Kinetic study of hydrolysis of xylan and agricultural wastes with hot liquid water

We investigated the kinetics of hot liquid water (HLW) hydrolysis over a 60-min period using a self-designed setup. The reaction was performed within the range 160-220 °C, under reaction conditions of 4.0 MPa, a 1:20 solid:liquid ratio (g/mL), at 500 rpm stirring speed. Xylan was chosen as a model compound for hemicelluloses, and two kinds of agricultural wastes-rice straw and palm shell-were used as typical feedstocks representative of herbaceous and woody biomasses, respectively. The hydrolysis reactions for the three kinds of materials followed a first-order sequential kinetic model, and the hydrolysis activation energies were 65.58 kJ/mol for xylan, 68.76 kJ/mol for rice straw, and 95.19 kJ/mol for palm shell. The activation energies of sugar degradation were 147.21 kJ/mol for xylan, 47.08 kJ/mol for rice straw and 79.74 kJ/mol for palm shell. These differences may be due to differences in the composition and construction of the three kinds of materials. In order to reduce the decomposition of sugars, the hydrolysis time of biomasses such as rice straw and palm shell should be strictly controlled.

退耕还林(草)工程对吴起县农村经济发展的驱动力分析

以陕西省吴起县为例,在实地调查的基础上,通过对退耕还林(草)工程实施后农村就业结构变化、基本农田种植结构及种植方式的改变、后续产业的发展与农民收入和农村经济进行相关性分析及灰色关联度分析,结果表明:非农行业就业人数占总人数的比例、农业中间物质消耗以及作为后续产业代表的肉类产量四个驱动因素对农村经济总收入提高的相对贡献率分别为:33.64%,32.17%,34.19%。对农民年收入提高的相对贡献率分别达到了33.30%,33.24%,33.46%。退耕还林(草)工程对农村经济的发展起到了巨大的驱动作用。