Experimentally Determined Flame Properties near Flammability Limits Under Gravity and Microgravity Conditions

Flammability limits for flames propagating in a rich propane/air mixture under gravity conditions appeared to be 6.3% C3H8 for downward propagation and 9.2% C3H8 for upward propagation. Different limits might be explained by the action of preferential diffusion of the deficient reactant (Le < 1) on the limit flames, which are in different states of instability. In one of the previous studies, the flammability limits under microgtravity conditions were found to be between the upward and downward limits obtained in a standard flammability tube under normal gravity conditions. It was found in those experiments that there are two limits under microgravity conditions: one indicated by visible flame propagation and another indicated by an increase of pressure without observed flame propagation. These limits were found to be far behind the limit for downward-propagating flame at 1 g (6.3% C3H8) and close to the limit for upward-propagating flame at 1 g (9.2% C3H8). It was decided in the present work to apply a special schlieren system and instant temperature measuring system for drop tower experiments to observe combustion development during propagation of the flame front. A small cubic closed vessel (inner side, 9 cm 9 cm 9 cm) with schlieren quality glass windows were used to study limit flames under gravity and microgravity conditions. Flame development in rich limit mixtures, not visible in previous experiments under microgravity conditions for strait photography, was identified with the use of the schlieren method and instant temperature measuring system. It was found in experiments in a small vessel that there is practically no difference in flammability limits under gravity and microgravity conditions. In this paper, the mechanism of flame propagation under these different conditions is systematically studied and compared and limit burning velocity is estimated.

Laminar Burning Velocities and Markstein Lengths of Premixed Methane/Air Flames near the Lean Flammability Limit in Microgravity

Effects of flame stretch on the laminar burning velocities of near-limit fuel-lean methane/air flames have been studied experimentally using a microgravity environment to minimize the complications of buoyancy. Outwardly propagating spherical flames were employed to assess the sensitivities of the laminar burning velocity to flame stretch, represented by Markstein lengths, and the fundamental laminar burning velocities of unstretched flames. Resulting data were reported for methane/air mixtures at ambient temperature and pressure, over the specific range of equivalence ratio that extended from 0.512 (the microgravity flammability limit found in the combustion chamber) to 0.601. Present measurements of unstretched laminar burning velocities were in good agreement with the unique existing microgravity data set at all measured equivalence ratios. Most of previous 1-g experiments using a variety of experimental techniques, however, appeared to give significantly higher burning velocities than the microgravity results. Furthermore, the burning velocities predicted by three chemical reaction mechanisms, which have been tuned primarily under off-limit conditions, were also considerably higher than the present experimental data. Additional results of the present investigation were derived for the overall activation energy and corresponding Zeldovich numbers, and the variation of the global flame Lewis numbers with equivalence ratio. The implications of these results were discussed. 2010 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

Influence of Obstacle-Produced Turbulence on Development of Premixed Flames

An investigation into influence of obstructions on premixed flame propagation has been carried out in a semi-open tube. It is found that there exists flame acceleration and rising overpressure along the path of flame due to obstacles. According to the magnitude of flame speeds, the propagation of flame in the tube can be classified into three regimes: the quenching, the choking and the detonation regimes. In premixed flames near the flammability limits, the flame is observed first to accelerate and then to quench itself after propagating past a certain number of obstacles. In the choking regime, the maximum flame speeds are somewhat below the combustion product sound speeds, and insensitive to the blockage ratio. In the more sensitive mixtures, the transition to detonation (DDT) occurs when the equivalence ratio increases. The transition is not observed for the less sensitive mixtures. The dependence of overpressure on blockage ratio is not monotonous. Furthermore, a numerical study of flame acceleration and overpressure with the unsteady compressible flow model is performed, and the agreement between the simulation and measurements is good.

Extinction of lean near-limit methane/air flames at elevated pressures under normal- and reduced-gravity

perimentally at evaluated pressures and under normal- and micro-gravity conditions utilizing the 3.5 s drop tower of the National Microgravity Laboratory of China. The results showed that under micro-gravity conditions the natural convection is minimized and the flames become more planar and symmetric compared to normal gravity. In both normal- and micro-gravity experiments and for a given strain rate and fuel concentration, the flame luminosity was found to enhance as the pressure increases. On the other hand, at a given pressure, the flame luminosity was determined to weaken as the strain rate decreases. At a given strain rate, the fuel concentration at extinction was found to vary non-monotonically with pressure, namely it first increases and subsequently decreases with pressure. The limit fuel concentration peaks around 3 and 4 atm under normal- and micro-gravity, respectively. The extinction limits measured at micro-gravity were in good agreement with predictions obtained through detailed numerical simulations but they are notably lower compared to the data obtained under normal gravity. The simulations confirmed the non-monotonic variation of flammability limits with pressure, in agreement with previous studies. Sensitivity analysis showed that for pressures between one and 5 atm, the near-limit flame response is dominated by the competition between the main branching, H + O2 ? OH + O, and the pressure sensitive termination, H+O2+M? HO2 + M, reaction. However, for pressures greater than 5 atm it was determined that the HO2 kinetics result in further chain branching in a way that is analogous to the third explosion limit of H2/O2 mixtures. 2010 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

微重力下热薄材料燃烧特性的窄通道实验研究

利用高度分别为10 mm, 12 mm和14 mm的水平窄通道对微重力环境下热薄材料表面的火焰传播、材料的可燃极限进行了地面实验模拟研究. 在环境氧气浓度为18%和21%, 气流速度为0-50 cm/s条件下, 窄通道模拟实验结果与已有微重力实验结果的对比分析表明:气流速度小于15-20 cm/s时, 高度为12 mm和14 mm的窄通道能较好模拟微重力条件下材料表面的火焰传播, 气流速度大于15-20cm/s时, 高度为10 mm的通道能较好模拟;高度为12 mm和14 mm的窄通道能够模拟热薄材料的可燃极限曲线, 而高度为10 mm的通道模拟的可燃极限曲线则出现一定偏差. 分析认为, 窄通道能够有效地限制浮力对流, 进而提供模拟微重力条件下材料燃烧特性的实验环境, 通道内的剩余浮力对流和通道壁面热损失可能是造成材料燃烧特性定量差别的主要原因.

近贫燃极限甲烷/空气火焰的层流燃烧速度研究

利用微重力条件下向外传播的球形火焰,对贫燃极限附近甲烷/空气预混火焰的层流燃烧速度进行了测量,得到当量比从0.512(本文微重力实验中测定的可燃极限)到0.601范围内的零拉伸层流燃烧速度,并与前人实验数据和使用3种化学反应动力学模型的计算结果进行了比较. 本文实验结果与已有的微重力实验数据非常接近,而其他研究者在常重力实验中得到的数据大多都明显高于微重力实验结果. 不同化学反应机理预测的燃烧速度比微重力实验测量值大得多,这是因为它们主要是用远离可燃极限的燃烧速度校核的

加压条件下甲烷/空气预混火焰可燃极限的微重力实验研究

本文成功搭建了适用于中国科学院力学研究所国家微重力实验室(NMLC)落塔的高压对冲火焰实验系统, 并首次开展了微重力条件下加压对冲火焰实验, 测定了一定张力条件下甲烷/空气层流预混火焰的熄灭极限. 实验结果表明, 随着压力的增高, 甲烷/空气混合气体的可燃极限呈先增后降的非单调变化趋势, 峰值发生在0.4 MPa左右. 浮力对加压下微弱火焰熄灭极限的影响明显, 在常重力条件下, 相同张力下的熄灭极限较微重力条件下的偏大, 峰值出现的压力略低. 微重力条件下的实验结果与使用CHEMKIN的数值模拟的结果相当一致.

Strengthening carbon deposition of polyolefin using combined catalyst as a general method for improving fire retardancy

Combination of Ni2O3 and solid acid with Bronsted acid sites and Lewis acid sites (such as HZSM-5 and H-beta) could dramatically improve fire retardancy of polyolefin, including polypropylene and linear low-density polyethylene. This is mainly attributed to the formation of a large amount of residual char from degradation products of polyolefin in the intermediate stage of combustion. Thus, the amount of flammable components diffusing into the flame zone was small.

Mechanism on flame retardancy of polystyrene/clay composites-The effect of surfactants and aggregate state of organoclay

Effects of organically modified montmorillonites (OMMTs) with different type and amount of modifiers on flame retardancy of polystyrene (PS) have been studied. The results from morphology analysis, gas chromatography-mass spectrometry and cone calorimeter have showed different mechanisms for the flame retardancy of PS/OMMTs composites, depending on surface property of OMNTrs. One is the catalysis of acid sites formed on the surface of octadecylammonium modified MMT (c-MMT) via Hoffman decomposition on the carbonization of degradation products, which promotes the formation of clay-enriched char barrier.

Promoting carbonization of polypropylene during combustion through synergistic catalysis of a trace of halogenated compounds and Ni2O3 for improving flame retardancy

The effect of combination between a trace of halogenated compounds (such as ferric chloride and ammonium bromide) and Ni2O3 particles on the carbonization of polypropylene (PP) was investigated during combustion. The results showed a synergistic catalysis of combined halogenated compounds with Ni2O3 in promoting the formation of the residual char during combustion. The investigation on the promotion mechanism showed that halide radical releasing from halogen-containing additives worked as a catalyst to accelerate dehydrogenation-aromatization of degradation products of PR which promote the degradation products to form the residual char catalyzed by nickel catalyst.

Combination of Carbon Nanotubes with Ni2O3 for Simultaneously Improving the Flame Retardancy and Mechanical Properties of Polyethylene

Effects of multiwalled carbon nanotubes (MWCNTs) and Ni2O3 on the flame retardancy of linear low density polyethylene (LLDPE) have been studied. A combination of MWCNTs and Ni2O3 showed a synergistic effect in improving the flame retardancy of LLDPE compared with LLDPE composites containing MWCNTs or Ni2O3 alone. As a result, the peak value of heat release rate measured by cone calorimeter was obviously decreased in the LLDPE/MWCNTs/Ni2O3 Composites. According to the results from rheological tests, carbonization experiments, and structural characterization of residual char, the improved flame retardancy was partially attributed to the formation of a networklike structure due to the good dispersion of MWCNTs in LLDPE matrix, and partially to the carbonization of degradation products of LLDPE catalyzed by Ni catalyst originated from Ni2O3, More importantly, both viscoelastic characteristics and catalytic carbonization behavior of LLDPE/MWCNTs/Ni2O3 composites acted in concert to result in a synergistic effect in improving the flame retardancy.

The effect of multiwall carbon nanotube on the crystallization, morphology, and rheological properties of nylon1010 nanocomposites

Nanocomposites based on poly(iminosebacoyl imino-decamethylene) (PA1010) and multiwall carbon nanotubes (MWNTs) were successfully prepared by melt blending technique. environmental scanning electron microscope micrographs of the fracture surfaces showed that not only is there an evenly dispersion of MWNTs throughout the PA1010 matrix but also a strongly interfacial adhesion with the matrix. The combined effect of more defects on MWNTs and low temperature buckling fracture is mainly responsible for the broken tubes. Differential scanning calorimeter results showed that the MWNTs acted as a nucleation agent and increased the crystallization rate and decreased crystallite size. In the linear region, rheological measurements showed a distinct change in the frequency dependence of storage modulus, loss modulus, and complex viscosity particularly at low frequencies. We conclude that the rheological percolation threshold might occur when the content of MWNTs is over 2 wt% in the composites.