16 resultados para LaNiO3 SrLaAlO 4

em Chinese Academy of Sciences Institutional Repositories Grid Portal


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The mixed oxides LaNiO3, La0.1Sr0.9NiO3, La2NiO4 and LaSrNiO4 with perovskite (ABO(3)) and related(A(2)BO(4)) structures were prepared and the adsorption property for NO and the catalytic activity for NO decomposition over these oxidse were also tested. The catalysts were characterized by means of BET surface measurement, chemical analysis, NO-TPD etc.. It was shown that the adsorption amount of NO is correlated with the concentration of oxygen vacancy formed and the adsorption type and strength of NO are related to the valence of metallic ion. Generally there are three kinds of adsorption species, NO-, NO+ and NO on the mixed oxides, among them the negative adsorpion species (NO-) are active for NO decomposition. The weaker the adsorption of oxygen on the catalyst is, the faster the mobility of oxygen is and the easier the redox process takes place in reproducing the active sites in which the oxygen species (O-, O2-) would participate.

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文章对渤海4号钻井船在我国渤中、辽东湾、东海和南海4大海域作业的疲劳损伤进行了详细的计算和分析,讨论了平台薄弱部位桩靴加强程度对平台疲劳损伤大小的影响及海流对平台损伤的作用。最后对渤海4号进行了充分的技术经济评价,为今后平台的合理使用、经济使用、安全作业提出了重要的建议。

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本文总结了针对涠11-4平台一年多时间的应变和加速度监测数据的处理分析工作,详细介绍了所用的数据处理方法,给出了应变数据的统计结果及长期分布规律。通过对应变和加速度信号进行频谱分析,揭示了平台在多种环境条件下的振动特性。

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本文介绍了一种固定式导管架平台综合强度监测系统,它用于对涠11-4平台关键部位的应力、加速度及与结构响应相关的环境参数进行长期监测。讨论的重点内容是结构响应的测量方案、设备及实施方法,并对运行结果作了说明

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本文研究了以PMBP-苯萃取稀土和钍、铀、钛、锆的萃取行为。测定了La、Ce、Pr、Nd、Sm、Gd、Dy、Yb、Y、U(Ⅵ)、Ti、Th和Zr的pH_(1/2)值,计算了它们的萃取平衡常数。并介绍了近十年来作者将此萃取剂应用于铀、钍、稀土、鋰、钢铁合金及岩石中痕量稀土、钍和钙的分离和测定方面的工作。实践证明,PMOP合成简便、价格低廉、萃取能力较强,是比TTA更为优越的萃取剂。

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针对中高温油藏调驱中使用的含醇类酚醛树脂类交联剂在现场应用中存在结块、醇的挥发性等问题,开展了可动凝胶合成技术、配方组成、成胶时间、热稳定性考察等试验研究,形成了以全水溶、高羟甲基化的预聚树脂交联剂为主体的KD-4型调驱体系配方。对KD-4型调驱体系成胶时间、热稳定性等进行了室内实验,并开展了前置段塞物模试验和可动性物模试验研究。依据试验结果,将总体段塞设计为“前置段塞+主段塞+保护段塞+驱油段塞(视井况而定)”,成胶黏度由低到高。自2006年7月以来,该技术进行了6口井的现场应用,井组有效率100%,截至2007年10月底,按驻点法统计,累计阶段增产原油16158.7t,目前继续有效,措施效果显著,说明调驱性能稳定,方案设计科学.

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基于线性压电材料的复势理论,通过解析分析,导出了一种分析有限压电板裂纹问题的解析数值方法.首先,计算了含中心裂纹有限板的断裂参数,与Woo和Wang的解析数值法(Int J Fract,1993,62:203~218)相比较,表明该方法具有很高的精度和很好的计算效率.随后,采用该方法和有限元法计算了PZT-4紧凑拉伸试样在绝缘裂纹面边界条件下断裂时的断裂参数,发现各断裂参数的临界值分散性很大,不能作为压电材料的单参数断裂准则.进而,针对试样真实的裂隙形状,采用有限元法计算了裂隙尖端的应力、电位移场,比较了裂隙内介质的介电性能对裂隙尖端场的影响,计算了带微裂纹的真实裂隙模型的断裂参数并进行了理论分析.

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由中国科学院力学研究所胡文瑞院士和解京昌研究员领导的研究小组承担的“微重力液滴热毛细迁移实验”项目,利用自行研制的“通用流体实验装置”,于2002年12月30日搭载“神舟4号”飞船,圆满完成了各项预定空间实验任务。对飞船下传数据和图像的初步分析表明,实验装置全部工作正常,实验获得了圆满成功,可望得到有价值的学术成果,并在相关理论研究中取得突破。此次空间实验的成功,显示了科学家和工程师的完美结合,标志着力学所在“两弹一箭”后重返空间技术领域,再铸辉煌!

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据中国数字地震台网测定,2004年1月20日16时34分11.9秒在滦县发生了ML=4.8的地震,震中位于东经118.77°,北纬39.71°,震源深度H=10km。尽管地震造成的破坏轻微,但有感范围较大,在秦皇岛市、青龙县、北京市、廊坊市、天津市等地均有震感。这次地震使震中及其附近地区的5台数字强震仪触发,记录了5组3分量数字加速度记录。本文对这次地震事件、地震地质概况作了简要介绍,并就台站(阵)基本背景资料、数字强震仪主要技术指标作了详细说明。最后,对获取的15条数字加速度记录作了初步处理分析,如基线校正、加速度峰值计算、傅里叶谱及反应谱计算等。

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This is the first part of direct numerical simulation (DNS) of double-diffusive convection in a slim rectangular enclosure with horizontal temperature and concentration gradients. We consider the case with the thermal Rayleigh number of 10^5, the Pradtle number of 1, the Lewis number of 2, the buoyancy ratio of composition to temperature being in the range of [0,1], and height-to-width aspect ration of 4. A new 7th order upwind compact scheme was developed for approximation of convective terms, and a three-stage third-order Runge-Kutta method was employed for time advancement. Our DNS suggests that with the buoyancy ratio increasing form 0 to 1, the flow of transition is a complex series changing fromthe steady to periodic, chaotic, periodic, quasi-periodic, and finally back to periodic. There are two types of periodic flow, one is simple periodic flow with single fundamental frequency (FF), and another is complex periodic flow with multiple FFs. This process is illustrated by using time-velocity histories, Fourier frequency spectrum analysis and the phase-space rajectories.