系统内存32K。改写后的程序只保持了原程序的基本原理,在内存,语句上改动很大,以适于微型机使用。数据在程序中直接嵌入,利于修改替换,且BASIC语言简单易学,便于操作。CART/BAS程序可计算含30个原子以内的分子的笛卡尔坐标,GMAT/BAS程序可计算含20个原子、45个内坐标的分子的G矩阵,VIFR/BAS程序可计算含15个原子的分子的简正振动频率。利用这组程序,作者以二氧六环分子为例做了一些试尝运算,误差14.4 cm~(-1),相对误差1.8%,结果较理想。
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Propulsion characteristics of wing-in-ground effect propulsors were investigated using a comparative analysis of thrust and powering characteristics between wing-in-ground (WIG) effect thrusters and traditional screw propellers. WIG thrusters were found to have constant thrust production and efficiency, nearly independent of speed of advance, as contrary to screw propellers, whose optimum efficiency occurs at only one speed point. To produce the same amount of thrust as equivalent screw propellers, WIG thrusters have to work under heavily loaded operating conditions. WIG thrusters were also found to produce a relatively lower but nearly constant efficiency and thrust, independent of speed. Another distinguishing propulsion characteristic revealed for WIG thrusters is that they are capable of operating at much higher speeds, in a range of three to six times that of screw propellers of the same size. While the speed range of screw propellers is mainly limited by their geometric pitch, the speed range of WIG thrusters has no speed limit in ideal fluid. In reality, the speed range is only limited by viscous drag and cavitation, or compressibility, in water or air, respectively. This suggests a potential for WIG thrusters of higher speed application than screw propellers. An experimental investigation and validation of the propulsion system is warranted. Crown Copyright (C) 2010 Published by Elsevier Ltd. All rights reserved.
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于2010-11-23批量导入
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A design and optimization procedure developed and used for a propeller installed on a twin-semitunnel-hull ship navigating in very shallow and icy water under heavy load conditions is presented. The base propeller for this vessel was first determined using classic design routines under open-water condition with existing model test data. In the optimization process, a panel method code (PROPELLA) was used to vary the pitch values and distributions and take into account the inflow wake distribution, tunnel gap, and cavitation effects. The optimized propeller was able to improve a ship speed of 0.02 knots higher than the desired speed and 0.06 knots higher than the classic B-series propeller. The analysis of the effect of inflow wake, hull tunnel, cavitation, and blade rake angle on propulsive performance is the focus of this paper.
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Chinese Academy of Sciences ; National Science Foundation of China [41071059]; National Key Technology R&D Program of China [2008BAK50B06-02]; National Basic Research Program of China [2010CB950900, 2010CB950704]; Natural Sciences and Engineering Research Council of Canada
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Hybridization between yak Poephagus grunniens and taurine Bos taurus or indicine B. indicus cattle has been widely practiced throughout the yak geographical range, and gene flow is expected to have occurred between these species. To assess the impact of cattle admixture on domestic yak, we examined 1076 domestic yak from 29 populations collected in China, Bhutan, Nepal, India, Pakistan, Kyrgyzstan, Mongolia and Russia using mitochondrial DNA and 17 autosomal microsatellite loci. A cattle diagnostic marker-based analysis reveals cattle-specific mtDNA and/or autosomal microsatellite allele introgression in 127 yak individuals from 22 populations. The mean level of cattle admixture across the populations, calculated using allelic information at 17 autosomal microsatellite loci, remains relatively low (mY(cattle) = 2.66 +/- 0.53% and Q(cattle) = 0.69 +/- 2.58%), although it varies a lot across populations as well as among individuals within population. Although the level of cattle admixture shows a clear geographical structure, with higher levels of admixture in the Qinghai-Tibetan Plateau and Mongolian and Russian regions, and lower levels in the Himalayan and Pamir Plateau region, our results indicate that the level of cattle admixture is not significantly correlated with the altitude across geographical regions as well as within geographical region. Although yak-cattle hybridization is primarily driven to produce F-1 hybrids, our results show that the subsequent gene flow between yak and cattle took place and has affected contemporary genetic make-up of domestic yak. To protect yak genetic integrity, hybridization between yak and cattle should be tightly controlled.
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P>The non-classical major histocompatibility complex (MHC) class I molecule CD1d presents lipid antigens to invariant natural killer T (iNKT) cells, which are an important part of the innate immune system. CD1d/iNKT systems are highly conserved in evoluti
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We investigated memory impairment in newly hatched chicks following in ovo exposure to a 50-Hz magnetic field (MF) of 2 mT (60 min/day) on embryonic days 12-18. Isolated and paired chicks were used to test the effect of stress during training, and memory retention was tested at 10, 30, and 120 min, following exposure to a bitter-tasting bead (100% methylanthranilate). Results showed that memory was intact at 10 min in both isolated and paired chicks with or without MF exposure. However, while isolated chicks had good memory retention levels at 30 and 120 min, those exposed to MF did not. The results suggest a potential disruption of memory formation following in ovo exposure to MF, with this effect only evident in the more stressed, isolated chicks. Bioelectromagnetics 31:150-155, 2010. (C) 2009 Wiley-Liss. Inc.
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Phyrobilisomes (PBS) are the major light-harvesting, protein-pigment complexes in cyanobacteria and red algae. PBS absorb and transfer light energy to photosystem (PS) II as well as PS I, and the distribution of light energy from PBS to the two photosystems is regulated by light conditions through a mechanism known as state transitions. In this study the quantum efficiency of excitation energy transfer from PBS to PS I in the cyanobacterium Synechococcus sp. PCC 7002 was determined, and the results showed that energy transfer from PBS to PS I is extremely efficient. The results further demonstrated that energy transfer from PBS to PS I occurred directly and that efficient energy transfer was dependent upon the allophycocyanin-B alpha subunit, ApcD. In the absence of ApcD, cells were unable to perform state transitions and were trapped in state 1. Action spectra showed that light energy transfer from PBS to PS I was severely impaired in the absence of ApcD. An apcD mutant grew more slowly than the wild type in light preferentially absorbed by phyrobiliproteins and was more sensitive to high light intensity. On the other hand, a mutant lacking ApcF, which is required for efficient energy transfer from PBS to PS II, showed greater resistance to high light treatment. Therefore, state transitions in cyanobacteria have two roles: (1) they regulate light energy distribution between the two photosystems; and (2) they help to protect cells from the effects of light energy excess at high light intensities. (C) 2009 Elsevier B.V. All rights reserved.
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Misfit defects in a 3C-SiC/Si (001) interface were investigated using a 200 kV high-resolution electron microscope with a point resolution of 0.194 nm. The [110] high-resolution electron microscopic images that do not directly reflect the crystal structure were transformed into the structure map through image deconvolution. Based on this analysis, four types of misfit dislocations at the 3C-SiC/Si (001) interface were determined. In turn, the strain relaxation mechanism was clarified through the generation of grow-in perfect misfit dislocations (including 90 degrees Lomer dislocations and 60 degrees shuffle dislocations) and 90 partial dislocations associated with stacking faults. (C) 2009 American Institute of Physics. [doi:10.1063/1.3234380]
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Hyperfine quenching rates of the 3s3p P-3(0) level in Mg-like ions were calculated using the GRASP2K package based on the multi-configuration Dirac-Hartree-Fock method. Valence and core-valence correlation effects were accounted for in a systematic way. Breit interactions and QED effects were included in the subsequent relativistic CI calculations. Calculated rates were compared with other theoretical values and with experiment, and a good agreement with the latest experimental value for the Al-27(+) ion (Rosenband et al 2007 Phys. Rev. Lett. 98 220801) was found. Furthermore, we showed in detail the contributions from Breit interaction and QED effects to concerned physical properties. Finally, electronic data were presented in terms of a general scaling law in Z that, given isotopic nuclear spin and magnetic moment, allows hyperfine-induced decay rates to be estimated for any isotope along the isoelectronic sequence.
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The decomposition of Spin(c)(4) gauge potential in terms of the Dirac 4-spinor is investigated, where an important characterizing equation Delta A(mu) = -lambda A(mu) has been discovered. Here, lambda is the vacuum expectation value of the spinor field, lambda = parallel to Phi parallel to(2), and A(mu) the twisting U(1) potential. It is found that when), takes constant values, the characterizing equation becomes an eigenvalue problem of the Laplacian operator. It provides a revenue to determine the modulus of the spinor field by using the Laplacian spectral theory. The above study could be useful in determining the spinor field and twisting potential in the Seiberg-Witten equations. Moreover, topological characteristic numbers of instantons in the self-dual sub-space are also discussed.
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Reducing uncertainties in the estimation of land surface evapotranspiration (ET) from remote-sensing data is essential to better understand earth-atmosphere interactions. This paper demonstrates the applicability of temperature-vegetation index triangle (T-s-VI) method in estimating regional ET and evaporative fraction (EF, defined as the ratio of latent heat flux to surface available energy) from MODIS/Terra and MODIS/Aqua products in a semiarid region. We have compared the satellite-based estimates of ET and EF with eddy covariance measurements made over 4 years at two semiarid grassland sites: Audubon Ranch (AR) and Kendall Grassland (KG). The lack of closure in the eddy covariance measured surface energy components is shown to be more serious at MODIS/Aqua overpass time than that at MODIS/Terra overpass time for both AR and KG sites. The T-s-VI-derived EF could reproduce in situ EF reasonably well with BIAS and root-mean-square difference (RMSD) of less than 0.07 and 0.13, respectively. Surface net radiation has been shown to be systematically overestimated by as large as about 60 W/m(2). Satisfactory validation results of the T-s-VI-derived sensible and latent heat fluxes have been obtained with RMSD within 54 W/m(2). The simplicity and yet easy use of the T-s-VI triangle method show a great potential in estimating regional ET with highly acceptable accuracy that is of critical significance in better understanding water and energy budgets on the Earth. Nevertheless, more validation work should be carried out over various climatic regions and under other different land use/land cover conditions in the future.