ELECTROCHEMICAL INVESTIGATION OF LIQUID/LIQUID SYSTEMS USING VARIOUS ORGANIC SOLVENTS

The potential windows of the system water/pure solvent (W/P) and water/solvent mixtures(W/S) have been investigated by cyclic voltammetry with solvents whose dielectric constants lie between 5.87 and 34.82. In the presence of LiCI in the aqueous phase and tetrabutytammoniumtetraphenylborate(TBATPB) in the organic phase, the systems water/allyl iso-thiocyanate (W/AIT) and water/nitrobensene (W/NB) show a same wide epotential window. thermodynamic parameters of ion transfer W/AIT interface were determined. In systems of W/P and V/S the influence solvent effect on the standard gibbs energies of transfer of was discussed.

Functionalization of an ethylene-propylene copolymer with allyl (3-isocyanate-4-tolyl) carbamate

An ethylene-propylene copolymer (EPM) was functionalized with an iso cyanate-bearing unsaturated monomer, allyl(3-isocyanate-4-tolyl) carbamate (TAI), with dicumyl peroxide as an initiator in a xylene solution. Fourier transform infrared (FTIR) was used to confirm the formation of EPM-g-TAI. The peak at 2273 cm(-1), characteristic of -NCO groups in EPM-g-TAI, revealed evidence of grafting. The grafting degree was determined with both chemical titration and FTIR. The grafting degree could be adjusted, and the maximum was over 6 wt % without any gelation. The molar mass distribution of EPM-g-TAI was narrower than that of EPM. The rheological behavior of both EPM-g-TAI and EPM was investigated with a rotational rheometer. The apparent viscosity of EPM-g-TAI was higher than that of EPM and increased with an increasing grafting degree of TAI. Surface analysis by contact-angle measurements showed that contact angles of EPM-g-TAI samples to a given polar liquid decreased with an increasing grafting degree of TAI. We also obtained the dispersion component of the surface free energy (gamma(S)(d)), the polar component of the surface free energy (gamma(S)(d)), and the total surface free energy (gamma(S) = gamma(S)(d) + gamma(S)(p)) of the grafted EPM. These parameters increased with the enhancement of the grafting degree, which gave us a quantitative estimation of the polar contribution of the grafted TAI to the total surface free energy of EPM-g-TAI.

Effects of sensing temperature on the NO2-sensing properties of octa-iso-pentyloxymetallonaphthalocyanine spin-coated films

A kind of 1,6,10,15,19,24,28,33-octa-iso-pentyloxy-2,3-metallonaphthalocyanines complexes MNc(iso-PeO)(8) (M = Co, Cu, Pd) are used as spincoating film-forming materials. The surface morphologies of the films prepared were studied first. These films were then used for the experiments of NO2 sensing. The effects of sensing temperature as well as the NO concentration on the sensing properties were studied. The experimental results showed that the three MNc(iso-PeO)(8) films were uniform, smooth and dense. Due to the different metal ions (M) on the center of naphthalocyanine, the CoNc(iso-PeO)(8) film had a higher film resistance and response-recovery rate in the NO2 sensing experiments. On the contrary, the response to NO2 of the PdNc(iso-PeO)(8) and CuNc(iso-PeO)(8) films were superior to that of CoNc(iso-PeO)(8). By varying the sensing temperature, it was found that the elevation of sensing temperature could improve the sensing response, recovery ratio, and sensitivity of the sensing films. At high concentrations of NO2, the response time became shorter. (c) 2007 Elsevier B.V. All rights reserved.

Preparation, characterization and gas sensing properties of nickel octa-iso-pentyloxynaphthalocyanine spin-coating films

Spin-coated films of nickel 1,6,10,15,19,24,28,33-octa-iso-pentyloxy-2,3-naphthalocyanine complex were obtained and characterized by UV-vis absorption spectroscopy. A linear relationship between the absorbance and solution concentration was observed. Low concentration solutions could afford smooth and homogeneous film surfaces as indicated by atomic force microscopy. The film structure was studied by small angle X-ray diffraction. The films were used for NO2 sensing experiments. The results indicate that the elevation of sensing temperature can shorten the response time and increase recovery ratio and response magnitude of the sensing films. High NO2 concentration can also shorten response time. (C) 2008 Elsevier B.V. All rights reserved.

基于ISO/IEC 9126标准的软件质量评价系统

中国计算机学会

一种符合ISO 14651语义的藏文排序实现方法

本文介绍了一种实现藏文字典序排序的方法,它针对藏文"大字丁字符集"编码方案.通过引入有(无)前加基字符的概念,它把待排序的藏字预处理为有(无)前加基字符、前加字符、基字(基字符或者字丁)、后加字符、再后加字符串后,再行比较,从而避免拆分字丁.本实现方法符合ISO/IEC14651标准语义.

ISO 2022的有限状态机描述

ISO 2022编码体系对字符集国家标准的制订有很大影响,然而标准条款存在不确定性,有时难于理解。本文引入有限状态机(FSM)模型来形式化地刻画ISO 2022的特征。针对FSM五元组,详细说明了其状态空间的构成,提出了输入字母表的等效分类方法,给出了初始状态以及终结状态集合,分析了状态转移函数的规模,并采用FSM描述方法分析了ISO-2022-CN、EUC-CN、复合文本等标准,揭示了这些标准与ISO 2022的内在联系。这些工作有助于ISO 2022标准符合性检测、扩展标准的制订与系统实现复杂度评估。鉴于形式化描述方法在编码字符集标准领域未得到广泛应用,本文工作为该类研究引入了新的思路和方法。

基于ISO/IEC10646标准的藏文操作系统若干问题研究

长期以来尚未有完整的藏文操作系统,原因是藏文文字的特性要求特定的文字处理。本文基于ISO/IEC10646的藏文字符集标准,结合藏文正字法要求,详细分析了藏文操作系统实现中的关键问题:(1)藏文字符集方案比较与藏文存储;(2)藏文输入;(3)藏文显现。藏文显现是公认的“瓶颈”问题。对此,本文提出基于音节划分、使用OpenType字体及相应的文本引擎来解决藏文“叠加”字符的显现。此方案应用于Qt库的实验及相关测试证明基于ISO/IEC10646标准的藏文操作系统实现是较合理的方案。