千烟洲中亚热带人工林生态系统CO_2通量的季节变异特征

作为中国陆地生态系统通量网络(ChinaFLUX)的组成部分,利用涡度相关技术对千烟洲中亚热带人工林生态系统CO2通量进行了长期观测．本研究集中探讨了千烟洲人工林2003年和2004年净生态系统CO2交换量(NEE)、生态系统呼吸(Re)和总生态系统CO2交换量(GEE)的季节变异特征及其源汇状况与强度．研究结果表明:(i)NEE,Re和GEE具有明显的季节变化趋势且密切相关,冬季和干旱期量级较低而夏季量级较高．(ii)光照、温度和水分条件是控制千烟洲人工林生态系统NEE,Re和GEE季节动态的主导因素．

A COMPARATIVE-STUDY ON STM IMAGING AND ELECTROCATALYTIC ACTIVITY OF DIFFERENT SURFACES MODIFIED WITH FLAVIN ADENINE-DINUCLEOTIDE

Flavin adenine dinucleotide (FAD) was modified onto the highly oriented pyrolytic graphite (hopg) and glassy carbon electrode (gee) surfaces with three methods, respectively. Corresponding image analysis for FAD-modified hopg surfaces has been performed by scanning tunnelling microscope (STM) for the first time. The molecular resolution STM image of FAD adsorbed on the freshly-cleaved hopg was obtained, the quantitative size determination suggests that the FAD molecules adsorb side lying on the substrate surface. The anodization treatment of hopg surface yields many pits, which were clearly observed under STM. These pits provide active sites on the hopg surface for modification and the treated hopg can strongly adsorb FAD molecules, the latter exhibiting an irregular cluster structure on such a surface. When FAD was electrochemically deposited on the substrate surface, a chain structure was successfully observed. The adsorbed FAD on anodized glassy carbon electrode (gee) surface can effectively catalyze the reduction of glucose oxidase, hemoglobin and myoglobin, with a large decrease in the overvoltage, whereas the deposited FAD film exhibits excellent electrocatalysis towards dioxygen reduction.