17 resultados para CS2
em Chinese Academy of Sciences Institutional Repositories Grid Portal
Resumo:
By using the home-made femtosecond laser system and the time-of-flight mass spectrometer, the decay dynamics of excited carbon disulfide (CS2) and ammonia (NH3) are investigated in real time by pump-probe multiphoton ionization detection. The estimated lifetime constant of the NH3 (A) over tilde (1)A(2)' state (51+/-4 fs) agreed quite well with the literature report. For the first time, the decay lifetime constants of the NH3 (E) over tilde'(1)A(1)' state (937+/-93 fs), the CS2 (a) over tilde (3)A(2) state (153+/-10 fs), and the CS2 Rydberg state [(3)/(2)]6ssigma(g) ((3)Pi(g)) (948+/-23 fs) are obtained.
Resumo:
Only H2S consumption and H2O formation was found in the sulfurization of CoMoK/Al2O3 water gas shift catalyst with H2S/H-2. but CO2 was formed first, then CH4, H2O and H2S appeared in the later part of TPS with CS2/H-2. Carbon deposition on the catalyst during the sulfurization with CS2/H-2 caused a lower activity than the catalyst sulfurized with H2S but could be removed in the run of WGS reaction.
Resumo:
目录
- 访罗湖 忆当年[李佩]
- 怀念同窗益友郭永怀教授[钱伟长]
- 郭永怀追求科学、为国献身的一生[洪友士]
- 深深怀念为核盾牌献身的著名科学家--郭永怀先生 中国工程物理研究院
- 深切怀念郭永怀教授的奠基性贡献 中国空气动力研究与发展中心
- 胸怀长江长城 心系国家安危--纪念我国核防护工程奠基人郭永怀先生[周丰峻]
- 缅怀我们的首任系主任--郭永怀教授[辛厚文 马兴孝 俞书勤 何天敬]
- 科学和技术结合的典范--纪念郭永怀先生诞辰九十周年[郑哲敏 李家春]
- 怀念与感激[俞鸿儒]
- 继承先师遗愿,谈我所冲击动力学的发展--纪念郭永怀副院长诞辰九十周年[陈裕泽]
- 英名长存--纪念郭永怀副院长诞辰九十周年[沈中毅]
- 郭永怀与我国导弹弹头再入气动物理研究[魏叔如]
- 科研工作引路人--纪念郭永怀九十诞辰[胡在军]
- 科技楷模,引路良师--怀念敬爱的郭永怀副院长[朱竟洪 郑百瑛]
- 七律 永怀永怀郭老师[董务民]
- 留得春晖映核魂--怀念我们的好领导好老师郭永怀同志[孙德纶 张克才]
- 难以忘怀--忆郭永怀副院长事迹点滴[孙天雄]
- 研究工作与工程技术工作之间的关系[谈庆明]
- 忆敬爱的郭永怀老师[张兆顺 呼和敖德]
- 根深叶茂 厚积薄发--追忆恩师郭永怀先生教诲我打好基础[严宗毅]
- 力学前辈,科德风范[徐友钜]
- 领导的楷模 学者的典范 青年的导师--怀念郭永怀副院长[于长勤]
- 怀念郭永怀副院长[陈裕泽]
- 关于郭永怀事迹的回顾[张长富]
- 严谨的导师,可亲的长者--忆著名的空气动力学家郭永怀先生[吴兰春]
- 严谨细致 实事求是--纪念郭永怀九十诞辰[李启廉]
- 纪念核武器环境试验技术的奠基人--郭永怀副院长诞辰九十周年[李荣林]
- 郭老精神激励着材料科学研究的不断深入[周维宣 谭云]
- 郭永怀副院长的关怀与我所有机材料研究的发展[陈晓丽]
- 忆与郭永怀副院长的一次谈话[孙德纶]
- 缅怀郭永怀院士[陈家镛]
- 记郭永怀先生二三事[屠善澄]
- Remembering Yunghuai Kuo[C.C.Lin]
- Recall with love and respect[William R.Sears]
- Y.H.Kuo:An appreciation[Frank E.Marble]
- A commemorative tribute to Professor Guo Yonghuai[T.Y.Wu]
- Y.H.Kuo:A great scientist,revered teacher and good friend[Alfred Ritter]
- 氢氧燃烧及爆轰驱动激波管[俞鸿儒]
- 颗粒材料中致密波结构研究[孙锦山 朱建士 贾祥瑞]
- 网格与高精度差分计算问题[张涵信 呙超 宗文刚]
- 植被层湍流的大涡模拟[李家春 谢正桐]
- 半浮区液桥热毛细振荡流[唐泽眉 阿燕 胡文瑞]
- 再入湍流尾迹及其对雷达散射的影响研究[牛家玉 于明]
- 超声射流中CS2分子态分辨转动弛豫研究[陈从香 刘世林 戴静华 张志萍 马兴孝]
- 37mm冲压加速器实验和计算[柳森 简和祥 白智勇 平新红 部绍清]
- 化学体系中噪声诱导的时空有序结构和随机共振[辛厚文 侯中怀 杨灵法]
- 根据守恒律计算热流和摩阻的有限元提法[童秉纲 段占元]
- 高阶精度线性耗散紧致格式的渐近稳定性[邓小刚 毛枚良]
- 离散流体力学:理论和数值方法[高智]
- 2号复合离心机自动控制系统研制[王磊 林明 冯晓军]
- 海沧大桥气动弹性特性风洞试验研究[李明水 陈忻 张大康 王卫华]
- 内爆炸载荷下圆管变形、损伤和破坏规律的研究[李永池 李大红 魏志刚 孙宇新]
- 两种凝聚炸药的静态断裂性能实验研究[罗景润 韦日演 马丽莲]
- 圆柱体侵彻薄靶极限击穿速度估算探讨[吴应白 唐平]
- 动力学修改方法在夹具设计中的应用研究[蒲怀强 唐定勇]
- Numerical simulation of non-linear stability of two-dimensional supersonic boundary layer[Shen Qing Yuan Xiangjiang]
Resumo:
The real and imaginary parts of third-order susceptibility of amorphous GeSe2 film were measured by the method of the femtosecond optical heterodyne detection of optical Kerr effect at 805 nm with the 80 fs ultra fast pulses. The results indicated that the values of real and imaginary parts were 8.8 x 10(-12) esu and -3.0 x 10(-12) esu, respectively. An amorphous GeSe2 film also showed a very fast response within 200 fs. The ultra fast response and large third-order non-linearity are attributed to the ultra fast distortion of the electron orbits surrounding the average positions of the nucleus of Ge and Se atoms. (c) 2005 Elsevier B.V. All rights reserved.
Resumo:
A faccile and efficient one-pot synthesis of highly substituted thiophenes has been developed and employed for the preparation of a small focused library. Treatment of 1,3-dicarbonyl compounds 1 with CS2 in the presence of K2CO3 in DMF at room temperature, followed by stepwise addition of alkyl bromides 2 and methylene active bromides 3, provided via intramolecular cyclization 2,3,4,5-tetrasubstituted thiophenes 4 in yields of 77-94%. This protocol, combining construction and modification of the thiophene ring, increases the structural diversity of final products from readily available materials. A mechanism for the one-pot synthesis of thiophenes of type 4 has been proposed. A small focused library of thiophenes is prepared using the sequential addition of reagents to achieve unique substitution in the 2 and 5 position of the thiophene ring
Resumo:
Poly (3-butylthiophene) (P3BT) is a much less studied conjugated polymer despite its high crystallizability and thus excellent electrical property. In this work, morphology of P3BT at different crystalline polymorphs and solvent/thermal induced phase transition between form I and U modifications have been intensively investigated by using optical microscopy, electron microscopy, differential scanning calorimetry, and X-ray diffraction. It is shown that a direct deposition from carbon disulfide (CS2) at fast evaporation results in P3BT crystals in form I modification, giving typical whiskerlike morphology. In contrast, low evaporation rate from CS, leads to formation of form II crystals with spherulitic morphology, which is so far scarcely observed in polythiophene.
Resumo:
The crystalline syndiotatic 1,2-polybutadiene was synthesized with a catalyst consisting of iron acetylacetonate (Fe(acac)(3))-triisobutylaluminum (Al(i-Bu)(3))-diethyl phosphite (DEP), and the effects of crystal growth conditions on morphology of thin films of the polymer were investigated by transmission electron microscopy (TEM) and electron diffraction (ED) techniques. The polymer with melting point 179 degreesC was found to have 89.3% 1,2-content and 86.5% syndiotacticity by C-13 NMR measurement. The results of electron microscopic studies indicate that the solution-cast thin films of the syndiotatic 1,2-polybutadiene consist of lath-like lamellae with the c-axis perpendicular to the film plane, while a- and b-axes are in the film plane. The morphology of isothermally crystallized thin films of the polymer is temperature dependent. At lower crystallization temperatures (130 degreesC), a spherulitic structure consisting of flat-on lamellae is formed. With an increase in the crystallization temperature (e.g., at 140 degreesC), the spherulites and single faceted crystals coexist. At higher crystallization temperatures (150 degreesC), single crystals with a hexagonal prismatic shape are produced.
Resumo:
We have investigated systematically the morphology of thin films spin-coated from solutions of a semicrystalline diblock copolymer, poly(L-lactic acid)-block-polystyrene (PLLA-b-PS), in solvents with varying selectivity. In neutral solvents (chloroform and tetrahydrofuran (THF)), a spinodal-like pattern was obtained and the pattern boundary was sharpened by diluting the solution. Meanwhile, loose spherical associates, together with larger aggregates composed of these associates by unimer bridges, formed partly due to crystallization of the PLLA blocks in relatively concentrated solutions. In slightly PS-selective solvent (e.g., benzene), both loose and compact spherical micelles were obtained, depending on the polymer concentration, coexisting with unimers. When enhancing the selectivity with mixed solvents, for example, mixing the neutral solvent and the slightly selective solvent with a highly PS-selective solvent, CS2, loose assemblies (nanorods in CS2/THF mixtures and polydisperse aggregates in CS2/benzene mixtures) and well-developed lamellar micelles were obtained.
Resumo:
Crystallization and phase behavior in solution-cast thin films of crystalline syndiotactic 1,2-polybutadiene (s-1,2-PB) and isotactic polypropylene (i-PP) blends have been investigated by transmission electron microscopy (TEM), atomic force microscopy (AFM) and field-emission scanning electron microscopy (FESEM) techniques. Thin films of pure s-1,2-PB consist of parallel lamellae with the c-axis perpendicular to the film plane and the lateral scale in micrometer size, while those of i-PP are composed of cross-hatched and single-crystal-like lamellae. For the blends, TEM and AFM observations show that with addition of i-PP, the s-1,2-PB long lamellae become bended and i-PP itself tends to form dispersed convex regions oil a continuous s-1,2-PB phase even when i-PP is the predominant component, which indicates a strong phase separation between the two polymers during film formation. FESEM micrographs of both lower and upper surfaces of the films reveal that the s-1,2-PB lamellae pass through i-PPconvex regions from the bottom, i.e. the dispersed i-PP regions lie on the continuous s-1,2-PB phase. The structural development is attributed to an interplay of crystallization and phase separation of the blends in the film forming process.