Inhibition Effect of 2,3,5-Triphenyl-2H-tetrazolium Chloride and 2,4,6-Tri(2-pyridyl)-s-triazine on the Corrosion of Mild Steel in 1 mol/L HCl and Mechanism Study (II)

The inhibitory effect of 2,3,5-triphenyl-2H-tetrazolium chloride (TTC) and 2,4,6-tri(2-pyridyl)-s-triazine (TPT) molecules on the corrosion of mild steel in 1 mol/L HCl and microcosmic inhibitory mechanism were investigated by X-ray photoelectron spectroscopy and ellipsometry. XPS results showed that C Is and N Is peaks of TTC, C Is and N Is peaks of TPT and their integral areas were obtained, which suggested the layer of the inhibitors (TTC or TPT) should have effectively protected the mild steel surface from the corrosion; and the depression from the inhibitors for the corrosion of mild steel surface was studied using ellipsometry combined with potentiodynamic polarization and the phasic difference was gained, which displayed the inhibitory coverage of the inhibitors formed.

Electrochemical, SEM/EDS and quantum chemical study of phthalocyanines as corrosion inhibitors for mild steel in 1 mol/l HCl

The inhibition effect of metal-free phthalocyanine (H2Pc), copper phthalocyanine (CuPc) and copper phthalocyanine tetrasulfuric tetrasodium salt (CuPc center dot S(4)center dot Na-4) on mild steel in I mol/l HCl in the concentration range of 1.0 X 10(-5) to 1.0 X 10(-3) mol/l was investigated by electrochemical test, scanning electron microscope with energy dispersive spectrometer (SEM/EDS) and quantum chemical method. The potentiodynamic polarization curves of mild steel in hydrochloric acid containing these compounds showed both cathodic and anodic processes of steel corrosion were suppressed, and the Nyquist plots of impedance expressed mainly as a capacitive loop with different compounds and concentrations. For all these phthalocyanines, the inhibition efficiency increased with the increase in inhibitor concentration, while the inhibition efficiencies for these three phthalocyanines with the same concentration decreased in the order Of CuPc center dot S(4)center dot Na-4 > CuPc > H2Pc according to the electrochemical measurement results. The SEM/EDS analysis indicated that there are more lightly corroded and oxidative steel surface for the specimens after immersion in acid solution containing 1.0 x 10(-3) mol/l phthalocyanines than that in blank. The quantum chemical calculation results showed that the inhibition efficiency of these phthalocyanines increased with decrease in molecule's LUMO energy, which was different from the micro-cyclic compounds. (c) 2005 Elsevier B.V. All rights reserved.

四边固定载流矩形薄板的磁弹性稳定性分析

本文针对四边固定载流矩形薄板，利用Mathieu方程解的稳定性，研究其在电磁场与机械荷载共同作用下的磁弹性稳定性问题。首先在载流薄板的磁弹性非线性运动方程、物理方程、几何方程、洛仑兹力表达式及电动力学方程的基础上，导出了载流薄板在电磁场与机械荷载共同作用下的磁弹性动力稳定方程，然后应用Galerkin方法将稳定方程整理为Mathieu方程的标准形式，并将薄板的动力稳定性问题归结为对Mathieu方程的求解。利用Mathieu方程的稳定解区域与非稳定解区域的分界，即方程系数λ和η的本征值关系，得出了磁弹性问题失稳临界状态的判别方程。通过具体算例，给出了四边固定载流矩形薄板的磁弹性动力失稳临界状态与相关参量之间的关系曲线，并对计算结果及其变化规律进行了分析讨论。

抗癌药长春新碱及其与微管蛋白相互作用的电化学研究

在0.05 mol/L Tris，0.15 mol/L NaCl溶液中，用吸附伏安法研究长春新碱(VCR)，其峰电位在-1.68 V(vs. Ag/AgCl)，峰电流与1.0*10^{-8}～2.0*10^{-7}mol/L VCR浓度成正比，检测限为7.0*l0^{-9} mol/L，用常规脉冲极谱法、线性扫描和循环伏安法等研究该体系的电化学行为，实验表明，电极还原过程为具有吸附特征的不可逆过程。VCR的吸附符合Frumkin吸附等温式。也研究了VCR与微管蛋白的相互作用。实验表明，VCR与微管蛋白形成一电活性的结合物，这一结合物具有吸附性，且还原过程也为不可逆过程。

Study of the Adsorption of Fibrinogen on Gold-Coated Silicon Wafer by an Impedance Method

In 0.1 mol/l KH2PO4–Na2HPO4 (pH 7.80) buffer solution, the potential of zero charge (PZC) and the open circuit potential of gold-coated silicon were determined to be about −0.6 and +0.10 V (vs SCE), respectively. The open circuit potential was higher than the PZC, which indicated that the surface of the gold-coated electrode had a positive charge. The ellipsometry experiment showed that the adsorption of fibrinogen onto the gold-coated silicon wafer surface arrived at a saturated state when the adsorption time exceeded 50 min. The percentage of surface without adsorbed protein, θ, was about 63%. This means that the proportion of surface actually occupied by fibrinogen was only about 37% after the adsorption arrived at saturation. The solution/protein capacitance value was determined in an impulse state around −0.59 V (vs SCE) and was stable (4.2×10−5 F) at other potentials.

泰氟隆烧蚀动力学在激波管中的研究

本文给出一种用激波管研究材料烧蚀的方法。这一方法的基础是对烧蚀气相产物进行全样色谱分析,求得气相产物的总量,最后直接得到样品的烧蚀速率。用此方法对泰氟隆材料进行研究求得在高温下聚四氟乙烯的表面烧蚀速率为1.6×10~-2exp(-18400/RT)mol?Cm~-2?s~-1,(1400K

沉降对不同粒径聚苯乙烯胶乳球异向聚集的影响

R.Folkersma等报道了在微重力环境下2μm聚苯乙烯（PS）胶乳球的异向聚集速率有明显增大的结果,本文作者之一孙祉伟等的实验结果却与此有很大差异.为此作者在孙祉伟等的实验基础上对1,2,3μm以及1μm+2μm PS胶乳球混和体系的相对聚集速率进行了研究.作者对原有实验装置进行了改进,并验证了改进后的实验装置的可行性.用密度匹配法实现模拟微重力条件,用快聚集过程中浊度随时间的变化表示相对聚集速率.结果表明,重力引起的沉降对所研究体系聚集速率的影响是很小的,在实验误差范围内可以忽略.作者认为与Stein等结果显著不同的原因是二者使用的样品表面性质不同以及实验方法的差异.

气相扩散法生长溶菌酶晶体的动态光散射研究

首次采用动态光散射研究了气相扩散法生长溶菌酶晶体 .实验中采用了两种溶解溶菌酶的方法，所得实验结果是有区别的 .这种区别表明了 NaCl对溶菌酶分子间相互作用产生十分重要的影响 .实验结果表明，晶体生长过程中，溶液中溶菌酶始终保持单分子与两分子聚集体的状态，这种状态是生长晶体的基础 .

四边简支载流矩形薄板的磁弹性动力屈曲分析

在载流薄板的磁弹性非线性运动方程、物理方程、几何方程、洛仑兹力表达式及电动力学方程的基础上,导出四边简支载流矩形薄板在电磁场与机械载荷共同作用下的磁弹性动力屈曲方程。应用Galerkin原理将该屈曲方程整理为Mathieu方程的标准形式,并利用Mathieu方程解的稳定区域与非稳定区域的分界,即方程系数的本征值关系,得出磁弹性问题屈曲临界状态的判别方程。通过具体算例,给出四边简支矩形板的磁弹性动力屈曲方程以及屈曲临界状态与相关参量之间的关系曲线,并对计算结果及其变化规律进行分析讨论。

气相扩散速率对溶菌酶晶体生长的影响

为研究气相扩散速率对溶菌酶晶体生长的影响,特设计了一种可方便调节气相扩散速率的晶体生长样品池,并用动态光散射法对不同气相扩散速率下晶体生长过程进行了研究.实验结果表明,随着气相扩散速率的增加,晶体生长过程中的成核阶段缩短.气相扩散速率通过影响溶菌酶溶液形成过饱和的速率来影响生长出的晶体的数量和大小.

用于多参数生化检测微系统的葡萄糖传感器的研究

基于生物酶催化的电化学电流检测原理对人体血液生化参数进行测试.利用MEMS技术将电极、酶、反应室以及微型流路等单片集成,研制单一生物芯片的多电极酶传感器目的是同时测定人体血液的多个生化参数.本文主要介绍传感器芯片的工作原理、结构设计、加工技术及初步实验结果,其中葡萄糖在磷酸盐缓冲盐水(PBS)中的测试范围为1～30 m*mol/L,可以满足临床血糖检测的要求.

Nonlinear Dynamic Responses of the Tensioned Tether under Parametric Excitations

The nonlinear dynamic responses of the tensioned tether subjected to combined surge and heave motions of floating platform are investigated using 2-D nonlinear beam model. It is shown that if the transverse-axial coupling of nonlinear beam model and the combined surge-heave motions of platform are considered, the governing equation is not Mathieu equation any more, it becomes nonlinear Hill equation. The Hill stability chart is obtained by using the Hill's infinite determinant and harmonic balance method. A parameter M, which is the function of tether length, the surge and heave amplitude of platform, is defined. The Hill stability chart is obviously different from Mathieu stability chart which is the specific case as M=0. Some case studies are performed by employing linear and nonlinear beam model respectively. It can be found that the results differences between nonlinear and linear model are apparent.

Fluid flow induced calcium response in bone cell network

In our previous work, bone cell networks with controlled spacing and functional intercellular gap junctions had been successfully established by using microcontact printing and self assembled monolayers technologies [Guo, X. E., E. Takai, X. Jiang, Q. Xu, G. M. Whitesides, J. T. Yardley, C. T. Hung, E. M. Chow, T. Hantschel, and K. D. Costa. Mol. Cell. Biomech. 3:95-107, 2006]. The present study investigated the calcium response and the underlying signaling pathways in patterned bone cell networks exposed to a steady fluid flow. The glass slides with cell networks were separated into eight groups for treatment with specific pharmacological agents that inhibit pathways significant in bone cell calcium signaling. The calcium transients of the network were recorded and quantitatively evaluated with a set of network parameters. The results showed that 18 alpha-GA (gap junction blocker), suramin (ATP inhibitor), and thapsigargin (depleting intracellular calcium stores) significantly reduced the occurrence of multiple calcium peaks, which were visually obvious in the untreated group. The number of responsive peaks also decreased slightly yet significantly when either the COX-2/PGE(2) or the NOS/nitric oxide pathway was disrupted. Different from all other groups, cells treated with 18 alpha-GA maintained a high concentration of intracellular calcium following the first peak. In the absence of calcium in the culture medium, the intracellular calcium concentration decreased slowly with fluid flow without any calcium transients observed. These findings have identified important factors in the flow mediated calcium signaling of bone cells within a patterned network.

Laser intensity effects in photoemission and photoelectron spectra produced in laser-induced autoionisation

Strong laser-field-induced autoionisation in the presence of both photoionising and radiative decay of the autoionising state (AS) is investigated, focusing on the laser intensity dependence of the photoemission and photoelectron spectra. In contrast to previous predictions, power broadening and increasing reduction of the doublet peak heights with field strength are found in the photoemission spectrum. Similar effects leading to considerable suppression and even complete disappearance of the lowest-order peaks in the photoelectron spectrum, together with peak switching, are also demonstrated, which are closely related to above-threshold ionisation. In addition, it is suggested that the total number of energetic photoelectrons may serve as an alternative to measuring the atomic parameters of the AS. All these effects are attributed to the presence of the strong `probe': laser-induced decay of the AS.