Long-Term Evolution Of Delayed Ettringite And Gypsum In Portland Cement Mortars Under Sulfate Erosion

The magnitude evolution of ettringite and gypsum in hydrated Portland cement mortars due to sulfate attack was detected by X-ray powder diffraction. The influences of sulfate concentration and water-to-cement ratio on the evolution of ettringite and gypsum were investigated. Experimental results show that the magnitude of ettringite formation in sodium sulfate solution follows a three-stage process, namely, the 'penetration period', 'enhance period of strength', and 'macro-crack period'. The cracking of concrete materials is mainly attributed to the effect of ettringite. The gypsum formations occurred in two stages, the 'latent period' and the 'accelerated period'. The gypsum formation including ettringite formation was relative to the linear expansion of mortars to some extend. Both water-to-cement ratio and sulfate concentration play important roles in the evolution of ettringite and gypsum. (C) 2008 Elsevier Ltd. All rights reserved.

Broad host range plasmid-based gene transfer system in the cyanobacterium Gloeobacter violaceus which lacks thylakoids

Gloeobacter violaceus, a cyanobacterium lack of thylakoids, is refractory to genetic manipulations because its cells are enveloped by a thick gelatinous sheath and in colonial form. In this study, a large number of single cells were obtained by repeated pumping with a syringe with the gelatinous sheath removed. And an exogenous broad host range plasmid pKT210 was conjugatively transferred into G. violaceus. Analyses with dot-blot hybridization and restriction mapping showed that the exogenous plasmid pKT210 had been introduced into G. violaceus and stably maintained with no alteration in its structure. pKT210 extracted from G. violaceus exconjugants could be transformed into the mcr - mrr - E. coli strain DH10B but not the mcr(+) mrr(+) strain DH5alpha, which suggests that a methylase system may be present in G. violaceus.

Design and characteristics of quantum cascade laser-based CO detection system

National High Technology Research and Development Program of China 2007AA03Z112；Program of Ministry of Education of China 20060183030；Program of Jilin Provincial Science and Technology Department of China 20070709；Program of Bureau of Science and Technology of Changchun City 2007107

Study of the LED based light calibration system for neutron wall detector

The light calibration system is one of the key components of Neutron Wall detector. It is used to calibrate the electronics and to monitor the long-term stability of the detector modules. With the detaile investigations, a calibration system with high-power LED (3W) driven by the fast pulses has been carried out. It is also tested together with the detector module of the Neutron Wall and the result of the preliminary calibration demonstrates that it fulfills the needs. It's a new design proposal to the light calibration system of the fast scintillator detector.

Study of the mechanism for synthesizing superheavy nuclei based on dinuclear system

Based on the concept of dinuclear system, considering the strong competition between fusion and quasiffision processes, by solving the master equation numerically to calculate the fusion probability of superheavy nuclei, we have estimated the excitation functions for the reactions Ti-50, Fe-58 + Pb-208, Bi-209, and the experimental data are basically reproduced. For different incident energies and different angular momentum, the effects on fusion and survival probability and the contribution to evaporation residue cross section have been given. These results help to further understand the mechanism for, synthesizing superheavy nuclei.

Study of mass distributions of quasifission products based on dinuclear system

In the concept of dinuclear system, the quasifission rate from Kramers formula has been incorporated in the master equation in order to study the competition between fusion and qusifission. Mass yields of quasifission products of the three reactions Ca-48 + Pu-244, Ca-48 + U-238 and Fe-58 + Th-232 have been calculated, and the experimental data are reproduced very well, which is a critical test for the existing fusion model. Also we have shown the time evolution of the mass distributions of quasifission products, which provides valuable information of the process of competition between fusion and quasifission.

Production cross sections of superheavy nuclei based on dinuclear system model

The barrier distribution function method is introduced in the dinuclear system model in the calculation of the transmission probability, which is the first stage in the synthesis of superheavy nuclei. Dynamical deformation and averaging collision orientations are considered in the calculation of the fusion probability by solving master equation numerically. Survival probability with respect to xn evaporation channel (x = 1-5) in the de-excitation process of the thermal compound nucleus is calculated, in which the level density of the Fermi-gas model is used. Production cross sections of a series of superheavy nuclei formed in the reactions taken magic and deformed nuclei as target in Ca-48 induced reactions are studied systematically. The calculated results are in good agreement with available experimental data. Isotopic dependence of the production cross sections in the reactions Ca-48 + Pu is analyzed.

Deformation Monitoring and Forecasting Model Study Based on Grey System Theory

The grey system theory studies the uncertainty of small sample size problems. This paper using grey system theory in the deformation monitoring field, based on analysis of present grey forecast models, developed the spatial multi-point model. By using residual modification, the spatial multi-point residual model eras developed in further study. Then, combined with the sedimentation data of Xiaolangdi Multipurpose Dam, the results are compared and analyzed, the conclusion has been made and the advantages of the residual spatial multi-point model has been proved.

Oxidative dehydrogenation of ethane and propane over Mn-based catalysts

The catalytic performances of Mn-based catalysts have been investigated for the oxidative dehydrogenation of both ethane (ODE) and propane (ODP). The results show that a LiCl/MnOx/PC (Portland cement) catalyst has an excellent catalytic performance for oxidative dehydrogenation of both ethane and propane to ethylene and propylene, more than 60% alkanes conversion and more than 80% olefins selectivity could be achieved at 650 degrees C. In addition, the results indicate that Mn-based catalysts belong to p-type semiconductors, the electrical conductivity of which is the main factor in influencing the olefins selectivity. Lithium, chlorine and PC in the LiCl/MnOx/PC catalyst are all necessary components to keep the excellent catalytic performance at a low temperature.

Study of Mn-based catalysts for oxidative dehydrogenation of cyclohexane to cyclohexene

The gas-phase oxidative dehydrogenation (ODH) of cyclohexane to cyclohexene in the presence of molecular oxygen has been studied over various Mn-based catalysts. It is found that LiCl/MnOx/PC (Portland cement) catalyst exhibits the highest catalytic performance, and a 42.8% cyclohexane conversion, 58.8% cyclohexene selectivity and 25.2% cyclohexene yield can be achieved under 600 degrees C, 20,000 h(-1) and C6H12/O-2/N-2= 14/7/79. There are good correlations between the selectivities to cyclohexene and the electrical conductivities of Li doped Mn-based catalysts, from which it is deduced that the non-fully reduced oxygen species (O-2(-), O-2(2-), O-) involved in a new phase of LiMn2O4 might be responsible for the high selectivity toward cyclohexene, whereas the Mn2O3 crystal phase results in the COx formation. The selectivity to cyclohexene increases with increasing molar ratio of Li to Mn in LiCl/ MnOx/PC.

20-W average power, high repetition rate, nanosecond pulse with diffraction limit from an all-fiber MOPA system

In this article, we report an all-fiber master oscillator power amplifier (MOPA) system, which can provide high repetition rate and nanosecond pulse with diffraction-limit. The system was constructed using a (2 + 1) X 1 multimode combiner. The Q-Switched, LD pumped Nd:YVO4 solid-state laser wets used (is master oscillator. The 976-nm fiber-coupled module is used as pump source. A 10-m long China-made Yb3+-doped D-shape double-clad large-mode-area fiber was used as amplifier fiber. The MOPA produced as much as 20-W average power with nanosecond pulse and near diffraction limited. The pulse duration is maintained at about 15 its during 50-175 kHz. The system employs a simple and compact architecture and is therefore suitable for the use in practical applications such as scientific and military airborne LIDAR and imaging. Based oil this system. the amplification performances of. the all fiber amplifier is investigated. (C) 2008 Wiley Periodicals, Inc.

A speaker-independent continuous speech recognition system using biomimetic pattern recognition

In speaker-independent speech recognition, the disadvantage of the most diffused technology (HMMs, or Hidden Markov models) is not only the need of many more training samples, but also long train time requirement. This paper describes the use of Biomimetic pattern recognition (BPR) in recognizing some mandarin continuous speech in a speaker-independent manner. A speech database was developed for the course of study. The vocabulary of the database consists of 15 Chinese dish's names, the length of each name is 4 Chinese words. Neural networks (NNs) based on Multi-weight neuron (MWN) model are used to train and recognize the speech sounds. The number of MWN was investigated to achieve the optimal performance of the NNs-based BPR. This system, which is based on BPR and can carry out real time recognition reaches a recognition rate of 98.14% for the first option and 99.81% for the first two options to the persons from different provinces of China speaking common Chinese speech. Experiments were also carried on to evaluate Continuous density hidden Markov models (CDHMM), Dynamic time warping (DTW) and BPR for speech recognition. The Experiment results show that BPR outperforms CDHMM and DTW especially in the cases of samples of a finite size.

Development of multi-channel gated integrator and PXI-DAQ system for nuclear detector arrays

A multi-channel gated integrator and PXI based data acquisition system have been developed for nuclear detector arrays with hundreds of detector units. The multi-channel gated integrator can be controlled by a programmable Cl controller. The PXI-DAQ system consists of NI PXI-1033 chassis with several PXI-DAQ cards. The system software has a user-friendly GUI which is written in C language using LabWindows/CVI under Windows XP operating system. The performance of the PXI-DAQ system is very reliable and capable of handling event rate up to 40 kHz. (C) 2010 Elsevier B.V. All rights reserved.

胜利油田低渗透砂岩油藏非均质地质建模

Guided by geological theories, the author analyzed factual informations and applied advanced technologies including logging reinterpretation, predicting of fractal-based fracture network system and stochastic modeling to the low permeable sandstone reservoirs in Shengli oilfield. A new technology suitable for precious geological research and 3D heterogeneity modeling was formed through studies of strata precious correlation, relation between tectonic evolution and fractural distribution, the control and modification of reservoirs diagenesis, logging interpretation mathematical model, reservoir heterogeneity, and so on. The main research achievements are as follows: (1) Proposed four categories of low permeable reservoirs, which were preferable, general, unusual and super low permeable reservoir, respectively; (2) Discussed ten geological features of the low permeable reservoirs in Shengli area; (3) Classified turbidite fan of Es_3 member of the Area 3 in Bonan oilfield into nine types of lithological facies, and established the facies sequences and patterns; (4) Recognized that the main diagenesis were compaction, cementation and dissolution, among which the percent compaction was up to 50%~90%; (5) Divided the pore space in ES_3 member reservoir into secondary pores with dissolved carbonate cement and residual intergranular pores strongly compacted and cemented; (6) Established logging interpretation mathematical model guided by facies- control modeling theory; (7) Predicted the fracture distribution in barriers using fractal method; (8) Constructed reservoir structural model by deterministic method and the 3D model of reservoir parameters by stochastic method; (9) Applied permeability magnitudes and directions to describe the fractures' effect on fluid flow, and presented four different fractural configurations and their influence on permeability; (10) Developed 3D modeling technology for the low permeable sandstone reservoirs. The research provided reliable geological foundation for the establishment and modification of development plans in low permeable sandstone reservoirs, improved the development effect and produced more reserves, which provided technical support for the stable and sustained development of Shengli Oilfield.

辛体系下曲线形水中悬浮隧道对波浪激励的动力响应研究

在哈密顿体系下建立曲线形水中悬浮隧道的运动方程,即哈密顿正则方程.用哈密顿混合能变分原理处理曲线形水中悬浮隧道的两端边界条件以及径向布设的张力腿弹性支承,建立满足边界条件的线性方程组,采用分离变量法和本征向量展开法求解哈密顿正则方程.为曲线形水中悬浮隧道的动力响应分析提供一类方法.最后结合案例,运用辛方法分析波浪作用下曲线形水中悬浮隧道的弯矩和扭矩,结果表明,可以忽略扭矩对弯矩的影响.