Distribution and mode of occurrence of As；Hg and Se and sulfur in coal Seam 3 of the Shanxi Formation,Yanzhou Coalfield；China

IEECAS SKLLQG

鄂尔多斯盆地上古生界包裹体研究及天然气成藏特征分析

Based on the study of types, even temperature, the character of age-old fluid and fluid pressure of the reservoir fluid-inclusion in the Upper Paleozoic of Ordos Basin , combining with the diagenesis and character of gas geochemistry, reservoir sequence, cause of the low pressure reservoir formation and formation environment have been studied, the following knows are acquired: Abundant fluid-conclusions have developed in sandstone reservoir in Upper Paleozoic of Ordos Basin,and its kinds is numerous , also taking place some changes such as shrinking rock, cracking, stretching after formation. According to formation cause, fluid inclusion is divided into two types:successive and nonsuccessive inclusion. Nonsuccessive inclusion is further divided into brine inclusion, containing salt crystal inclusion, gaseity hydrocarbon conclusion and liquid hydrocarbon conclusion and so on. The gaseity hydrocarbon conclusion distributes at all the Basin, the liquid hydrocarbon conclusion mainly distributes at the East of Basin, and its two kinds of fluorescence color: blue and buff reflects at least two periods of oil filling and oil source of the different maturity. The study of diagenesis has indicated that five periods of diagenesis correspond to five periods inclusion's growth.The first and second period conclusions mainly distribute at the increasing margin of quartz, little amount and low even temperature, containing little gaseity hydrocarbon conclusion; The third and fourth conclusions are very rich, and having multiplicity forms, gaseity hydrocarbon conclusion of different facies, distributing at the increasing margin and crevice of quartz, its even temperature is between 85℃and 135℃;The fifth inclusion is relatively few ,mainly distributing at vein quartz and calcite, and developing few gaseity hydrocarbon conclusion. The fluid in the inclusion is mainly NaCl brine:low and high salinity brine fluid(containing salt crystal).The former salinity is between 0.18% and 18.55%,and mainly centralized distributing at three sectongs: from 0% to 4%, from 6% to 8%, from 10% to 14%, expressing that the alternation of the underground fluid was not intense, the conservation condition was good in different periods. The trapping pressure of the gaseity hydrocarbon conclusion calculated by PVTsim(V10)simulation is between 21.39 MPa and 42.58MPa,the average is 28.99MPa,mainlydistributes at between 24 MPa and 34MPa,and having a character of gradually lower from early to late time. The pressure of SuLiGe and WuShenQi dropped quickly in early time, and YuLin, ShenMu-MIZhi gas area dropped slowly in early and quickly in late time, ha portrait the change of trapping pressure can be divided into three old-age pressure systems: TaiYuan-ShanXi formation, low ShiHeZi formation and high ShiHeZi-ShiQianFeng formation. In plane, the trapping pressure dropped lowly from south to north in main reservoir period, and this reflects the gas migrating direction in the geohistory period. The analysis of gas component and monnmer hydrocarbon isotope indicates that the gas in Upper Paleozoic of Ordos Basin is coal-seam gas. The gas C_1-C_4 rnonnmer hydrocarbon isotopes has distinct differences in different stratums of different areas, and forming YuLin, SuLiGe and ShenMu-MIZhi three different distributing types. To sum up, gas reservoir combination in Upper Paleozoic of Ordos Basin can be divided into three sets of combination of reservoir formation: endogenesis type, near source type and farther source type,and near source gas combinations of reservoir formation is the main gas exploration area for its high gas filling intensity, large reservoir size.

煤与瓦斯突出的初次破坏特征分析

针对煤矿煤与瓦斯突出动力现象的复杂过程,对突出启动前煤体的初次破坏特征进行了分析。特别是对影响突出发生的煤体初次破坏的几何特征以及层裂拱壳形成的力学原理,通过简化的力学模型做了分析,同时讨论了影响初次破坏特性的主要因素,包括与不同煤体结构相适应的煤体材料不同破坏准则的影响。为进一步认识煤与瓦斯突出的机理,突出的启动、发展演化提供一种思路,进而为突出的预测和防治提供基础。

线性组合边界中煤层气井的不稳定压力数值分析

文章建立并求解了不同线性组合边界条件下的煤层气井不定常渗流模型，得到了井底压力和压力导数的理论曲线，以及压力场分布图。在不稳定流动的早期，压力和压力导数曲线都是斜率为1的直线段。当流体流动进入稳定流动状态时，在压力导数曲线上出现一个值为0．5的水平直线段。在理论曲线的晚期，理论曲线与边界性质存在密切关系。对于全封闭煤层气藏，所有压力和压力导数曲线是斜率为1的直线段。对于存在定压边界煤层气藏，压力双对数曲线的晚期是水平直线段，压力导数双对数曲线的晚期都是急剧下掉的曲线。但是混合边界的压力导数存在上翘现象，上翘程度和早晚与封闭边界的数目多少以及距离大小有关。压力场中，在靠近封闭边界的等压线垂直于边界，在靠近定压边界的等压线平行于边界。在邻近定压和封闭边界交合处，定压边界起主导作用。所得到的理论曲线可以直接应用于煤层气田的试井测试资料分析，压力场分布图对了解煤层气藏的开发状况有积极的意义。

松辽盆地长岭断陷火山岩气藏的形成条件与分布规律

Changling fault depression is a compound fault depression complicated by interior fault, with faults in the west and overlap in the west. North of Changling fault depression show NNE strike while south is NW strike. Changling fault depression has undergone twochasmic stage which control the development and distribution of volcanic rock, one depression stage, later inversion and uplift stage which control the formation of natural gas reservoir, and basin atrophic stage. The main boundary faults and main faults in Changling fault depression control three volcanic cycles and the distribution of volcanic rock. Seismic reflection characteristic and logging response characteristic of volcanic rock in study area are obvious, and the distribution characteristic, volcanic cycle and active stage of volcanic rock can be revealed by seismic attribute, conventional logging data can distinguish clastic rock from volcanic rock or distinguish partial different types of volcanic rock. The reservoir property of rhyolite and volcanic tuff are the best. Favorable volcanic reservoir can be preserved in deep zone. Imaging logging and frequency decompostion technology of seismic data act as effective role in the study of reservoir physical property and gas-bearing properties of volcanic rock.. Hydrocarbon gas in study area is high and over mature coal type gas, the origin of CO2 is complex, it is either inorganic origin or organic origin, or mixing origin. Hydrocarbon gas is mainly originate from Shahezi formation and Yingcheng formation source rocks, CO2 is mainly mantle source gas. Hydrocarbon has the characteristics of continuous accumulation with two charging peak. The first peak represent liquid hydrocarbon accumulation time, The second peak stand for the accumulation time of gaseous hydrocarbon.CO2 accumulate approximately in Neocene. The source rock distribution range, volcanic rock and favorable reservoir facies, distribution characteristic of deep fault (gas source fault) and late inversion structure are the major factors to control gas reservoir formation and distribution. All the results show that these traps that consist of big inherited paleo uplift(paleo slope), stratigraphic overlap and thinning out, volcanic rock, are the most advantageous target zone.

渤海湾盆地前第三系构造演化与煤成气成藏研究

The disequilibrium between supply and demand the east part of North China accelerated natural gas exploration in Bohai bay basin. Exploration practice showed that coal-derived gas is important resource. In searching of big to middle scaled coal derived gas field, and realize successive gas supply, the paper carried out integrated study on structural evolution of Pre-Tertiary and evaluation of reservoir forming condition of coal-derived gas. Study work of the paper was based on the following condition: available achievement in this field at present, good understanding of multiphase of tectonic movement. Study work was focused on geological evolution, source rock evaluation and dissection key factors controlling reservoir forming. Based on analysis of seismic data, drilling data, tectonic style of Pre-Tertiary was subdivided, with different tectonic style representing different tectonic process. By means of state of the art, such as analysis of balanced cross section, and erosion restoration, the paper reestablished tectonic history and analyzed basin property during different tectonic phase. Dynamic mechanism for tectonic movement and influence of tectonic evolution on tectonic style were discussed. Study made it clear that tectonic movement is intensive since Mesozoic including 2 phase of compressional movement (at the end of Indo-China movement, and Yanshan movement), 2 phase of extensional movement (middle Yanshan movement, and Himalayan movement), 2 phase of strike slip movement, as well as 2 phase of reversal movement (early Yanshan movement, and early Himalayan movement). As a result, three tectonic provinces with different remnant of strata and different tectonic style took shape. Based on afore mentioned study, the paper pointed out that evolution of Bohai bay basin experienced the following steps: basin of rift valley type (Pt2+3)-craton basin at passive continental margin (∈1－2)-craton basin at active continental margin (∈3- O)-convergent craton basin (C-T1+2)-intracontinental basin (J＋K). Superposition of basins in different stage was discussed. Aimed at tectonic feature of multiple phases, the paper put forward concept model of superposition of tectonic unit, and analyzed its significance on reservoir forming. On basis of the difference among 3 tectonic movements in Mesozoic and Cenozoic, superposition of tectonic unit was classified into the following 3 categories and 6 types: continuous subsidence type (I), subsidence in Mesozoic and uplift for erosion in Cenozoic (II1), repeated subsidence and uplift in Mesozoic and subsidence in Cenozoic (II2), repeated subsidence and uplift in Mesozoic and uplift for erosion in Cenozoic (II3), uplift for erosion in Mesozoic and subsidence in Cenozoic (II4), and continuous uplift (III). Take the organic facies analysis as link, the paper established relationship between sedimentary environment and organic facies, as well as organic facies and organic matter abundance. Combined information of sedimentary environment and logging data, the paper estimated distribution of organic matter abundance. Combined with simulation of secondary hydrocarbon generation, dynamic mechanism of hydrocarbon generation, and thermal history, the paper made static and dynamic evaluation of effective source rock, i.e. Taiyuan formation and Shanxi formation. It is also pointed out that superposition of tectonic unit of type II2, type II4, and type I were the most favorable hydrocarbon generation units. Based on dissection of typical primary coal-derived gas reservoir, including reservoir forming condition and reservoir forming process, the paper pointed out key factors controlling reservoir forming for Carboniferous and Permian System: a. remnant thickness and source rock property were precondition; b. secondary hydrocarbon generation during Himalayan period was key factor; c. tectonic evolution history controlling thermal evolution of source rock was main factor that determine reservoir forming; d. inherited positive structural unit was favorable accumulation direction; e. fault activity and regional caprock determined hydrocarbon accumulation horizon. In the end, the paper established reservoir forming model for different superposition of tectonic units, and pointed out promising exploration belts with 11 of the first class, 5 of the second class and 6 of the third class.

煤系地层三维三分量地震数据解释方法研究

Conventional 3D seismic exploration cannot meet the demand of high yield and high efficiency safe production in coal mine any more. Now it is urgent to improve the discovery degree of coal mine geological structures for coal production in China. Based on 3D3C seismic exploration data, multi-component seismic information is fully excavated. First systematic research on 3D3C seismic data interpretation of coal measure strata is carried out. Firstly, by analyzing the coal measure strata, the seismic-geologic model of coal measure strata is built. Shear wave logging is built by using regression analysis. Horizon calibration methods of PP-wave and PS-wave are studied and the multi-wave data are used together to interpret small faults. Using main amplitude analysis technology, small faults which cannot be found from PP-wave sections can be interpreted from the low frequency PS-wave sections. Thus, the purpose to applying PS-wave data to fine structure assistant interpretation is achieved. Secondly, PP- and PS-wave post-stack well constrained inversion methods of coal measure strata are studied. Joint PP- and PS-wave post-stack inversion flow is established. More attribute parameters, which are applied in fine lithology interpretation of coal measure strata, are obtained from combinations of the inversion results. Exploring the relation between rock with negative Poisson’s ratio and anisotropy, fracture development in coal seam are predicted. Petrophysical features of coal measure strata are studied, and the relations between elastic parameters and lithology, fluid and physical properties are established. Inversions of the physical parameters such as porosity, permeability and water saturation, which reflect lithology and fluid property, are obtained. Finally, the approaches of shear wave splitting and Thomsen parameters inversion, which provide new ideas for seismic anisotropy interpretation of coal measure strata, are studied to predict fracture development. The results of practical application indicate that the methods in this paper have good feasibility and applicability. They have positive significance for high yield and high efficiency safe production in coal mine.

急倾斜金属矿体开采岩体移动规律与变形趋势预测研究

Rockmass movement due to mining steep metallic ore body is a considerable question in the surface movement and deformation issue caused by underground mining. Research on coal mining induced rockmass movement and its prediction problem have been performed for a long-term, and have achieved great progress at home and abroad. However, the rockmass movement caused by mining steep metal mine is distinctivly different from coal seam mining.. Existing surface movement laws and deformation prediction methods are not applicable to the rockmass movement caused by mining steep metal mine. So far the home and abroad research to this theory is presently at an early stage, and there isn’t mature theory or practical prediction method, which made a great impact on production. In this paper, the research object—Jinchuan nickel mine, which is typical steep metal mine, characterized by complex geological conditions, developed faults, cracked rockmass, high geostress, and prominent engineering stability problems. In addition, backfill mining method is used in the mine, the features of rockmass movement caused by this mining method are also different from other mining methods. In this paper, the laws of rock mass movement, deformation and destroy mechanism, and its prediction were analyzed based on the collection of data, detailed in-sit engineering geology survey, ground movement monitoring by GPS, theoretical analysis and numerical simulation. According to the GPS monitoring of ground surface movement, ground subsidence basin with apparent asymmetry is developing, the influence scope is larger in the upper faulted block than in the lower faulted block, and the center of ground movement is moving along the upper faulted block direction with increasing depth of mining. During the past half and seven years, the largest settlement has amounted to 1287.5mm, and corresponding horizontal displacement has amounted to 664.6mm. On the ground surface, two fissure belts show a fast-growing trend of closure. To sum up, mining steep metal mine with backfill method also exist the same serious problem of rockmass movement hazards. Fault, as a low intensity zone in rockmass, when it located within the region of mining influence, the change of potential energy mainly consumed in fault deformation associated with rockmass structure surface friction, which is the essence of displacement and stress barrier effects characterized by fault rupture zone. when steep fault located in the tensile deformation region incurred by underground excavation, no matter excavation in hangingwall or in footwall of the fault, there will be additional tensile stress on the vertical fault plane and decrease in the shear strength, and always showing characteristics of normal fault slip, which is the main reason of fault escarpment appeared on the ground surface. The No.14 shaft deformation and failure is triggered by fault activation, which showed with sidewall move, rupture, and break down features as the main form of a concentrated expression of fault effects. The size and orientation of principal stress in surrounding rock changed regularly with mining; therefore, roadway deformation and damage at different stages have different characteristics and distribution models. During the process of mining, low-intensity weak structures surface always showed the most obvious reaction, accompany with surface normal stress decrease and shear strength bring down, to some extent, occurred with relative slide and deformation. Meanwhile, the impact of mining is a relatively long process, making the structure surface effect of roadway deformation and damage more prominent than others under the influence of mining. Roadway surrounding rockmass deformation caused by the change of strain energy density field after excavation mainly belongs to elastic deformation, and the correspondented damage mainly belongs to brittle rupture, in this circumstance, surrounding rockmass will not appear large deformation. The large deformation of surrounding rockmass can only be the deformation associated with structure surface friction or the plastic deformation of itself, which mainly caused by the permanent self-weigh volume force，and long-term effect of mining led to the durability of this deformation Good pitting fill effect and supporting effect of backfill, as well as the friction of rockmass structure surface lead to obvious macro-rockmass movement with long-lag characteristics. In addition, the loss of original intensity and new structure surface arisen increased flexibility in rockmass and fill deformation in structure surface, which made the time required for rockmass potential energy translate into deformation work associated with plastic deformation and structure surface friction consumed much, and to a large extent, eliminated the time needed to do those plastic work during repeated mining, all of which are the fundamental reason of rockmass movement aftereffect more significant than before. Mining steep deposits in high tectonic stress area and in gravity stress area have different movement laws and deformation mechanism. The steep deposit, when the vertical size of the mining areas is smaller than the horizontal size of the orebody, no matter mining in gravity stress area or in high tectonic stress area, they have similar features of ground movement with mining horizontal orebody; contrarily, there will appear double settlement centers on the ground surface under the condition of mining in high tectonic stress area, while there will always be a single center under the other condition. Meanwhile the ground movement lever, scale of mining influence area and macro features of ground movement, deformation and fracture are also different from mining in gravity stress area, and the fundamental reason lies in the impact of orientation of the maximum principal stress on rock movement features in in-site rock stress field. When mining thick and steep deposit, the ground surface movement and deformation characteristic curves are significantly different from excavating the horizontal ore bed and thin steep deposit. According to the features of rockmass movement rate, the development process of mining-induced rockmass movement is divided into three stages: raising stage, steadily stage and gradually decay stage. Considering the actual exploitation situation, GPS monitoring results and macro-characteristics of surface movement, the current subsidence pattern of Jinchuan No.2 mine is in the early stage of development. Based on analysis of surface movement rate, surface subsidence rate increase rapidly when mining in double lever at the same time, and reach its peak until the exploitation model ended. When double lever mining translate into single, production decreased, surface subsidence rate suddenly start to reduce and maintain a relatively low value, and the largest subsidence center will slowly move along with the hangingwall ore body direction with increasing depth of mining, at the same time, the scope and extent of subsidence in footwall ore body will begin magnify, and a sub-settlement center will appear on ground surface, accompanied with the development and closure trend of ground fissure, the surrounding rockmass of shaft and roadway will be confronted to more frequent and severe deformation and failure, and which will have a negative impact on the overall stability of No.2 mine mining. On the premise of continuity of rockmass movement, gray system model can be used in ground rockmass movement prediction for good results. Under the condition of backfill mining step by step, the loose effect of compact status of the hard, broken rockmass led to lower energy release rate, although surrounding rockmass has high elastic energy, loose and damage occurred in the horizontal ore body, which made the mining process safety without any large geological hazards. During the period of mining the horizontal ore body to end, in view of its special “residual support role”, there will be no large scale rockmass movement hazards. Since ground surface movement mainly related to the intensity of mining speed and backfill effect, on the premise of constant mining speed, during the period of mining the horizontal ore body to end, the rate of ground surface rockmass movement and deformation won’t have sudden change.

Numerical Simulation of Nox Formation in Coal Combustion with Inlet Natural Gas Burning

A full two-fluid model of reacting gas-particle flows and coal combustion is used to simulate coal combustion with and without inlet natural gas added in the inlet. The simulation results for the case without natural gas burning is in fair agreement with the experimental results reported in references. The simulation results of different natural gas adding positions indicate that the natural gas burning can form lean oxygen combustion enviroment at the combustor inlet region and the NOz concentration is reduced. The same result can be obtained from chemical equilibrium analysis.