Crystal structure and drawing-induced polymorphism in poly(aryl ether ether ketone). IV

A new crystal modification induced by strain and denoted as form II exists alongside the dominant form I structure in the uniaxially oriented poly(ether ether ketone) (PEEK) and the related polymers. The crystal structure of form II for PEEK is also found to possess a two-chain orthorhombic packing with unit cell parameters of a equal to 0.475 nm, b equal to 1.060 nm, and c equal to 1.086 nm. More extended and flattened chain conformation of form II relative to that of form I is expected to account for an 8% increase in c-axis dimension, which is attributed to the extensional deformation fixed in situ through strain-induced crystallization during uniaxial drawing. Annealing experiments suggest that form II is thermodynamically metastable and can be transformed into more stable form I by chain relaxation and reorganization at elevated temperature without external tension. This strain-induced polymorphism exists universally in the poly(aryl ether ketone) family. (C) 1999 John Wiley & Sons, Inc.

东营凹陷北部陡坡带砂砾岩体性油气藏形成机理及分布规律研究

The north steep slope zone of Dongying Depression has great potential in oil resource and as the usage of 3-d seismic data in the last decade, the exploration of oil and gas has get into the stage of sandy glavel body lithological oil-gas pool exploration. In this thesis, writer take the north steep slope zone of Dongying Depression as target area and take Sha-III and Sha-[V Menber as purpose stratum, study on sequence stratigraphy, depositional system, reservoir description, emphasesing on analyzing of forming of lithological oil-gas pool, especially the dynamics principle of oil and gas preliminary movement from the source rock to the reservoir form lithological oil-gas pools. The aim of this work is to give some quantitatively explanation for the mechanism of lithological oil-gas pool forming, and set up the theory of pool form with characteristic terrestrial faulted basin. There are main conclusions and views as follow. 1. Applying with principle of sequence stratigrapgy, according to the depositional cycles of Dongying Depression, the sequence stratigraphical partition of Tertiary was finished, stressing on dismembering Sha-III and Sha-IV Menber as 5system tracts. 2. The structure of Dongying Depression especially of the north steep slope zone has accomplished, including the analyzing the structural cortroling to depositional condition of the north steep slope zone of Dongying Depression, discussed relationship between the structure of the north steep slope zone and the pool-forming. 3. The horizontal and vertical exchanges of ancient climates and ancient physiognomy of the all stratum units and studies on characteristic of depositional system distribution have been finished, found that there are five depositional systems in the north steep slope zone of Dongying Depression as fluvial, delta (tan-delta), sub-water fluvial fan lacustrine, gravitive flow, and seven formations of sandy glavel body, and forecasting of all kinds of sandy glavel body has been made. 4. Seismic stratigraphy and log stratigraphy have been made, described and forecasted all kinds of reservoir of objective stratum by means of physical geography method, setup a series means of sandy glavel body description suit to target area. 5. The pool-forming system has been studied, analyzing all the elements in petroleum sub-system of Sha-III and Sha-IV Menber of Dongying Depression with view of source controlling, estimated the petroleum system applying source rock potential index combining with distribution ofreservior. 6.Through studying types of pool, the controlling factors of pool-forming of sandy glavel body were discussed by deposition stages, formation types, structure ect. as a conclusion that the characteristics of pool forming in the north steep slope zone of Dongying Depression are, the controlling factor of the pools is mainly lithology, petrophysics of oil sands vary greatly, with a large heterogeneity, all kind of reservoir with different formation has different pool-forming conditions, and as a result, formed various pools of sandy glavel body along the steep slope with regular combination, distribution and constituted the multiple petroleum accumulative pattern. 7. It's the first time to cauculate and estimate the fluid pressure in source rock of Dongying Depression, set up the stratum fluid pressure in Dongying Depression, and firstly use equivalent charging pressure and reservoir forming index to quantitatively evaluate the pool-forming condition of lithological pool.8. Above all studies, follow up the scent of the exploration combined with practice a lot of explorative targets were found, and got geat economic and social benefit.