Morphology of conductive blend fibers of polyaniline and polyamide-11

Polyaniline (PANI), a member of the intrinsically conducting polymer (ICPs) family, was blended with polyamide-11 (polyco-aminoundecanoyle) in concentrated sulfuric acid. The above solution was used to spin conductive PANI/polyamide-11 fibers by wet-spinning technology. Scanning electron microscope (SEM) and transmission electron microscope (TEM) were employed to study the two-phase morphology of the conductive PANI/polyamide-11 fibers. The micrographs of the cross-section, the axial section and the surface of the monofilament demonstrated that the two blend components were incompatible. The morphology of PANI in the fibers was of fibrillar form, which was valuable for producing conducting channels. The electrical conductivity of the fibers was from 10(-6) to 10(-1) S/cm with the different PANI fraction and the percolation threshold was about 5 wt.%. By comparing the two blend systems of PANI/Polyamide-11 fibers and carbon black filled poly(ethylene terephthalate) (PET) fibers, it was shown that the morphology of the conductive component had an influence on electrical conductivity, The former had higher conductivity and lower percolation threshold than the latter. (C) 2001 Elsevier Science B.V. All rights reserved.

基于项目驱动的藉河流域土地利用时空变化动态分析

根据1997年、2001年和2005年三期TM影像资料,运用遥感非监督分类的方法提取土地利用信息。利用地理信息系统空间分析和数据统计的方法,分析藉河流域1997~2005年间土地利用数量变化和空间变化特征,研究该地区主要土地利用类型数量变化、空间变化以及在不同坡度的动态变化特征。结果表明:耕地、林地和草地三种主要土地利用类型占该研究区土地利用面积的97%以上,是该研究区主要的土地利用类型。以1997年为基数,到2001年和2005年耕地减少幅度分别为1.2%和11.1%,因此1997~2001年的退耕程度小于2001~2005年;在不同坡度上,土地利用变化主要发生在5°~40°,而且在15°~25°之间变化最大。