A highly reduced polyoxoanion with phosphorus-centered alternate layers of Mo/V oxides, [(PMo2Mo6V4O40)-Mo-V-V-VI-O-IV((VO)-O-IV)(2)](9-)

An unusual polyoxometalate [H2N(C2H4)(2)NH2](4)(H3O)[(PMO2Mo6V4O40)-Mo-V-V-VI-O-IV((VO)-O-IV)(2)].H2O is hydrothermally synthesized and characterized by IR, UV-VIS, elemental analyses, X-ray photoelectron spectrum, ESR, TG and Single crystal X-ray diffraction. The title compound crystallizes in the orthorhombic space group Pbca with a = 15-227(5), b = 19.491(4), c = 18.737(3) Angstrom, V = 5123(2) Angstrom(3), Z = 4, and R-1 (wR(2)) = 0.0726(0.1416). The compound contains an unusual highly reduced pseudo-Keggin type polyoxoanion and exhibits an interesting phosphorus-centered alternate arrangement of layers of molybdenum and vanadium oxides.

Turbulence in laminar premixed V-flames

Strong velocity fluctuations had been found in the laminar premixed V-flames. These velocity fluctuations are closely related to the chemical reaction. But the effects of the upstream combustible mixture velocity on the velocity fluctuations inside the flame are quite weak. The probability distribution function (PDF) of the velocity in the centre region of the flame appears "flat top" shaped. By analyzing the experiment results the flame-flow interactions are found to affect the flame not only at large scale in the flow field but also at small scale inside the flame. These effects will give rise to flame generated small scale turbulences.

解不可压缩流体力学问题的降阶法——Ⅱ.空间V~h的基函数和误差估计

本文对于一大类数值求解二维Navier-Stokes方程边值问题的有限元格式给出了零散度空间V~h的一组简单基函数,讨论了速度的数值误差对压力的数值解的影响,并提出一个改进算法。

倒V电子沉降通量能谱的理论计算

沿极光区磁力线大约在2000公里到8000公里的高度范围内,存在着一个等离子体湍流和大尺度平行电场的加速区。沿磁力线运动的等离子体片中的电子通过此加速区时,受到等离子体湍流和平行电场的共同作用,形成电子沉降的倒V结构。从一维准线性的动力学方程出发,导出了沉降电子通量的能谱方程,得出了电子通量能谱的理论公式。对等离子体湍流和平行电场对沉降电子能谱的影响作了分析和讨论。本文所提出的理论可以解释目前观测到的某些基本现象。

Singular behaviour near the tip of a sharp V-notch in a power law hardening material

This paper presents an asymptotic analysis of the near-tip stress and strain fields of a sharp V-notch in a power law hardening material. First, the asymptotic solutions of the HRR type are obtained for the plane stress problem under symmetric loading. It is found that the angular distribution function of the radial stress sigma(r) presents rapid variation with the polar angle if the notch angle beta is smaller than a critical notch angle; otherwise, there is no such phenomena. Secondly, the asymptotic solutions are developed for antisymmetric loading in the cases of plane strain and plane stress. The accurate calculation results and the detailed comparisons are given as well. All results show that the singular exponent s is changeable for various combinations of loading condition and plane problem.

层流预混V形火焰中的湍流

研究火焰中的情况，发现即使层流预混V形火焰中也存在着强烈的速度脉动。这种速度脉动与预混可燃气的当量比(化学反应因素)密切相关，而受来流速度的影响较小。火焰中心区速度的概率分布函数呈“平顶型”。分析认为火焰与流动的相互作用不仅在流场大尺度空间内影响火焰特性，而且在火焰中小尺度空间内也存在着火焰(化学反应)与流动的相互作用，其结果之一就是在火焰中产生小尺度湍流，这种小尺度湍流将在火焰中小尺度空间内影响火焰特性。