Preparation and characterization of cationic corn starch with a high degree of substitution in dioxane-THF-water media

Cationic corn starch derivatives with a high degree of substitution are prepared in alkaline solution or in mixed media of organic solvent and water with different levels of the cationic reagent, 2,3-epoxypropyltrimethylammonium chloride. The starch cationization yield is investigated, and the results indicate that the degree of substitution (DS) of the samples depends on the reaction conditions and reaction media. The maximum DS values are up to 1.37 in 1,4-dioxane alkali ne-aqueous solution. Meanwhile, the structures of the cationic starch derivatives are characterized by elemental analyses, FTIR spectroscopy, X-ray diffraction, and C-13 NMR spectroscopy, as well as by SEM techniques.

KEL-TI介质的地震波场响应与成像方法研究

To deal with the problems in multi-component converted seismic wave exploration in coal fields, the wave propagating features and imaging methods of multi-component converted waves in coal measure strata are researched in this thesis firstly. The relations between viscoelasticity and anisotropy in coal measure strata are analyzed to build KEL-TI model, and which seismic wave propagating and attenuating features are researched. The disadvantages of converted wave imaging methods based on common converted point gather are analyzed and constant velocity no NMO converted wave imaging method based on common scattering point gather is put forward, according to Huygens-Fresnel principle, which applicabilities in the elastic isotropic, elastic TI and KEL-TI situations are discussed. To different model simulation data, the common scattering point gathers’ and stacked profiles’ features are analyzed. The results show that the method can image compressional waves and converted waves with high precision. Secondly, the resolution enhancing theories and methods of converted wave are researched by Rayleigh wave suppressing, converted wave static correction and poststack inverse-Q filtering. 1) The polarization filter is designed by the instantaneous polarization information of seismic waves, and the Rayleigh wave suppressing method is researched. From the spectrum analysis before and after filtering, it can be derived that the amplitudes are kept relatively. 2) To constant velocity no NMO converted wave imaging method, the static correction method based on common equivalent offset point gather is put forward and tested to the actual converted waves. 3) The relation between equivalent quality factor of converted wave, compressional wave quality factor and the ratio of compressional to shear wave velocity is derived. The compressional wave quality inversion method by first arrivals of none-offset VSP is researched, and which is then transformed to the equivalent quality factor to perform inverse-Q filtering of actual converted waves. The result has shown that the method can recover the high frequency energy of converted waves. At last, the theories and methods researched in this thesis are practiced to the 3D3C seismic exploration in Guqiao coal mine in Huainan and achieve good results.