Microscopic theory of chemical-reaction rate

In this paper we deduce the formulae for rate-constant of microreaction with high resolving power of energy from the time-dependent Schrdinger equation for the general case when there is a depression on the reaetional potential surface (when the depression is zero in depth, the case is reduced to that of Eyring). Based on the assumption that Bolzmann distribution is appropriate to the description of reactants, the formula for the constant of macrorate in a form similar to Eyring's is deduced and the expression for the coefficient of transmission is given. When there is no depression on the reactional potential surface and the coefficient of transmission does not seriously depend upon temperature, it is reduced to Eyring's. Thus Eyring's is a special case of the present work.

脉冲啁啾对于阿秒脉冲的影响

采用单电子近似和软核势模型，通过数值求解一维含时薛定谔方程，理论研究了当脉冲分别带有正、负啁啾的情况下所产生的阿秒脉冲，分析了不同脉冲啁啾特性对阿秒脉冲的强度和宽度的影响，研究结果表明，无论是正啁啾还是负啁啾，随着啁啾量的增加，都将使激光脉冲由产生单个阿秒脉冲趋向于产生阿秒脉冲链，正啁啾和负啁啾对于阿秒脉冲宽度的影响是不同的，负啁啾对于阿秒脉冲宽度影响很小，适当的负啁啾有利于缩小阿秒脉冲的宽度；而正啁啾脉冲产生的阿秒脉冲较无啁啾时展宽，且随着啁啾量的增加，其阿秒脉冲宽度迅速增大。

非均匀交换各向异性铁磁介质的非线性表面自旋波

利用Landau Lifshitz方程 ,研究了具有非均匀交换各向异性的半无限大铁磁体的非线性表面自旋波理论。导出了部分钉扎纯交换铁磁介质的磁化强度所满足的边界条件和非线性表面自旋波的色散关系 ,并获得了自旋波振幅沿z方向驻波的一维非线性Schr dinger方程和包络振幅沿平面传播的二维非线性Schr dinger方程 ,结果表明铁磁体磁化强度的包络振幅随时空变化的性质是由二维非线性Schr dinger方程决定的。因此预言铁磁介质的表面非线性激发应是二维孤波的形式。对于弱非线性表面自旋波 ,对非线性Schr dinger方程存在孤子形式解的可能性作了讨论 .